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81.
Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions 下载免费PDF全文
Jing Guo Jie Pan Shuai Chang Xuewen Wang Na Kong Wenrong Yang Jin He 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(15)
The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction. 相似文献
82.
油品的密度与温度有着确定的对应关系,通过测量温度可以间接测量密度。根据这一关系可以利用小巧的BASIC单片机设计一个价廉、实用的密度计。经实验对比,其稳定性较好,反应灵敏,测量较准确,较常规方法更方便快捷 相似文献
83.
Approximate dynamic programming (ADP) formulation implemented with an adaptive critic (AC)-based neural network (NN) structure has evolved as a powerful technique for solving the Hamilton-Jacobi-Bellman (HJB) equations. As interest in ADP and the AC solutions are escalating with time, there is a dire need to consider possible enabling
factors for their implementations. A typical AC structure consists of two interacting NNs, which is computationally expensive. In this paper, a new architecture, called the ‘cost-function-based single network adaptive critic (J-SNAC)’ is presented, which eliminates one of the networks in a typical AC structure. This approach is applicable to a wide class of nonlinear systems in engineering. In order to demonstrate the benefits and the control synthesis with the J-SNAC, two problems have been solved with the AC and the J-SNAC approaches. Results are presented, which show savings of about 50% of the computational costs by J-SNAC while having the same accuracy levels of the dual network structure in solving for optimal control. Furthermore, convergence of the J-SNAC iterations, which reduces to a least-squares problem, is discussed; for linear systems, the iterative process is shown to reduce to solving the familiar algebraic Ricatti equation. 相似文献
84.
徐文 《中国科学:信息科学》2011,(Z1)
本文回顾总结了我国陆地观测卫星载荷体系、地面系统建设及数据应用等方面的发展现状和成就,分析了当前所面临的挑战和任务,以此为基础,对我国陆地观测卫星的未来发展进行了战略思考和展望,提出了加强国家顶层规划、加强地面系统统筹建设、实现系列化业务化运营、加强国际合作、推进产业化发展等建议. 相似文献
85.
企业办公自动化系统的应用十分广泛,随着互联网的高速发展,WEB应用成为主流,OA系统在互联网上的延伸成为大趋势,本文阐述在WEB应用中如何保障数据和系统安全的手段和方法。 相似文献
86.
In this paper, a single-iteration strategy is proposed for the design of a multi-loop PI controller to achieve the desired gain and phase margins for two-input and two-output (TITO) processes. To handle loop interactions, a TITO system is converted into two equivalent single loops with uncertainties drawn from interactions. The maximum uncertainty is estimated for the initial controller design in one loop and single-input and single-output (SISO) controller design is applied. This controller is substituted to other equivalent loop for design, and finally, the first loop controller is refined on knowledge of other loop controller. For SISO controller tuning, a new method is presented to determine the achievable gain and phase margins as well as the relevant controller parameters. Examples are given for illustration and comparison. 相似文献
87.
88.
Model reference control design methods fail when the plant has one or more non-minimum phase zeros that are not included in the reference model, leading possibly to an unstable closed loop. This is a very serious problem for data-based control design methods, where the plant is typically unknown. In this paper, we extend the Virtual Reference Feedback Tuning method to non-minimum phase plants. This extension is based on the idea proposed in Lecchini and Gevers (2002) for Iterative Feedback Tuning. We present a simple two-step procedure that can cope with the situation where the unknown plant may or may not have non-minimum phase zeros. 相似文献
89.
针对单件小批量型生产企业,为了保证交货期和控制原材料、在制品库存,提出一种生产排产算法--逆序递推算法.本文在算法中考虑到了生产扰动对交货期的影响,并结合实例作出逆序递推排产甘特图来指导生产. 相似文献
90.