Kinetic study of the deep hydrodesulfurization of dibenzothiophene over molybdenum carbide supported on a carbon black composite: Existence of two types of active sites

Hydrodesulfurization (HDS) is part of the hydrotreating process, which is an ensemble of several reactions (HDN, HDO, HDS, etc.) taking place simultaneously at the industrial scale. Only sulfur is currently submitted to drastic Europeans specifications and conventional commercial catalysts cannot reach the specifications at low cost. This paper presents the behavior of a potential substitute catalyst tested for the deep HDS of a model molecule such as the dibenzothiophene (DBT). The substitute is molybdenum carbide supported on a mesoporous carbon black composite of surface area 240 m² g⁻¹. A global kinetic study of the deep HDS of DBT (300 ppm S) was performed at 623 K and 5.0 MPa and a global kinetic model was proposed as well as global rate constants were calculated to obtain theoretical plots of concentration versus contact time to compare with the experimental data. The kinetic model and global kinetic orders were confirmed as an acceptable correlation was found between calculated and experimental data. Furthermore, the determination of the global kinetic orders indicated that two types of active sites must be present on the surface in order to explain the observed results.     

两江水利枢纽泄洪洞出口右侧高边坡锚喷支护施工技术

锚喷支护作为地质灾害治理中山体过坡支护的一杆方法．具有安全、优质、高效、灵活等特点，本文以吉林省安图县两江水利枢纽泄洪洞出口右侧高边坡治理工程为例．对锚喷支护施工技术作一简单介绍。     

F150交换机告警关联规则的研究

为了提高电信网络运营效率，降低维护成本，电信运营企业在网络告警管理系统中需要引入数据挖掘技术。本文主要研究利用数据挖掘技术来进行故障的管理，即对告警进行关联性分析，详细分析了告警序列数据的关联规则挖掘算法，并在南昌本地网F150交换机的告警数据库中予以实现，同时对实际挖掘结果进行分析和整理，推导出一些实用的关联规则。     

全面留矿法采场顶板支护和落矿爆破工艺的研究

本文介绍的接杆锚杆护顶技术和上向眼大孔距多排微差爆破落矿技术，解决了逐昌金矿全面留矿法采矿工艺中存在的采场顶盘围在面积冒落和采场落矿爆破效果差、效率低这两个问题。     

数据挖掘技术在大坝安全决策支持系统中的应用

数据挖掘技术是一个新兴的，具有广阔应用前景和极富挑战性的研究领域。在充分研究大坝安全决策支持系统的基础上，结合数据挖掘技术的概念与方法等，对数据挖掘技术在大坝安全决策支持系统中的应用进行论述，与此同时，运用数据挖掘技术分析了某大坝垂直位移测值突变的物理成因。     

乳化液浓度自动检测配比系统

本文论述了乳化液浓度自动检测配比系统。文章给出了阻容型浓度、液位传感器的原理、结构和测试电路，以及实现乳化液浓度自动检测与自动配比的系统硬件和软件。系统样机通过了型式试验、防爆和工业性试验。研究结构表明，本系统性能优良，达到了煤矿监控产品技术标准，对提高煤机械自动化程度具有重要意义，推广应用前景广阔。     

构皮滩水电站尾水隧洞特大断面软岩开挖支护

构皮滩水电站尾水隧洞软岩不良地质洞段占尾水隧洞全长的70%以上,确保软岩洞段的安全快速开挖是尾水隧洞施工的关键,尤其一次支护的强度对洞室稳定影响极大。为此,施工中根据软岩的地质特点及尾水隧洞开挖的断面尺寸,采取分层开挖和超前锚杆的施工方式和型钢拱架进行一次支护。根据监测结果,围岩变形很小,一次支护效果良好,表明构皮滩水电站尾水隧洞大断面软岩采取的开挖方式和一次支护方式是成功的。     

Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

巷道最佳注浆加固时机的分析研究

对松散破碎以及软弱围岩巷道进行注浆加固巷道围岩时,注浆时机的选择对注浆效果具有很大的影响。有效地进行注浆加固的先决条件是浆液能够在围岩中均匀地流动渗透到一定范围,且注浆后能明显提高围岩强度和整体承载能力。在综合考虑围岩裂隙的发育程度、注浆加固体的强度、所需控制的围岩变形量及注浆工艺等因素的基础上,确定了最佳的注浆时机——滞后15d～25d。