Synthesis of Sn-Incorporated Folded Sheets Mesoporous Materials (Sn-FSM-16)

Sn-incorporated folded sheets mesoporous materials (Sn-FSM-16) with various contents of Sn were synthesized by using a mixture of water glass, SnCl₄ and NaOH as starting materials. Hexadecyltrimethyl-ammonium chloride (surfactant) was used to intercalate into the layered silicate. The reaction process was followed by measurements of XRD patterns of intermediates. The Sn-FSM-16 was formed via the following mechanism: (1) layered silicates such as - - and -Na₂Si₂O₅ were formed as intermediates by the calcination of the mixture of the starting materials; (2) the surfactant was intercalated into the layered silicates; (3) the surfactant-silicate complex with hexagonal structure was obtained as a precursor of Sn-FSM-16; (4) the precursor was calcined to decompose the surfactant in the interlayer and was changed to Sn-FSM-16. The structural aspect of Sn in Sn-FSM-16 was studied by XPS profiles of Sn 3d _5/2 and Si_2p, ²⁹ Si MAS NMR and FTIR. The content of Sn in Sn-FSM increased with increasing concentrations of both Sn and NaOH in the starting materials. The surface area of Sn-FSM-16 decreased with an increase of Sn content in Sn-FSM (1160–620 m²/g).     

Alkylation of aldehydes with methanol over titanium oxide catalysts

The methylation of various aldehydes, such as acetaldehyde, propionaldehyde, and phenylacetaldehyde over titanium oxidesupported vanadium oxide was studied under atmospheric pressure and temperatures of 250–400°C. The catalyst properties of titanium oxide can be enhanced only by addition of a fairly small amount of vanadium. High-temperature treatment transforms titanium oxide, the support, from anatase to rutile, which causes the catalysts to lose their catalytic properties. The reactivity of these can be ranked in the following order: acetaldehyde > propionaldehyde > phenylacetaldehyde. The steric effect of the substituted groups in propionaldehyde or phenylacetaldehyde may prevent self-condensation to form oligomers and to give a high selectivity of alkylated products.     

Hydrolysis of human horny cells by alkaline protease: Morphological observation of the process

The interaction of highly purified alkaline protease fromBacillus sp. KSM-K16 with the horny cells of human skin contained in skin grime was directly visualized by electron microscopy. It became clear that the protease first penetrates the horny cells and then adsorbs, mainly onto the internal structure of the cells at the initial stage of hydrolysis, and directly hydrolyzes the keratin filaments, though the marginal band surrounding them retains its original shape. Then, hydrolysate produced from the keratin filaments flows out of the cell, and early in the hydrolysis process keratin filaments decrease and then disappear, leaving a marginal band, i.e., the cell turns to a hollow state. As a result, the remaining marginal band loses support from inside the cell, thus promoting cleavage and dispersion. Until this stage in the protease reaction, the remarkable liberation of hydrolysis products as water-soluble protein does not occur.     

Klebsieila sp．601细菌漆酶的鉴定及性质

从森林树木根部土壤中分离得到一株具有2，6-二甲氧基酚（DMP）和2，2＇-连氮基-双（3-乙基苯丙噻唑啉-6磺酸（ABTS）氧化活性的细菌。Cu^2＋、Ca^2＋、Mn^2＋、Fe^2＋和Mg^2＋可诱导细菌表达活性的胞质可溶性单体酶蛋白。该酶进行DMP或ABTS氧化时需要铜离子的协助，在pH5．0～7．5范围内氧化DMP，在pH4．0～4．5范围内氧化ABTS，但不能氧化酪氨酸。SDS-PAGE估测酶蛋白分子量大约为55kD。经60℃处理4h或pH10条件下透析20h仍能保持酶活性。16S rDNA序列分析结合常规细菌形态学分析，表明该细菌属于克雷伯氏菌（Klebsiella）属，并命名为Klebsiella sp．60l。这是首例报道Klebsiella细菌菌株具有漆酶活性。     

