Cure reaction for modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide

The glass‐transition temperature as a function of curing conversion for a modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide (BMI) resin was investigated at different temperature regimes and modeled using a modified Di Benedetto equation. Although the relationship between the glass‐transition temperature and conversion of the BMI system conforms to the Di Benedetto equation for α < 0.6 and at lower cure temperatures, at higher cure temperatures the results deviated significantly from the equation; thus, it was an inadequate model for the system. Fourier transform IR analysis showed that the major crosslinking reactions did not occur during cure for the modified BMI at and below 150°C. However, as the cure temperature was increased, the crosslinking reactions responsible for 3‐dimensional network structures became more dominant. At 190°C the C? N? C_stretch vibration of the uncured maleimide ring converted into succinimide rings in the curing process. Simultaneously, a decrease was observed for the absorbance bands of ? C? H_bending (maleimide). The higher cure temperatures induced a significantly faster initial crosslinking rate and also resulted in a shorter period of time after which further crosslinking was retarded, because the increase in the crosslinks also physically slowed further crosslinking activity. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 227–235, 2002     

Al2O3基耐磨陶瓷涂层的燃烧合成与应用

介绍了燃烧合成表面涂层技术的基本原理 ,开发了相应的制备工艺 ,并在此基础上研制了内覆陶瓷涂层的复合钢管、弯管及弯头。陶瓷涂层主要由α Al2 O3相、部分FeO·Al2 O3相和 3Al2 O3·2SiO2 相组成 ,采用添加剂可以有效提高熔体的流动性 ,使陶瓷的凝固和结晶过程得到进一步控制 ,有助于减少孔隙 ,提高陶瓷涂层的致密度。现场应用试验表明 ,涂层具有较好的耐磨性能 ,可使设备的使用寿命大为延长     

Pure perceptual-based sequence learning.

Learning a sequence of target locations when the sequence is uncorrelated with a sequence of responses and target location is not the response dimension (pure perceptual-based sequence learning) was examined. Using probabilistic sequences of target locations, the author shows that such learning can be implicit, is unaffected by distance between target locations, and is mostly limited to first-order transition probabilities. Moreover, the mechanism underlying learning affords processing of information at anticipated target locations and appears to be attention based. Implications for hypotheses of implicit sequence learning are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Characterization of Tomato Pulp Stickiness during Spray Drying using a Contact Probe Method

A contact probe test was developed to characterize the surface stickiness of a tomato pulp droplet at various moisture contents and temperatures. To provide tomato pulp samples with different moisture contents, tomato powder produced by a laboratory spray dryer was wetted to seven different moisture levels. The instantaneous tensile force curve was recorded during the probe withdrawal from which the maximum tensile force and other useful information were obtained and cross-examined against images of bonding, debonding, and failure of the material. Generally, at higher moisture contents tomato pulp exhibited cohesive failure followed by semi-adhesive failure, but when moisture content decreased to a certain level, a peak tensile pressure was observed and the failure was adhesive. In addition, higher temperatures shifted the points of adhesive failure toward lower moisture content.     

考虑抗力退化的公路钢筋混凝土梁抗弯强度可靠性分析

本文采用了一个时变荷载模型和一个考虑了钢筋锈蚀，钢筋屈服拉力，混凝土抗压强度和粘结力等多个影响因素的多参数抗力劣化模型，对公路钢筋混凝土梁抗弯强度可靠性在服役期内的变化趋势进行了研究，并针对一实例对各影响参数对可靠性分析的敏感性进行了分析。     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

Dynamics of hydrated iron(II) cations in nafion polymer membranes

Mössbauer studies of Fe²⁺ in water-soaked nafion polymer membranes in the temperature range between 90 K and 250 K have been performed. Above a critical temperature (～ 180 K) the spectra exhibit both elastic narrow absorption lines and quasielastic broad lines. These spectra are typical of bounded diffusion phenomena observed by Mössbauer spectroscopy in macromolecular systems like haemoglobin, myoglobin and ferritin. Similar spectral shapes have been observed by quasielastic neutron scattering from water in nafion membranes. Within 50 K above the critical temperature the total Mössbauer absorption area decreases by an order of magnitude whereas the narrow absorption line decreases by two orders of magnitude. The results are interpreted in terms of bounded diffusive motion of the iron. Using a model based on overdamped harmonically bound Brownian motion, the essential parameters of the iron motion can be derived as a function of temperature. The iron motion most probably reflects the motion of a large Fe²⁺ complex, e.g. Fe(H₂O)²⁺₆, which is attached to the polymer side chains via the sulphonic group.     

罐装食品用电镀锡板的耐蚀性及其试验方法

综述了影响罐装食品用电镀锡板耐蚀性能的因素及其试验方法。