Leaching kinetics of Cs and Co radionuclides fixed in cement and cement-based materials

Leach characteristics of ¹³⁷Cs and ⁶⁰Co radionuclides from both ordinary Portland cement and cement mixed with two different ratios of silica fume and ilmenite have been studied using International Atomic Energy's (IAEA) standard leach method. A mathematical model has been simulated to predict the release rate of each nuclide from cubic geometry waste matrix and the predicted values are discussed in relation to experimentally observed leach rates to confirm the validity of the proposed mechanism in the model. The effect of temperature on the radionuclides leaching rates was also studied and the effective diffusion coefficients were obtained at different temperatures. The net fractional release of the two radionuclides from different waste forms showed a decreasing pattern as ¹³⁷Cs>⁶⁰Co, indicating the largest diffusion coefficient for cesium in all waste matrices.     

垃圾焚烧发电厂烟气处理系统设计研究

文中结合垃圾焚烧发电厂烟气处理设计,介绍了干法烟气净化系统设计的主要技术要点及其效果,为垃圾焚烧发电厂烟气净化处理提供了设计的方向.     

马钢A/OO生物脱氮装置的试运行

介绍了马钢A/OO生物脱氮装置的工艺流程、工艺条件及影响因素,探讨了A/OO生物脱氮工艺试运行中存在的问题和解决措施。     

从含有机物的金废料中提取纯金的研究

物料的经蒸发、燃烧和焙烧除去有机物。焙渣用硝酸浸出可溶性杂质，金富集在渣中。用正水溶解金。金溶液用Ｈ２ＳＯ４和ＮａＯＨ进行纯化处理，用亚硫酸钠沉积金。金粉洗至无Ｃｌ＾－反应后，加稀硝酸煮沸３０￣６０ｍｉｎ，得到纯度９９．９５％以上的海锦金。     

降低锅炉飞灰可燃物的途径

介绍在发电厂锅炉运行过程中降低燃烧低挥发分高热值燃料飞灰含碳量的途径     

关于新建炉EDTA低浓度清洗的探讨

阐述了EDTA清洗锅炉的基本原理,低浓度清洗新建炉的工艺、方法及控制要点,EDTA低浓度清洗与协调EDTA清洗的经济性比较,为新建炉EDTA低浓度清洗探索了方向。     

燃煤锅炉供热系统的模糊控制

介绍燃煤锅炉供热系统的自动化节能模糊控制方案,燃煤锅炉供热系统是一个大惯性的滞后系统,传统的单纯PID控制效果不理想,而基于工人熟练的经验和专家知识的模糊控制能够达到比较好的效果。系统中对控制参考量水温和炉膛负压这两个输入量模糊化处理,由控制规则推出输出模糊子集,再应用模糊推理合成规则得出PID的系数,PID控制器根据输出量来控制鼓风机、引风机、炉排电机和水泵的变频器。     

黄金冶炼厂污染源治理技术

本文阐述了采用加温加压无氰解吸、金电解精炼，活性炭酸洗、火法再生产工艺，所产生污染物的治理技术。     

Fenton试剂处理苯酚和甲醛废水的研究

用H2O2同Fe^2 结合的Fenton试剂处理有机废水是一种经典的催化氧化法，这种方法适合于处理废水中高浓度、难降解的有机物质。主要研究了Fenton试剂处理含苯酚和甲醛有机废水样的反应机理和影响因素，试验结果表明：废水中苯酚和甲醛的去除率均可达到95％以上，COD去除率达到85％以上，表明用Fenton法处理含苯酚和甲醛的有机废水是一种非常有效的方法。     

Simultaneous recovery of copper and surfactant by an electrolytic process from synthetic solution prepared to simulate a concentrate waste stream of a micellar-enhanced ultrafiltration process

Electroplating method was employed to recover copper and surfactant simultaneously from synthetic solutions prepared to simulate concentrated waste stream generated from micellar-enhanced ultrafiltration. Effects of surfactant and copper (II) concentrations, surfactant to copper (II) molar ratio (S/M), electroplating voltage and time, solution pH, and ionic strength on metal recovery and electrical current efficiency were investigated. Results show that at a fixed S/M ratio of 5, the first-order kinetic constant for Cu (II) removal by electroplating increases with decreasing SDS concentration. At fixed SDS concentration of 8.5 mM, increasing initial Cu (II) concentration increases both Cu (II) recovery and current efficiency. Electrolyte pH has profound effects on the metal recovery and current efficiency due to the difference in solution conductivity after pH adjustment and the extent of Cu (II) adsorption onto SDS at different pHs.