基于Linux+ARM的多格式视频图像采集系统的设计

设计了基于S3C2440微处理器的视频图像采集系统,详细分析了该系统的启动过程。在一块裸板上搭建起整个视频图像采集系统。结合V4L2技术完成了支持YUV、MJPEG图像格式的USB摄像头和支持RGB图像格式的CMOS摄像头的多格式视频图像采集系统。测试结果表明,该系统可以在LCD显示屏上动态显示多格式摄像头所采集到的视频图像,且视频图像具有清晰度高、流畅性好、稳定性强等特点,具有进一步推广使用的广阔前景。     

Implicit Bayesian Inference Using Option Prices

Abstract. A Bayesian approach to option pricing is presented in which posterior inference about the underlying returns process is conducted implicitly via observed option prices. A range of models allowing for conditional leptokurtosis, skewness and time‐varying volatility in returns are considered, with posterior parameter distributions and model probabilities backed out from the option prices. Models are ranked according to several criteria, including out‐of‐sample predictive and hedging performance. The methodology accommodates heteroscedasticity and autocorrelation in the option pricing errors, as well as regime shifts across contract groups. The method is applied to intraday option price data on the S&P500 stock index for 1995. While the results provide support for models that accommodate leptokurtosis and skewness, no one model dominates when all criteria are considered.     

Ultrasonic spray pyrolysis of nano crystalline spinel LiMn2O4 showing good cycling performance in the 3 V range

Spherical lithium manganese oxide spinel was synthesized by an ultrasonic spray pyrolysis method, and has been characterized using X-ray diffraction, scanning electron microscopy, transimission electron microscopy and electrochemical cycling at 3 V regions. The LiMn₂O₄ powders were composed of about 10 nm-sized primary particles. The delivered discharge capacity of the synthesized nano-material was 125 mAh g⁻¹ between 2.4 and 3.5 V and its retention was about 96% upon 50 cycling. From the high resolution transmission electron microscopic study, it was found that structural transition of the parent material did not occur even after the 50th electrochemical cycling on the 3 V region. It seems that the reversible structural change is possible for nanocrystalline LiMn₂O₄ as observed by the X-ray diffraction and transition electron microscopic observations.     

16Mn钢在3％氯化钠水溶液中的阴极保护及其氢脆敏感性

本文用失重法和慢应变率法确定16Mn钢在3％氯化钠水溶液中适宜阴极保护电位区间,用扫描电镜观察慢应变拉伸断口形貌。结果表明:16Mn钢在3％氯化钠水溶液中适宜阴极保护电位区间是:-775mVSCE——-900mVSCE。阴极过保护电位下,16Mn钢将发生以沿晶脆断为特征的氢脆,而且保护电位越负,其氢脆敏感性越大。     

Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

乌苏里江流域TRMM降水数据精度评价与修正

将地面站点观测的降水数据作为基准降水数据,评估汛期热带降雨观测计划(TRMM)降水产品3B42研究型数据(V7)与实时降水数据(RT)的日以及月尺度数据在黑龙江省乌苏里江流域的时空精度。结果表明:在时间尺度上,TRMM 3B42V7与3B42RT的日降水数据与站点降水数据相比,均系统性偏小,且相关性不是很好;相对而言,3B42RT与站点数据的偏差程度较小,相关性较好;月尺度数据与日尺度数据相比,月数据精度均有很大提高,且2种产品数据精度相差不大;在空间尺度上,TRMM 3B42V7和3B42RT都能较好地展现乌苏里江流域降水的空间分布特征。针对评估结果,使用加法和乘法模型对TRMM 3B42V7和3B42RT的月降水数据进行修正。修正后,2种TRMM卫星降水产品的月降水数据精度均有提高,并且加法模型修正效果更好。因此,可选取加法模型修正后的3B42RT月尺度降水数据用于汛期乌苏里江流域的相关水文研究。