Cu对NiFe/Cu/NiFe层状薄膜的巨磁阻抗效应影响的研究

用直流磁控溅射方法制备了NiFe/Cu/NiFe层状薄膜 ,研究了Cu膜宽度对NiFe/Cu/NiFe层状薄膜的巨磁阻抗效应的影响 ,结果表明 ,层状薄膜的巨磁阻抗效应随Cu膜宽度发生振荡现象 ;并提出了一个等效电路模型直观地解释了层状薄膜增强巨磁阻抗效应的机理     

多尺度模拟研究纳米凸体几何形貌对初始塑性的影响

研究金属表面微凸体的力学行为对深入理解摩擦、磨损和设计微纳米机电器件有很大帮助.采用准连续方法探索了纳米压痕作用在薄膜(001)表面的纳米微凸体几何形貌对铝和铜薄膜初始塑性的影响规律.结果显示,相较于平坦表面,微凸体的存在显著地降低了薄膜的屈服应力.矩形微凸体横纵比对屈服应力的影响不大.随着底角α的增大,梯形微凸体的屈服应力呈现降低的趋势,尤其是α＞54.7°.同时,在纳米尺度限制全位错形成的条件下,铝中可能容易形成挛晶结构.     

考虑温度效应的微操作平台的建模与性能分析

微操作平台处于温度变化的工作环境中会产生热误差、断裂或疲劳破坏等意外情况.为了提高基于直梁式柔性铰链的微操作平台的精度,采用有限元方法建立考虑温度效应的平台热响应模型,并基于该模型对其热误差和热应力进行分析.采用欧拉-伯努利梁模拟直梁式柔性铰链和杆件的力学行为,采用最小势能原理得到计入温度效应的微操作平台的力学方程.采用模态截断技术推导出温度变化与热误差、热应力之间的传递函数.以桥式微操作平台为算例分析温度变化对其性能的影响.分析结果表明:热误差对温度变化的灵敏度为0.192μm/℃,温度变化会产生较大的静态热误差;通过选择合理的结构参数可减小热误差;当单位温度变化时会产生0~0.21μm振动和11.6 MPa的热应力,在动态热载荷作用下会产生较大的热振动和热应力.所以,不能忽略温度效应对微操作平台的影响,需要通过优化设计和热误差补偿策略减小其影响.     

30.4 nm Si/C多层膜反射镜的制备与测量

采用离子束溅射镀膜装置制备了一种新的材料组合Si/C多层膜 ,用于 30 4nm波段的正入射多层膜反射镜。并用软X射线反射率计测得其反射比最大值为 0 14。有效地抑制了 15 0nm处的二级衍射峰。     

掺铜铌酸钾锂晶体光析变效应的研究

在铌酸钾锂 (KLN)晶体中掺进CuO ,采用Czochralski法生长Cu∶KLN晶体。测试Cu∶KLN晶体红外透射谱 ,研究OH- 吸收峰发生红移的原因。以二波耦合光路测量Cu∶KLN晶体的光析变擦除曲线 ,计算擦除时间和光电导 ,研究Cu∶KLN晶体的光折变性能     

