Influence of washing and of heat-treatment conditions on the thermal stability of VPI-5

Thorough washing of a VPI-5 synthesized with n-dipropylamine as template improves greatly its thermal stability while no major change is observed in the template content. A detailed study of the influence of the pretreatment conditions shows that in order to obtain a high thermal stability (up to at least 960 °C) two parameters are of importance. The removal of both the template and the adsorbed water requires either a low heating rate at atmospheric pressure or a low pressure (less than 3 Torr) when the heating rate is 300 ° per hour.     

Stability of large-scale coal-fired MHD channels

Stability of large-scale coal-fired MHD channels is studied by (1) linearized stability analysis, and (2) time-dependent 1-D analysis. The channel length is 15 m with 600 electrode pairs, and the output power ranges from 220.6 MW through 258.7 MW. Linearized stability analyses show that the Faraday channels operated with fixed loading resistance are stable, whereas the two waves of u and u–a (u, a: gas and sound velocity) become unstable in the Faraday channel with fixed loading factor. Two waves of u and u–a are unstable in the diagonal channel with fixed loading current and the u + a wave becomes unstable in the diagonal channel with fixed electrode current. Time-dependent one-dimensional analyses indicate that the Faraday channels with fixed load resistance are smooth without growth of fluctuation. The diagonal channels with fixed electrode current are smooth with no fluctuation, though the linear theory indicates that the u + a wave is unstable. The diagonal channel with fixed load current suffers large disturbance along the latter half of the channel, being consistent with the linearized analysis which indicates that the u - a and u waves are unstable.     

The Danish Twin Apartment Study – Part II: Mathematical modeling of the relative strength of sources of indoor air pollution

Abstract This study deals with the modeling of air pollution in apartments from laboratory measurements of source strengths, using formaldehyde and Total Volatile Organic Compounds (TVOCs) as model pollutants. The sources in two test apartments were grouped into two: building-related sources and occupant-related sources. The measured source strengths and ventilation rates were used for the prediction of concentrations expected in the apartments. These predictions were compared to measurements in the apartment over 12 months. The conclusions were that the model predictions based on emission rates measured in the laboratory can be used to predict the long-term concentration of the two model pollutants in the apartments. Considering the measured differences in ventilation between the apartments, an occupant emission rate of between 0.2 and 0.3 mg/h/kg body weight could be estimated. Based on previous suggested limits of acceptable exposures of humans to VOCs, an acceptable average emission rate of VOCs from building materials in general was estimated to be about 30 (μ/m²/h. The modeling showed that during the first 200 days, building materials dominated the emissions. After this, sources relating to the occupants dominated. On average about half of the VOC pollution originated from the building materials.     

Monitoring water quality in reservoirs with IRS-1A-LISS-I

An attempt has been made to quantify the relationship between the variation in IRS-IA-LISS-I (Indian Remote Sensing Satellite-1A Linear Imaging Self-Scanning System) radiance data and field measured change in secchi disc depth. Secchi disc depth was measured for 47 predetermined sampling locations on reservoir surface water. At extinction depth (secchi depth), water samples were collected from all the sampling locations. Suspended sediments of eight locations representing various reaches of the reservoir were selected for mineralogical, particle size and optical properties analysis. The LISS-I radiance value in band 1 (0.45–0.52µm) band 2 (0-52–0.59 µm) and band 3 (0.62–0.68 µm) were used in a regression analysis. The absorption infrared band 4 (0.77–0.86 µm) was not included in the analysis. In these, the dependable variable was secchi depth (SD) and the LISS-I-radiance data was the estimator variable. Forty-seven data sets of 20 October 1988 from Tawa reservoir surface water were used to obtain an estimator equation for SD. The verification of the estimator equation was tested by applying it to a data set of 21 measurements of 28 September 1988 for this reservoir. The coefficient of correlation between observed and estimated values for the 28 September 1988 data set wasr=0.92 for SD, indicating that the equation could accurately predict the water clarity (SD) for this reservoir on new occasions from IRS-IA-LISS-I spectral data. It is shown that mineral composition and optical properties of suspended sediments influence the reflected radiance of water quality. It is concluded that IRS-IA-LISS-I data provide a useful means of mapping water quality in reservoir.     

