锆钡镧铝氟化物玻璃的分相研究

本文综述了氟化物玻璃中的分相研究。在前人研究基础上应用透射电镜，X射线能谱，电子能量损失谱及X射线衍射，差热分析等研究了锆钡镧铝氟化物玻璃中的液-液分相，发现此种现象普遍存在于该类玻璃之中。对玻璃成分与分相形貌及微观结构之间的关系、对析出晶相种类及分相与析晶的相互影响进行了研究。提出欲降低氟化物玻璃的光损耗，分相与析晶一样是不容忽视的因素。     

不用专门相移装置的三维面形测量

提出一种不需要专用相移装置实现相移，主要利用数字图像处理技术实现三维面形测量的方法，研究结果表明，用原干涉图像及1幅以上的移值条纹图主可能实现物体三维面形的测量。     

Experimental investigation of the normal spectral emissivity and other thermophysical properties of pulse-heated Ni-Ti and Au-Ni alloys into the liquid phase

1. Introduction Metal working industry needs accurate thermo- physical properties of liquid metals and alloys as input data for different simulation routines to im- prove the performance of their products. Within this paper we continue the systematic investigation of the dependence of emissivity of binary alloys on the relative concentration of the constituent elements (for a previous paper see [1]). 2. Experimental method A fast ohmic pulse heating technique is applied to heat metallic wire-s…     

Phase Composition of Oxide Scales during Reheating in Hot Rolling of Low Carbon Steel

Low carbon steel was oxidized over the temperature range 1000‐1250°C in O₂‐CO₂‐H₂O‐N₂, O₂‐H₂O‐N₂, and O₂‐CO₂‐N₂ gas mixtures. Oxidation times were 12‐120 min. and the scales were 50‐2000 μm thick. The variations of these parameters were chosen to elucidate the phase composition of oxide scales under conditions similar to those of reheating furnaces in hot strip mills, using either thin slab casting or conventional casting and rolling technology. Two types of scales have been observed which are influenced by the furnace atmosphere, oxidation time, and temperature. The first type is a crystalline scale with an irregular outer surface, composed mostly of wustite (FeO), and a negligible amount of magnetite (Fe₃O₄). The second type is the classical three‐layer scale, composed of wustite (FeO), magnetite (Fe₃O₄), and hematite (Fe₂O₃). In general, the experiments showed that an increase in oxidation time decreased the percentage of wustite while the percentages of magnetite and hematite increased. A rise in oxygen concentration in the gas mixture increased the percentages of magnetite and hematite, confirming earlier experimental findings. In water vapour‐free atmospheres O₂‐CO₂‐N₂, the oxide scales had a low percentage of wustite, and high percentage of magnetite and hematite. Carbon dioxide showed a small influence at 1100°C, and a negligible one at 1250°C.     

Thermodynamic state of reinforced interpenetrating polymer networks

The free energies of mixing of two networks in the interpenetrating polymer network based on crosslinked polyurethane and poly(ester acrylate) have been determined by the vapour sorption method. It was established that the constituent networks in the IPN are not miscible. The introduction of fillers of different chemical nature increases the compatibility. The thermodynamic affinity of the fillers to the individual networks and IPN was estimated. It was established that when the free energy of interaction of one or both components of the IPN with the filler is negative, reinforcement leads to the formation of a compatible and equilibrium system. For fillers having no affinity to the polymers, compatibilization is observed, which is connected with slowing down of phase separation in the system in the presence of filler.     

Liquid phase epitaxial growth of pure and doped GaSb layers: morphological evolution and native defects

Undoped and Te-doped gallium antimonide (GaSb) layers have been grown on GaSb bulk substrates by the liquid phase epitaxial technique from Ga-rich and Sb-rich melts. The nucleation morphology of the grown layers has been studied as a function of growth temperature and substrate orientation. MOS structures have been fabricated on the epilayers to evaluate the native defect content in the grown layers from theC-V characteristics. Layers grown from antimony rich melts always exhibitp-type conductivity. In contrast, a type conversion fromp- ton- was observed in layers grown from gallium rich melts below 400 C. The electron mobility of undopedn-type layers grown from Ga-rich melts and tellurium doped layers grown from Sb- and Ga-rich solutions has been evaluated. Paper presented at the poster session of MRSI AGM VI. Kharagpur. 1995     

Effect of Annealing on the Surface Microstructure of Y-Ba-Cu-O Superconducting Ceramics

Precusors to the YBa₂Cu₃O_7-δ material were prepared by both the oxalate precipitation method and conventional ceramic processing. Second-phase grains were observed to develop on the exposed fracture surface during annealing at 500° to 600°C in an ambient atmosphere. The second-phase grains were identified to be BaCO₃ using EDX and XRD. The liquid phase, which was formed because of local chemical inhomogeneity in the Y-Ba-Cu-O system, contributed to the formation of second-phase grains as a source of Ba.     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

The application of microencapsulated phase‐change materials to nylon fabric using direct dual coating method

The fabrication of functional textiles able to provide thermal regulation and comfort for the body has attracted increasing interest in recent years. This research investigated fabric coatings containing energy absorbing, temperature stabilizing, phase‐change material microcapsules (PCMMcs), and their methods of application. Specifically, a coated fabric was directly prepared by a dual‐type coating method, in which the PCMMcs were dispersed in a polyurethane coating solution with no binder. The thermal performances of the dual‐coated samples were evaluated by differential scanning calorimetry, and their physical characteristics were examined by scanning electron microscopy, thermal vision camera, porosity, water vapor transmission rate (WVTR), and water entry pressure (WEP) analyses. Furthermore, the microclimate characteristics of the thermally enhanced fabrics were investigated under experimental conditions using a human‐clothing‐environment (HCE) simulator system. The study results confirmed the superior performance of the dual‐coated fabrics in terms of thermal regulation and body comfort, compared with those coated by the dry or wet coating method, because of the improved WEP, WVTR, and thermal performance. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008