Study of the Adsorption Space of Modified Clinoptilolites

Carbon dioxide （CO2） adsorption is an important adsorbent characterization method and a significant industrial process. In separation and recovery technology, the adsorption of the CO2 is important to reduce the concentration of this gas considered as one of the greenhouse gases. Natural zeolites, particularly clinoptilolite, are widely applied as adsorbents. In this regard, in the present research, the structure, composition and morphology of modified with hexafluorosilicate （HFSi） and orthophosphoric acid （H3PO4） clinoptilolites were investigated by characterizations and measurements made with, X-ray diffraction （XRD）, thermogravimetric analysis （TGA）, scanning electron microscopy-energy dispersive X-ray analysis （SEM-EDAX） and gravimetric adsorption. Additionally, the surface Chemistry of the modified clinoptilolites was analyzed by applying diffuse reflectance fourier transform infrared spectrometry （DRIFTS）. Further, the interaction of CO2 within the adsorption space of these modified clinoptilolites and a synthetic ZSM-5 zeolite was studied with the help of adsorption measurements. After all, an appropriate theoretical methodology for the analysis of the XRD and adsorption data was applied. The calculated cell parameters of the tested are similar to those reported for a typical clinoptilolite of： a = 17.662 A, b = 17.911A, c = 7.407 ~ and fl = 116.40 The resolution of the TGA derivative profiles indicated the presence of two steps for water release, one of them represents the loss of majority of the water present in the micropores. This was evidenced as a broad peak centered at about 50℃ for the CSW-HFSi-0.1, but at 100 ℃ for the samples CSW-HFSi-0.4. The SEM micrographs corresponding to the modified clinoptilolites, was evidenced that the CSW zeolite shows secondary particles exhibiting diameters from 3 to 40 μm, formed by primary clinoptilolite crystallites showing a crystallite size, φ = 40 nm. The EDAX elemental analysis it can be demonstrated that the exchange process replaced about 85% of the charge compensating ions. The DRIFT spectra of the modified clinoptilolites, specifically, CSW-HFSi-0.1, show a narrow band at about： 3,740 cm-1 corresponding to terminal silanol groups （Si-OH） and a band 3,600-3,650 cm1 resulting from extra-framework AI-OH. With the precision of the measured micropore volumes related to the excellent fitting of the adsorption data by the D-R isotherm equation, it can be affirm that carbon adsorption took only place in the micropore region. The isosteric heat of adsorption calculated for the modified clinoptilolites was greater than those values reported of ZSM-5 zeolite, particle packing silica, dealuminated Y zeolite （DAY） Cd, Zn and Ni-nitroprussides and Cu-nitroprusside and a Ni-MOF. With the obtained result it can be concluded that the modified clinoptilolites with HFSi showed a quality as adsorbent comparable to commercial synthetic zeolites.     

PZT/Y0.9Ca0.1Ba2Cu4O8及Ag2O掺杂的复合氧化物陶瓷的NTC效应

报道了压电材料ＰＺＴ中掺杂超发Ｙ０．９Ｃａ０．１Ｂａ２Ｃｕ４Ｏ８,而超导粉中又能Ａｇ２Ｏ的掺杂,这种复合氧化物陶瓷的制备方法及电导率的测试结果,表明材料具有很强的ＮＴＣ效应。     

Oxidation and Mechanical Properties of SiC/SiC-MoSi2-ZrBa Coating for Carbon/Carbon Composites

To improve oxidation resistance of carbon/carbon （C/C） composites, a SiC/SiC-MoSi2-ZrB2 double-layer ceramic coating was prepared on C/C composites by two-step pack cementation. The phase compositions and microstructures of as-prepared multilayer coating were characterized by X-ray diffraction and scanning electron microscopy. The oxidation resistance at 1773 K and the effect of thermal shock between 1773 K and room temperature on mechanical performance of coated specimens were investigated. The results show that the SiC/SiC-MoSi2-ZrB2 coating exhibits dense structure and is composed of SiC, Si, MoSi2 and ZrB2. It can protect C/C composites from oxidation at 1773 K for more than 510 h with weight loss of 0.5%. The excellent anti-oxidation performance of the coating is due to the formation of SiO2-ZrSiO4 complex glassy film. The coating can also endure the thermal shocks between 1773 K and room temperature for 20 times with residual flexural strength of 86.1%.     

MO3Si-MO5Si3硅化物中温氧化行为及其机理

研究了Mo3Si-Mo5Si3共晶硅化物在600～1200℃中温氧化行为，分析了中温氧化机理和氧化瘟疫现象。结果表明，在1000℃氧化并发生氧化瘟疫现象的试样中发现在孔洞和裂缝等缺陷处优先生成混合氧化物。这种混合氧化物的体积效应导致pest现象的发生。     

铁磁流体互易性磁致旋光效应的传输特性及数值模拟

对水基铁磁流体在外加磁场作用下的磁致旋光效应的传输特性进行实验和数值模拟研究.在构建铁磁流体纵向磁光效应测试平台的基础上,对铁磁流体在恒定磁场、单个脉冲磁场以及连续方渡脉冲磁场作用下的磁致旋光效应进行了研究.结果表明,铁磁流体对偏振光振动方向的旋转与纵向调制磁场的方向无关;铁磁流体对于快脉冲磁场的响应是一个双指数弛豫过...