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941.
在面向过程的陶瓷膜材料设计理论模型的基础上,以TS-1钛硅分子筛悬浮液固液分离为应用体系,计算了陶瓷膜分离过程的操作条件与渗透性能的关系,与实验结果有良好的一致性.计算表明,对于平均粒径为290 nm的钛硅分子筛体系,陶瓷膜存在最优孔径区间(200~300 nm),使膜保持高渗透通量.孔径小于200 nm时膜通量随孔径增大而增大,孔径大于300 nm时膜通量随孔径增大而减小;采用孔径为200 nm的陶瓷膜过滤钛硅分子筛,渗透通量随时间的变化关系与模型预测结果一致,稳定通量达到800 L/(m2.h). 相似文献
942.
A NEW SIMULATION APPROACH TO THE ENTROPY-RELATED PROPERTIES OF FLUIDS——CHEMICAL POTENTIAL AND HELMHOLTZ FREE ENERGY OF HARD SPHERE FLUIDS
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A new approach to the computation of entropy-related properties of fluids has been pre-sented.Application of the new technique to hard sphere fluids shows that it is capable of providingreliable estimates of such properties as the chemical potential and Helmholtz free energy,even athigh density where other existing methods are hardly applicable.The chemical potential of an infinitedilute component in hard sphere systems has been estimated,and compared with that calculated fromthe Carnahan-Starling equation. 相似文献
943.
A Numerical Sirnulation of Gas-Particle Two-Phase Flow in a Suspension Bed Using DifFusion Flux Model
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A mathematical modei of two-dimensional turbulent gas-particle twophase flow based on the modified diffusion flux modei (DFM) and a numerical simulation method to analyze the gas-particle flow structures are developed. The modified diffusion flux modei, in which the acceleration due to various forces is taken into account for the calculation of the diffusion velocity of particles, is applicable to the analysis of multi-dimensional gas-particle two-phase turbulent flow. In order to verify its accuracy and efficiency, the numerical simulation by DFM is compared with experimental studies and the prediction by k-ε-kp two-fluid modei, which shows a reasonable agreement. It is confirmed that the modified diffusion flux modei is suitable for simulating the multi-dimensional gas-particle two-phase flow. 相似文献
944.
聚合物流变性能对共注射成型的影响 总被引:3,自引:0,他引:3
在共注射成型多相分层流动充模成型机理的基础上,揭示了芯壳层熔体对共注射成型的分层界面形貌和芯层熔体前沿突破的影响,并模拟了芯壳层熔体粘度比对共注射成型的影响,建立了芯壳层熔体粘度与分层界面和前沿移动界面菜貌的关系。本文的模拟研究结果与一些文献的实验结果相吻合。 相似文献
945.
Molecular dynamics simulation used to study the binary polymer blend of poly (ether imide) (PEI) and polycarbonate (PC) showed that these polymer blends are immiscible. The Flory-Huggins interaction parameter, χ, calculated from simulation reached a minimum value at 80 wt% PEI. The simulation results showed that the concentration dependence of χ was mainly due to electrostatic interaction and van der Waals force. The simulation results were supported by differential scanning calorimetry (DSC) measurements. The DSC measurements showed that there are two distinct glass transition temperatures for all the blends' concentrations. However, at 80wt % PEI, the Tg of PEI-rich phase reached a minimum while that of the PC-rich phase was comparable to its pure form indicating that there is some partial miscibility of PC in the PEI rich phase, but no PEI is incorporated in the PC rich phase. From simulations, the χ versus concentration plot shows the same trend as the experimentally measured glass transition temperature versus concentration plot. 相似文献
946.
生产实习教学环节是化工类高职学生实践教学内容的重要组成部分,传统的考核形式简单、方法单一,学生的实际水平从分数上得不到很好的反映.采用"挂牌仿真生产操作"方式可以对每一个学生的实习结果做出科学的评价,有利于学生主观能动性的发挥. 相似文献
947.
Polyurethane prepolymers prepared from toluene 2,4‐diisocyanate, toluene 2,6‐diisocyanate, and polypropylene glycol with a ratio between the isocyanate and hydroxyl groups equal to 2 were analyzed by 1H nuclear magnetic resonance (NMR) spectroscopy in acetone‐d6. Different temperatures and concentrations were used. Toluene 2,4‐dimethylurethane and toluene 2,6‐dimethylurethane were synthesized and used as model compounds to assign prepolymers signals. Measurements of spin–lattice relaxation time T1 by “inversion recovery” experiments were carried out on toluene 2,4‐diisocyanate, toluene 2,6‐diisocyanate, toluene 2,4‐dimethylurethane, toluene 2,6‐dimethylurethane, and polyurethane prepolymers. Differences in T1 times were used to interpret prepolymers spectra, by means of the strong observed effect on protons due to the presence of adjacent isocyanate groups. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 347–357, 2003 相似文献
948.
Hydrolysis of olive oil, soybean oil, mink fat, lard, palm oil, coconut oil, and a hydrogenated, hardened oil with lipase
from anAspergillus sp. has been studied. The lipase had high specific activity (60,000 U/g) and did not show any positional specificity. The
lipase proved to be a more effective catalyst than Lipolase fromA. oryzae, with an optimal activity at 37°C and pH 6.5–7.0. It was activated by Ca2+ but inactivated by organic solvents such as isopropanol and propanone. All substrates examined could be hydrolyzed to corresponding
fatty acids with this enzyme at concentrations of 5–30 U/meq with yields of 90–99% in 2–24 h. The degree of hydrolysis was
almost logarithmically linear with reaction time and occurred in two stages. The lipase was stable and could be repeatedly
recycled for hydrolysis. 相似文献
949.
950.
以扫描仪面框薄壁件注塑成型为例,应用Moldflow软件分析了模具温度、熔体温度、浇口位置和保压参数对翘曲变形的影响规律,提出了减小翘曲变形的工艺措施,分析结果与生产实际吻合。 相似文献