Study on Dihydrated Praseodymium Acetylacetonate by Photoacoustic Spectra with Broad Wavelength Range

Photoacousticspectroscopy (PAS)hasbeenusedtonondestructivelyinvestigatealmostallkindsofsam ples,whetherthesampleiscrystalline ,powderorgel .PAspectr oscopyisacalorimetrictechniquewhichmeasurestheenergyabsorbedandsubsequentheatingofthesamplesduetoanonradiativerelaxationpro cess .ThereforePAScanbeusedtostudyopaque ,highlyreflectiveandscatteringsamples ,whicharedif ficulttostudybyconventionalspectroscopytech niques[1] .Withouttheneedofsamplepreparation ,PASavoidstheriskofsamplealteration ,pre…     

真空钙热还原炉渣的综合利用研究

研究了从真空钙热还原炉渣中回收稀土的工艺条件；采用本工艺得到的合格稀土溶液，其回收率达65．41％；副产品氟化钙用作炼硅铁合金的助熔剂，使钙热还原炉渣得到综合利用。     

Crystalline Behavior and Magnetic Properties of Nd60Fe30-x Al10Cox（x = 0,5,10） Bulk Amorphous Alloys

Crystalline behavior and magnetic properties of Nd60Fe30-xAl10Cox( x = 0, 5, 10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X-ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as-cast Nd60Fe30-xAl10Cox ( x = 0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as-cast Nd60Fe30-xAl10Cox (x = 0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity (iHc) increases while the saturation magnetization(σs) and remanence (σr) decrease. The Curie temperature for the as-cast Nd60Fe30-xAl10Cox alloys increases from 451 K for x =0 to 468 K for x = 10. Some pre-cipitation of crystalline phases does not affect the hard magnetic properties of Nd60Fe30-xAl10Cox(x = 0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.     

溶胶-凝胶生物玻璃多孔材料显微结构和生物活性的扫描电镜及红外光谱分析

本文利用溶胶．凝胶法制备了CaO-P2O5-SiO，系统生物活性玻璃，并以其为原料制备了用于骨修复及骨组织工程支架的块状生物活性材料。利用体外实验方法(invitro)结合x射线衍射(XRD)、扫描电子显微镜(SEM)和傅立叶变换红外光谱分析(FTIR)技术对不同烧结工艺制备的材料结构、晶相和生物活性的影响进行了分析研究。研究表明，经800℃和1100℃烧结5min的两种材料均有硅磷酸钙Ca5(PO4)2SjO4微晶相析出。烧结温度越高，析出微晶相的体积比例越大，材料的生物活性则越低。在模拟生理溶液中碳酸羟基磷灰石(HCA)只在烧结体中的玻璃颗粒表面形成，而在其硅磷酸钙Ca5(PO4)2SiO4微晶相表面未发现HCA形成。     

Alleviation Effect of Lanthanum on Cadmium Stress in Seedling Hydroponic Culture of Kidney Bean and Corn

Since1970s,rare earths(RE)have been exten-sively used as micro-fertilizers for crops in China.Ithas already been proved that REcani mprove the pro-duction and quality of crops.However,there havebeen a fewinvestigations about using RE as regulatorin pollution ecology.For example,An et al[1]studiedthe effects of O3on wheat growth and the protectiveeffect of RE.Yan and Zhou et al[2,3]discussed theprotective effect of RE on plants under acid rainstress.Jia et al[4]and Hu et al[5]reported th…     

HDA-1特种不锈钢焊条的研制及应用

以不锈钢焊丝作焊芯，通过药皮过渡某些合金，用常规方法制造一种特殊焊条。焊层金属为铁素体 奥氏体双相组织，具有良好的抗裂性和抗高温(900—1200℃)氧化性能，特别耐含S气氛的高温氧化。经用户在镁还原罐上两年多的使用，获得了理想的效果。     

Hydrogen Absorption and Release Behavior in Hydrogen Decrepitation Process of Nd-Fe-B Alloys

The behavior of hydrogen absorption and release in hydrogen decrepitation (HD) process of Nd-Fe-B alloys were investigated. The results reveal that the reactivity and the amount of hydrogen absorption in HD process are related to the surface activity of the alloy so that the fresh and active surface has a higher efficiency. The presence of Nd-rich phase at the grain boundary is an essential factor of the HD activity of the alloy at room temperature. On degassing, hydrogen is released from the HD powder continuously with increasing temperature. And the residual hydrogen is as low as 0.0015% at 1073K, which shows that the hydrogen is almost exhaused. It is feasible to remove the hydrogen from the HD powder by heating treatment at the temperature of 523-723K for 1h prior to the magnetic field forming in order to decrease the harmful effect of hydrogen on the easy axis alignment of HD magnet.     

“呼吸道吸入天然钍（ThO2）和稀土矿尘联合作用的研究”（1987～2002）2003年获奖

由中国疾病控制中心辐射防护和核安全医学研究所(原卫生部工卫所)及协作单位包钢白云鄂博矿职工医院共同完成的“呼吸道吸入天然钍(ThO2)和稀土矿尘联合作用的研究”项目，获2003年度北京市科学技术奖二等奖。