Characterization of FeS2-pyrite thin films synthesized by sulphuration of amorphous iron oxide films pre-deposited by spray pyrolysis

FeS₂-thin films with good crystallinity were synthesized by a simple method which consists of sulphuration, under vacuum, of amorphous iron oxide thin films pre-deposited by spray pyrolysis of FeCl₃·6H₂O (0.03 M)-based aqueous solution onto glass substrates heated at 350 °C. At optimum sulphuration temperature (450 °C) and duration (6 h), black green layers having granular structure and high absorption coefficient (5.10⁴ cm⁻¹) were obtained. The study of the electrical properties of the as-prepared films vs. the temperature variations showed three temperature domain dependence of the conductivity behaviour. The first one corresponds to the high temperature range (330 K–550 K) for which an Arrhenius plot type was obtained. The activation energy value was estimated at about 61.47 meV. The second domain corresponding to the intermediate temperature range (80 K–330 K) showed a variable activation energy between the grain boundaries. The barrier height, q¯, was estimated to 27±0.5 meV, and the standard deviation, qσ, was evaluated at about 14±0.5 meV. We found that at lower temperatures (20 K–80 K), the conductivity is governed by two conduction types. The density of localised states, was about 2.45×10²⁰ eV⁻¹ cm⁻³.     

Processing of Net‐shaped Nanocrystalline Fe‐Ni Material

Development of nanoparticulate materials technology is essential to processing of highly functional nanoparticulate materials and components with small and complex shape. This paper provides an overview on our recent investigations on the processing of net‐shaped nanocrystalline Fe‐Ni powder and related material property such as mechanical property. The key‐processing concept is the synthesis of nanopowders and subsequent consolidation with controlled microstructure by using powder injection molding (PIM) process. Especially, the pressureless sintering process is inevitable for consolidation of the PIMed nanopowder. The present review focuses on the densification process and related mechanical property of the PIMed Fe‐Ni nanopowder in association with microstructural evolution and diffusion process.     

4πβ-4πγ符合外推法测量59Fe比活度

将小型4πβ流气式正比计数器置于大体积4π γNaI(T1)探测器中，组成4πβ-4πγ符合装置，采用效率外推法测量了^59Fe溶液的比活度．研究γ道探测效率很高时符合外推法活度测量准确度的改善情况。结果表明，γ道探测效率的提高，显著减少了活度测量的统计不确定度，有效地缩短效率外推全过程的时间，因此适用于较短寿命放射性核素活度的测量。     

Fe_2O_3基陶瓷的气湿敏特性

论述了由不同制备工艺获得的Ｆｅ２Ｏ３陶瓷及各种添加剂下表面羟基和吸附氧的形成和性质，分析了表面羟基和吸附氧的酸碱性对气湿特性的影响。     

利用新的指示反应褪色光度法测定微量铁的研究及应用

研究了在ｐＨ５．７－６．２的丙二酸介质和Ｔｗｅｅｎ－８０存在的条件下，间苯二酚酞与Ｆｅ的褪色反应的适宜条件。建立了一种光度的的新方法，可测定０－１６．０μｇ／２５ｍＬ范围内的铁，表观摩尔吸光系数为９．６×１０＾４，用于茶叶及酒样中铁的测定，结果令人满意。     

空心超顺磁性Fe3O4纳米微球的制备与表征

利用聚氧乙烯-聚氧丙烯-聚氧乙烯嵌段共聚物F127作为模板采用共沉淀法制备了空心超顺磁性Fe3O4纳米微球并用X射线衍射(XRD)和透射电子显微镜(TEM)进行了表征，纳米微球的大小为55-75nm，壳的厚度为7nm左右，颗粒大小均匀、在水溶液中分散良好．     

贵州水城观音山铁矿成矿构造体系分析

文章应用地质力学的理论和方法，通过对贵州水城观音山铁矿区内结构面力学性质的鉴定，将区内构造形迹划分为三种类型的构造体系，并在此基础上，通过对矿区内矿床的控矿构造型式进行分析，确立了属于威宁弧形构造的北西构造带为成矿期构造体系。     

The Effect of the Thickness of Fe2 Al5 Phase Layer at Fe/Al Interface on the Mechanics Behavior of Hot Dip Aluminizing Coating

Hot Dip Aluminized Coatings with different thickness were prepared on Q235 steel in aluminum solutions with different temperature for certain time. Through tensile tests and in-situ SEM observations, the effect of the coating's microstructure on the tensile strength of the samples was studied. It was disclosed at certain aluminum solution temperature,transaction layers mainly composed of Fe2 Al5 phase got thicker with time prolonging, and this changed initial crack's extending direction from parallel with to vertical with stretching direction. The change in crack direction decreased tensile strength of samples, thus made the coating easy to break. It was concluded that the existence of thick Fe2 Al5 phase layer was the basic reason for the lowering of tensile strength of the coating.     

Spark Plasma Sintering Bulk Sm2 Fe17NxMagnets

High performance Sm2Fe17Nx magnetic powders were fabricated by ball-milling method and were compacted using spark plasma sintering(SPS) technique.Effects of processing conditions on the magnetic properties and decomposition dynamic of the magnets were investigated.It is found that higher sintering temperature improves the densification of the magnets, while deteriorates their magnetic properties simultaneously due to the decomposition of the Sm2Fe17Nx.Sintering at lower temperature can preserve the crystal structure of Sm2Fe17Nx compound, while the powders cannot be consolidated into a fully dense compact.An increased compressive pressure leads to better magnetic properties and higher density for the magnet at the same sintering temperature.     

流动注射悬浮液脉冲进样--火焰原子吸收光谱法测定中草药生地中的铁和锌

以流动注射悬浮脉冲进样－火焰原子吸收光谱法进行了中草药生地中铁和锌元素的测定，生地被干燥，粉碎，过筛后加入琼脂溶液制成悬浮液，然后用流动注射脉冲送入雾化器。实验考察了仪器工作条件，样品悬浮液制备和方法的准确性，用标准加入法测定，该法简便，快捷，测定结果与灰化法一致。