A structure/function study of polyaminoamide dendrimers as silica scale growth inhibitors

Dendrimers have attracted immense attention during the last decade due to their interesting properties both from a basic and an applied research viewpoint. Encapsulation of metal nanoparticles for catalysis, drug delivery and light harvesting are only some applications of dendrimers that are breaking new ground. A novel application of dendrimer technology is described in the present paper that relates to industrial water treatment. Industrial water systems often suffer from undesirable inorganic deposits. These can form either in the bulk or on metallic surfaces, such as heat exchangers or pipelines. Silica (SiO₂) scale formation and deposition is a major problem in high‐silica‐containing cooling waters. Scale prevention rather than removal is highly desired. In this paper, benchtop screening tests on various silica inhibition chemistries are reported, with emphasis on materials with a dendrimeric structure. Specifically, the inhibition properties of commercially available STARBURST^® polyaminoamide (PAMAM) dendrimers generations 0.5, 1, 1.5, 2, and 2.5 are investigated in detail together with other commonly‐used scale inhibitors. Experimental results show that inhibition efficiency largely depends on structural features of PAMAM dendrimers such as generation number and nature of the end groups. PAMAM dendrimers are effective inhibitors of silica scale growth at 40 ppm dosage levels. PAMAM dendrimers also act as silica nucleators, forming SiO₂–PAMAM composites. This occurs because the SiO₂ formed by incomplete inhibition interacts with cationic PAMAM‐1 and ‐2. The general scope of silica formation and inhibition in industrial waters is also discussed. Copyright © 2005 Society of Chemical Industry     

压力容器材料质量控制的几个重要环节

针对压力容器材料方面存在的问题,从设计、采购、检验、制造等环节进行了分析,根据实际情况确定材料的质量控制要点。材料使用前要通过各种检测手段,判断材料的真实性,确保所用材料合格;并应从设计、选材、采购、计划、填报内容和选择可靠的供应方等方面加以控制,确保材料的正确使用,为压力容器产品的材料控制提供借鉴。     

Thermal stability and high-temperature wear of Ti–TiN and TiN–CrN nanomultilayer coatings under self-mated conditions

Ti–TiN and TiN–CrN nanomultilayers were thermally stable retaining uniform and sharp layer interfaces up to 24 h at 773 K, without any oxidation or phase transformation accompanying each individual layer. Decreasing the multilayer spacing resulted in an increase in the hardness in both cases. The coating hardness was found to be independent of the substrate type, when applied on HS718, Ti64 and HCHCr substrates. In scratch testing, the multilayers displayed a better resistance to the onset of failure, as compared to the monolayer TiN. The substrate plasticity played an important role in determining the coating failure mode. Self-mated wear tests revealed the CrN–TiN system to exhibit the best wear behaviour, both at room temperature and at 773 K. The Ti–TiN coatings are more accommodative with all three substrates, as compared to TiN–CrN and TiN.     

我国车用无铅汽油的质量状况及分析

对1998－2001年间生产领域和流通领域的近500批次汽油产品检验数据进行了总结和分析，表明我国汽油的实物质量正在不断提高，但从环保要求出发还需不断向国际水平靠扰，尤其应进一步降低烯烃含量，硫含量。     

北京城市供水安全及对策研究

“十一五”期间是首都经济社会快速发展的关键时期，也是应对水资源紧缺、保障供水安全的关键时期。确保首都供水安全是北京水务工作的第一要务，北京市水务局针对城市供水存在的主要矛盾和问题，对城市供水水源、水质水量、水厂、管网、设施等情况进行了全面调查，确定了工作思路，并据此提出了保障城市供水安全的目标和措施。