Study on Reduction of Sulfur Content in FCC Gasoline

Reduction of sulfur content in FCC gasoline was studied in a fixed fluid bed (FFB) unit by using metal-modified LV-23 FCC catalyst. The results showed that the sulfur content in FCC gasoline could be reduced with LV-23 catalyst modified with zinc, palladium, zinc-palladium, zinc-cobalt, and zinc-nickel. Among these metals or metal combinations, palladium-containing catalyst was the most effective. Desulfufization of the heavy fraction of FCC gasoline was more effective than full-range gasoline under the same conditions with palladium-containing catalysts. A high reaction temperature was favorable to desulfurization, but it would reduce the yield of liquid product. After desulfurization reaction, the olefm content of product gasoline decreased while the aromatic and iso-alkane contents increased. Removal of thiophene and benzothiophene is higher.     

Al2O3对唐钢高炉炉渣性能的影响

针对唐钢近2年提高进口矿配比后，Al2O3含量升高对炉渣流动性带来的不利影响，对唐钢高炉的炉渣性能进行了试验研究。并结合国内同行业的生产实践经验，从理论上分析了炉渣中Al2O3及MgO的适宜含量范围，着重论述了唐钢所处冀东矿区条件下降低Al2O3的主要途径及适应高Al2O3炉渣的具体措施。     

30t转炉三位一体护炉实践

以转炉终点高拉碳操作法及降低出钢温度等操作护炉为根本护炉手段，溅渣为主要护炉方法，贴砖作为护炉的辅助措施，有效地提高了转炉炉龄，达到了1万炉以上，实现了根据设备检修计划下炉。     

An integrated biodesulfurization process,including inoculum preparation,desulfurization and sulfate removal in a single step,for removing sulfur from oils

BACKGROUND: A single‐stage reactor, in which the growth of bacterial culture, induction of desulfurizing enzymes, and desulfurization reaction are carried out in a single step, was adopted to investigate desulfurization of dibenzothiophene (DBT) at high cell densities. Rhodococcus erythropolis, IGTS8 was used as the biocatalyst. Optimal conditions for bacterial growth and DBT desulfurization were investigated. RESULTS: Optimization of fermentation conditions was necessary to obtain high cell densities including controlling accumulation of acetate. Under optimal operating conditions, the maximum optical density at 600 nm (OD₆₀₀) was measured to be 26.6 at 118 h of cultivation. When biodesulfurization of DBT in model oil with a high cell density culture of IGTS8 was investigated, accumulation of sulfate was found to limit the extent of desulfurization. A sulfate removal step was added to obtain a single‐stage integrated biodesulfurization process. Sulfate removal was achieved via an aqueous bleed stream and use of a separation unit to recycle the organic phase. CONCLUSION: A proof of principle of a complete system capable of biocatalyst growth, induction, desulfurization and by‐product separation was demonstrated. This system enables simplification of the biodesulfurization process and has potential to lower the operating cost of the bioprocess. Copyright © 2008 Society of Chemical Industry     

钢坯修磨金属切除率数学模型的研究

从分析修磨过程运动学和单个磨粒切削入手,建立了磨削深度与磨削过程诸参数(如工艺、材料性能、砂轮性能等)的关系表达式,从而建立起金属切除率与各单项参数的定量关系,为改善或提高修磨效率和修磨过程控制提供了有意义的根据。理论分析与实验结果吻合良好。     

转炉溅渣层与镁碳砖炉衬的结合机理

通过对生产现场带有溅渣层的转炉炉衬残砖和试验室小型坩埚溅渣试验结果进行矿相显微结构分析、研究，确定了溅渣层的矿相组成、溅渣层与ＭｇＯ－Ｃ砖结合区域的矿相结构及坩埚溅渣层自上而下的矿相分布规律，并根据矿相结构分析中观察到的烧结层、结合层和溅渣层３个区域，提出了溅渣层与镁碳砖炉衬的结合机理为化学结合、机械镶嵌与化学烧结结合及冷凝结合３种形式。     

吸附法脱除乙烯中少量氧气的吸附剂研究

采用重量法在电子天平上研究了Ｃ２Ｈ４和Ｏ２单组份在５Ａ、１３Ｘ、丝光沸石和碳分子筛等不同吸附剂上的吸附平衡性质和扩散动力学性质。结果表明，在沸石类吸附剂上，Ｃ２Ｈ４的平衡吸附量远大于Ｏ２的平衡吸附量，Ｃ２Ｈ４的吸附扩散速率也大于Ｏ２的扩散速率；在碳分子筛吸附剂上Ｃ２Ｈ４的平衡吸附量大于Ｏ２的平衡吸附量，但Ｏ２的吸附扩散速率远大于Ｃ２Ｈ４的扩散速率，其扩散系数是Ｃ２Ｈ４的２３９倍。单柱评价结果表明，Ｃ２Ｈ４－Ｏ２混合组份通过该碳分子筛吸附剂时，Ｏ２的破点时间长，Ｃ２Ｈ４的纯度可达１００％。加压有利于选择吸附Ｏ２，而且加压吸附、常压脱附再生性能好。该碳分子筛是脱除高浓度乙烯中少量氧气的理想吸附剂。     

新型梳形电缆防火墙的应用

通过新型梳形电缆防火墙的实施，有效地限制了电缆火灾范围，增强了电缆防火、隔火能力，并详细地介绍了梳形电缆防火墙的原理结构、安装使用和注意事项。     

从氯化铅渣中回收铅铋的研究

本文以柿竹园有色金属矿粗铋火法精炼、气化除铅产出的铅渣为原料，在常压下采用氯化钠水溶液进行浸出处理，有效地分离了铅和铋，并将铅制成了化工产品黄丹及硫酸铅     

应用光度分析法测定铁和渣中的微量镓

用光度分析法测定镓，为适应多种试样的测定，补做了个别条件试验。用该方法测定了铁、渣、浸钒渣等六种不同类型试样中镓的含量，分析其精度精度符合要求。