高磷鲕状赤铁矿酸浸脱磷动力学

在HSC6.0计算软件热力学分析的基础上,采用正交实验确定了高磷鲕状赤铁矿酸浸脱磷保铁的最佳工艺,并以最佳工艺为基础进行了酸浸过程中脱磷和铁损反应的动力学研究。热力学分析表明H_2SO_4为最佳酸浸用酸。正交实验得出最佳酸浸条件为:H+浓度为0.5mol/L的H_2SO_4溶液、酸浸时间40min、温度298K、液固比200mL∶14g、搅拌速度100r/min。在该条件下,脱磷率可达98.89%,铁损率仅为0.51%。通过SEM-EDS对酸浸前后高磷鮞状赤铁块矿试样分析表征得出:经H_2SO_4浸出后,磷灰石基本完全溶解,含铁矿相未发生明显反应。动力学分析显示:优化条件下,酸浸脱磷反应在298~328K内符合收缩未反应核模型,浸出过程主要受内扩散控制,表观活化能为11.24kJ/mol;铁损反应在298~328K内遵循收缩未反应核模型,浸出过程主要受化学反应控制,表观活化能为42.24kJ/mol。     

四川某高磷鲕状赤铁矿工艺矿物学研究

通过对四川某高磷鲕状赤铁矿进行详细的工艺矿物学研究,查明了该矿石的化学成分、矿物组成、结构构造、主要矿物嵌布特性和有益有害元素的赋存状态,为该矿石的选矿工艺研究提供了依据。     

再生水回用中氮磷对两种典型水华藻类生长影响研究

根据相关标准,试验选取了不同的氮磷浓度值,对蓝藻水华常见的铜绿微囊藻和绿藻水华常见的小球藻分别进行了单独培养以及两者的竞争试验.结果表明,铜绿微囊藻生长的最适氮磷浓度分别为15 mg/L、0.3～0.5 mg/L,小球藻生长的最适氮磷浓度分别为15 mg/L、0.1～0.5 mg/L;在氮磷比为15、30、50、150的试验条件下,竞争试验中的优势藻均为小球藻.建议以再生水为补水水源的景观水体中,再生水的氮磷浓度分别控制为:总氮≥15 mg/L、磷≤0.1 mg/L、氮磷比为150以上,能有效地抑制铜绿微囊藻生长.     

普光气田鲕滩储层形成的物质基础和保存成因

通过岩心和薄片观察,普光气田飞仙关组飞一到飞三段并不发育石膏,储层中H2S溶蚀作用的标志也不多见,相对于H2S,鲕滩储层的发育与其原岩鲕粒灰岩关系更密切。鲕粒灰岩本身发育原生粒间孔,经大气水溶蚀后也可以形成较好的储层,是普光气田鲕滩储层形成的物质基础。飞仙关期鲕滩的加积作用、飞仙关组早期快速埋藏和烃类充注的匹配、飞仙关组的构造托举和上覆雷口坡和嘉陵江组的膏盐悬浮减压,构成了原生粒间孔、同生期溶孔和晶间孔的保存成因。早期孔隙网络的发育和良好的保存成因,为后期埋藏溶蚀流体的出入提供了良好的条件,最终演化成了优质储层。     

扬水曝气技术在河道型深水水库水质原位修复中的应用

以西安市地表饮用水水源—黑河金盆水库为研究对象,采用扬水曝气技术修复其受污染原水水质。结果表明,该项技术应用于大水深水库水质原位修复改善是可行、有效的;在扬水曝气器混合充氧作用影响下,金盆水库季节性缺氧/厌氧状况得到遏制,底泥表层DO浓度均维持在2mg/L以上;沉积物中氮、磷、有机质等内源释放过程明显减弱,藻类繁殖生长受抑;出水水质中TP、NH3—N、CODMn、叶绿素a等指标浓度较2008年同期分别削减46.7%、69.5%、22.4%及53.6%,水质改善效果明显。     

基于Gassmann方程的鲕滩储层流体替换模拟技术及其应用

基于单井资料的储层地震响应模拟和流体识别大多采用褶积模型,但对于复杂地质模型,采用褶积模型模拟的波场动力学特征不明显。提出了基于Gassmann方程的流体替换波动方程模拟技术,从波动方程角度刻画了复杂鲕滩储层模型的地震响应。该方法利用Gassmann等效介质理论,对鲕滩储层实现由干岩石到有效孔隙饱和岩石的替换,由已知预测未知;之后通过建立鲕滩薄互层模型和薄互层楔形体模型,正演模拟了鲕滩储层含气后的地震响应,地震响应表现为“亮点”特征。     

川东飞仙关组鲕滩气藏控制因素及其储集条件研究

根据川东地区飞仙关组已钻资料,对飞仙关组的鲕滩气藏控制因素及储集条件进行了研究。研究表明:飞仙关组的鲕滩气藏控制因素为沉积相、白云石化作用和埋藏溶解作用;从飞仙关组的鲕滩气藏储集条件看,鲕滩气藏多为构造圈闭气藏,保存条件良好。飞仙关组鲕滩气藏成藏条件的关键因素是储层与圈闭。在以上研究的基础上,综合沉积相、成岩相、烃类运聚优势相、局部构造、钻井显示和油气测试结果等因素,对川东的北部地区进行了有利区带预测和划分,即环开江—梁平海槽外缘分布的川东碳酸盐连陆台地边缘鲕粒滩发育区、环开江—梁平海槽内缘分布区是川东飞仙关组鲕滩气藏有利分布区。     

Effects of algal hydrolyzate as reaction medium on enzymatic hydrolysis of lignocelluloses

Effects of an algal hydrolyzate on the enzymatic hydrolysis of lignocelluloses were examined using four bioenergy feedstocks (poplar, corn stover, switchgrass, and anaerobically digested manure fiber). Feedstocks were pretreated using dilute acid or alkali prior to hydrolysis. Hydrolysis reactions were conducted using the neutralized algal hydrolyzate, citrate buffer, or deioinized water as reaction media. Results demonstrated that algal hydrolyzate significantly improved the efficiency of enzymatic hydrolysis of lignin-rich or structurally recalcitrant biomass such as poplar and anaerobically digested manure fiber. This study showed that algal biomass can be used as not only a biofuel feedstock for direct diesel and ethanol production, but also a supplemental feedstock to enhance the performance of lignocellulosic biorefining.     

Reconstruction of Windermere Sewage-Treatment Works

This sewage-treatment works, which is located within the Lake District National Park, on the shores of England's largest lake, receives flows from the villages of Windermere, Bowness and Troutbeck and serves a population which can double from winter to summer.
The paper describes the logistical and other aspects of undertaking construction works within the confines of an existing site whilst maintaining treatment to incoming flows. The background and regulatory influences on the design of the scheme are covered, together with details of the new treatment units and the provision of facilities to strip phosphate from the effluent.     

Magnetizing roasting mechanism and effective ore dressing process for oolitic hematite ore

Magnetizing roasting of oolitic hematite ore from western Hubei Province was investigated.The mechanism for reduction roasting of oolitic hematite ore was discussed and analyzed.It is found that flash magnetizing roasting-magnetic separation process is a promising approach for the processing of oolitic hematite ore from western Hubei Province.