Carbon nanotube supported ruthenium catalysts for the treatment of high strength wastewater with aniline using wet air oxidation

Multi-walled carbon nanotubes (MWCNT) can be efficiently used as support of ruthenium catalysts for the catalytic wet air oxidation of high strength wastewater containing aniline. Catalysts were prepared using different ruthenium precursors, Ruthenocene [Ru(η⁵-C₅H₅)₂], Ruthenium (1,5-cyclooctadiene, 1,3,5-cyclooctatriene) [Ru(cod)(cot)] and Ruthenium trichloride (RuCl₃ · xH₂O), different impregnation methods (excess solution and incipient wetness impregnation) and different MWCNT support surface chemistry (nitric acid oxidized MWCNT-COOH and Na₂CO₃ ion exchanged MWCNT-COONa). The efficiency of the aniline removal obtained with the catalysts prepared with different precursors decreases in the order [Ru(cod)(cot)] > RuCl₃ · xH₂O > [Ru(η⁵-C₅H₅)₂], 100% aniline conversion being obtained after 45 min of reaction with the catalyst prepared with [Ru(cod)(cot)]. The influence of the impregnation technique was found to be negligible, while the use of the MWCNT-COONa support led to increased catalyst performances when compared to that obtained with catalysts prepared with the MWCNT-COOH support. Leaching of ruthenium was observed in all cases, but the use of the precursor [Ru(cod)(cot)] and of the support MWCNT-COONa in the preparation of the catalysts seems to improve their stability. A direct relationship between metal load and catalyst stability was found and attributed to the strength of metal-support interactions.     

基于组织学习理论的装备保障能力生成研究

应用组织学习理论（organizational learning theory,OLT）,分析了装备保障能力生成与组织学习的相关性,对基于组织学习理论的装备保障能力生成机理进行了剖析,并从本体论角度对装备保障能力生成过程中的知识转移和创新进行了研究,最后提出了基于组织学习理论的装备保障能力生成应该注意的问题。可为系统认识和指导我军装备保障能力生成模式转变提供思路。     

探索新形势下军民融合式装备保障发展之路

从分析军民融合式装备保障的动因和存在的问题入手,阐述了构建完善军民融合式装备保障体系,必须要在思想观念、法规制度、体制机制、两用标准、军地人才、军用技术和民用技术等6个方面实现融合,为理解、贯彻装备保障走好军民融合式发展之路提供了一些思路和设想。     

非战争军事行动装备保障若干问题研究

随着我军遂行非战争军事行动任务的增加,对装备保障的要求越来越高,非战争军事行动的研究进入了一个重要时期。我军对非战争军事行动装备保障的研究还处于起步阶段。介绍了非战争军事行动装备保障的特点、原则和要求,研究了非战争军事行动装备保障的运行机制,最后提出了关于问题的几点思考。     

对军民融合式装备保障的认识

军民融合式装备保障是新世纪新阶段我军装备保障建设发展的必由之路。介绍了军民融合式装备保障产生的背景和基本概念,分析了军民融合式装备保障的特征、地位和作用,提出了加强军民融合式装备保障建设发展应重点把握的6个问题。     

混合SVM结合信息熵检测ICMP隐通道*

攻击者可以将生成的任意信息隐藏在ICMP的有效负载中传递出去,构成了ICMP负载隐通道。在分析ICMP数据流熵标准差和熵值分布特性的基础上,提出了基于信息熵的样本集缩减策略。为提高采用标准支持向量机(SVM)的学习能力与推广能力,建立了若干选取规则,构造出一种有效的混合核函数。最后采用混合SVM结合信息熵的方法检测ICMP隐通道,取得了较快的分类速度和较高的检测率。实验结果表明,采用混合SVM结合信息熵检测ICMP隐通道的方法,是有效的、可行的。     

基于简易支持向量机的客户流失预测研究*

应用简易支持向量机（SSVM）进行客户流失预测,以提高机器学习方法的预测能力。以国外电信公司客户流失预测为实例,与最近邻算法（NPA）进行了对比,发现该方法在获得与NPA近似准确率的条件下,所花费的时间和时间增加值远小于NPA,是研究客户流失预测问题的有效方法。     

Fault-Diagnosis Method Based on Support Vector Machine and Artificial Immune for Batch Process

A new fault-diagnosis method to be used in batch processes based on multi-phase regression is presented to overcome the difficulty arising in the processes due to non-uniform sample data in each phase. Support vector machine is first used for phase identification, and for each phase, improved artificial immune network is developed to analyze and recognize fault patterns. A new cell elimination role is proposed to enhance the incremental clustering capability of the immune network. The proposed method has been applied to glutamic acid fermentation, comparison results have indicated that the proposed approach can better classify fault samples and yield higher diagnosis precision.     

Shear performance analysis of a heavy-duty universal hinged cast steel support

This paper presents the shear performance analysis of a heavy-duty universal hinged cast steel support with the largest bearing capacity. The effect of 9 parameters ( 52 specimens) ,i. e. height of the upper support,depth of the ring of the upper support,depth of the top plate of the bottom support,height of the ribs of the bottom support,depth of the ribs of the bottom support,bolt hole diameter,number of the ribs of the bowl,depth of the ribs of the bowl,and yield strength of the material,were analyzed with a 3-dimensional elastic-plastic finite element model in which the nonlinearities of geometry,material and contact were all considered. Analysis shows that height of the upper support,depth of the ring of the upper support and yield strength of the material have a great effect on the mechanical performance of the support. Height of the upper support has the largest effect on performance price ratio of the support,and the maximum effect can be up to 160% . Depth of the top plate of the bottom support,height of the ribs of the bottom support and depth of the ribs of the bottom support have a medium effect on performance price ratio of the support,and the effect is within the limit of 15% 19% .     

新型半刚性网壳锚喷支护技术在软岩巷道中的适用性研究

通过对钢筋网壳锚喷支护的技术特色、结构特点、支护原理的研究,分析了半刚性网壳支护结构对软岩支护的适应性。并完成了室内整架载荷试验。结合在桃园矿的应用情况,阐述了其支护参数选择和施工工艺,并对其进行现场监测,分析了这种新型支护形式的支护性能。实践证明,空间网壳锚喷支护结构与围岩相互作用的整体性好,具有良好的力学性能与较高的承载能力,是软岩巷道中的一种既经济又安全可靠的支护结构形式。