La_2O_3掺杂(Bi_(0.5)Na_(0.5))_(0.94)Ba_(0.06)TiO_3陶瓷的介电和压电性能的研究

用固相反应法制备La2O3掺杂的铁电陶瓷(Bi0.5Na0.5)0.94Ba0.06TiO3(BNBT6)。X射线衍射曲线表明掺杂0-0.6wt%La2O3的BNBT6为钙钛结构。研究了La2O3掺杂对BNBT6陶瓷介电性能和压电性能的影响。结果表明La2O3掺杂量为0.3wt%的BNBT6陶瓷综合性能最佳,其中介电常数为1981.4,介电损耗为0.0625和压电常数为145pc/N。SEM图象表明La2O3掺杂提高了陶瓷的致密度。     

工程陶瓷超高速磨削过程的动力学特性分析

在设计转速为314 m/s的超高速磨削试验台上, 比较研究了氧化锆和氧化铝材料在不同磨削条件下的磨削过程,得到了如下主要研究结果:(1)不能单以振动强度大小判断磨削过程的稳定性和工件表面磨削质量的优劣,而需要结合陶瓷材料力学性能、材料去除机理、砂轮磨粒和接触刚度等因素综合考虑;(2)磨削过程可激发机床的高阶固有频率模态振动;该振动频率远高于主轴转动频率,且与主轴转频无明显的倍速关系;(3)在较低速度时,由于磨削粘性及电动机低速转矩特性原因,磨削过程可能不稳定,从而导致工件表面质量下降;随着砂轮线速度的增加,强迫振动占主导地位,但由于砂轮动平衡精度高,实际振幅小,磨削过程稳定,工件表面质量反而提高;当磨削速度进一步提高时,受机床结构刚度的限制,工件表面质量又呈下降趋势.     

Development of waste derived nano-lakargiite bonded high alumina refractory castable for high temperature applications

This work provides a new binder system, i.e., nano-lakargiite (NL) [CaZrO₃] for unshaped refractories. NL powder formulation is done through a green and facile route, i.e., solution mixing technique, which is easily capable of recycling the byproducts. The waste eggshells are practiced as a source of CaO for the preparation of NL. The characteristics such as differential thermal/thermogravimetric (DTA-TGA) analysis, X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM) of the synthesized NL powder are accomplished. The single phase orthorhombic crystal structure with the Pnma space group of nano CaZrO₃ (avg. crystallite size ∼19 nm) is attained at 1100 °C. High alumina castable specimens are formulated through the replacement of calcium aluminate cement (CAC) by the NL and heat treated at 1600 °C. The different physico-mechanical properties of the prepared castables are comprehensively investigated. The corrosion resistance in the molten glass at 1400 °C is also examined. The properties are also equated with the different advanced bonding systems of high alumina refractory castables. Significant progress in terms of densification, hot strength, and thermal shock resistance is achieved for the NL bonded refractory castables.     

EDXRF应用于古陶瓷科技鉴定的实验条件探讨

能量色散X射线荧光分析法(EDXRF)是目前古陶瓷科技鉴定中应用最广泛的成分测试技术之一。在应用该法进行古陶瓷科技鉴定时,由于不同研究者所选择的分析测试条件不同,测试数据会出现一定的差异性,严重的甚至导致截然相反的结论。有鉴于此,本文对EDXRF应用于古陶瓷科技鉴定的实验条件进行了分析探讨,为建立统一的测试标准,实现数据的通用性打下基础,以提高成分鉴定法的准确度和可信度。     

Ti_3SiC_2及其复合材料的研究现状及发展趋势

介绍了Ti3 SiC2陶瓷材料的微观结构与性能,认为该材料良好的综合性能有望解决 陶瓷材料的脆性问题。并概述了Ti3SiC2及Ti3SiC2基复合材料各种制备方法的特点和研究状 况、应用前景和发展趋势。     

微晶玻璃——陶瓷复合曲面板生产工艺研究

通过研究微晶玻璃陶瓷复合材料在高温下软化流动的特征和晶粒相对位移的特点论述了复合平板加热、加压弯曲过程中的温场分布规律,制定出合理的温度制度,使复合板微晶表面和坯体在合理的温度制度、温场分布制度使两者同步弯曲成为设计的曲面。     

High temperature dielectrics in the ceramic system K0.5Bi0.5TiO3-Ba(Zr0.2Ti0.8)O3-Bi(Zn2/3Nb1/3)O3

Ceramics in the system (1-x)[0.5K_0.5Bi_0.5TiO₃-0.5Ba(Zr_0.2Ti_0.8)O₃]-xBi(Zn_2/3Nb_1/3)O₃ have been fabricated by a solid-state processing route for compositions x≤0.3. The materials are relaxor dielectrics. The temperature of maximum relative permittivity, T_m, decreased from 150 °C for composition x=0, to 70 °C for x=0.2. The x=0.2 sample displayed a wide temperature range of stable relative permittivity, ε_r, such that ε_r=805±15% from −20 to 600 °C (1 kHz). Dielectric loss tangent was ≤0.02 from 50 °C to 450 °C (1 kHz), but due to the tanδ dispersion peak, the value increased to 0.09 as temperatures fell from 50 °C to −20 °C. Values of dc resistivity were of the order of ~10⁹ Ω m at 300 °C. These properties are promising in the context of developing new high temperature capacitor materials.     

陶瓷材料与结构增材制造技术研究现状

增材制造技术在聚合物材料与结构、金属材料与结构制备中已经得到了大量应用。近年来,陶瓷材料与结构的增材制造技术得到了初步发展,受到了越来越多陶瓷工作者的关注。本文综述了目前几种常见的陶瓷材料与结构增材制造技术,并预测了未来陶瓷材料与结构增材制造技术发展的主要关注点,以期为陶瓷工作者提供关于增材制造技术一定的参考与思考。     

不同介质中Si3N4陶瓷的静疲劳与循环疲劳

系统研究了Si3N4陶瓷在空气、水、煤油3种介质中的静疲劳及循环疲劳特性。结果发现，在不同介质条件下，循环疲劳的应力腐蚀指数(n)相差不大，且远远低于相同介质条件下静疲劳的应力腐蚀指数。经分析发现，循环载荷部分或全部消除了显微组织屏蔽作用，对材料造成附加损伤，导致其疲劳寿命远远低于静疲劳寿命。     

Ceramic wear maps

Ceramic wear maps have been developed to elucidate the complex interactions of the operating parameters, environments, and wear mechanisms. This paper summarizes these interactions for four ceramics, alumina, yttria-doped zirconia, silicon carbide and silicon nitride. Wear maps of these ceramics are systematically constructed using measured data under dry sliding, water, and paraffin lubricated conditions. For each material, different wear level regions acid wear transition zones are identified as a function of operating conditions and lubrication conditions. Wear mechanism studies performed within each wear region give rise to the wear mechanism maps. These maps facilitate material comparison and selection. The knowledge of wear, wear transitions, and wear mechanisms for a material pair enables realistic wear model development. One outcome of this approach is the recognition that a single wear model for a material pair cannot cover all operating conditions and environments.

As wear maps are constructed today, they are material pair specific. Within a material pair, there are microstructural dependence and surface properties influence. These parameters can change substantially for a given chemical composition of the material. How to incorporate these factors into the wear map research remains an issue. The search for a universal parameter such as the “asperity temperature” in Ashby's wear map continues in spite of mounting evidence that this may not be practical or feasible. But the hope remains that some parameters can be identified to normalize a large number of materials, operating conditions, and environments for tribological applications. Systematic wear maps are the first steps in this direction.