红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

快速高吸油性丙烯酸酯树脂的合成研究

以丙烯酸丁酯与甲基丙烯酸甲酯为共聚单体，在聚合体系中引入致孔剂和大分子增容剂，采用悬浮聚合法合成了快速高吸油性树脂，考察了致孔剂用量、增容剂用量、乙酸乙酯／异戊醇混合致孔剂质量比等对高吸油性树脂吸油性能的影响。结果表明：通过引入致孔剂乙酸乙酯，不仅使树脂对甲苯和汽油的吸油率分别达到了3300％和1000％，而且吸油速度加快，2h内可达到饱和吸油；在致孔的基础上引入增容剂，可使树脂对汽油的吸收率显著提高，达到了1500％。     

聚丙烯工程化研究

采用纳米填充、交联和转晶的复合技术对聚丙烯进行了改性，优选了纳米碳酸钙为填料。当β成核剂用量为0．5％、助交联剂为3％时，复合材料的综合性能达到最好，接近普通工程塑料的各项力学性能。红外光谱分析和熔体质量流动速率的测定表明，复合材料体系产生了微交联；DSC分析发现，PP材料的聚集态结构中含有β球晶。     

高精度冷轧不锈钢管生产

介绍了用ＬＤ型冷轧管机生产高精度冷轧不锈钢管的经验和质量保证措施。     

High temperature corrosion mechanisms and effect of alloying elements for materials used in waste incineration environment

Corrosion products on two typical materials, SA213-T12 steel and alloy 625 exposed to the actual combustion gas, were analyzed in addition to laboratory tests for penetration of corrosive matter. It has been clarified that corrosion products of oxides containing a little chlorides and sulphides show lamellar structures and that at the alloy-scale interface, chlorination, sulphidation, and oxidation occur under a low P_O2-high P_Cl2 condition. The formation of scale structures and the effect of corrosion-resistant alloying elements can be explained according to the stability tendencies of metals, chlorides, and oxides in the M-Cl-O equilibrium diagrams. The severity of corrosion environments at the interface is influenced by the penetration extent of corrosive matters through deposits and scales, and the protective effects of oxide films derived from alloying elements play an important role in preventing the corrosion. On the other hand, it has been shown that thermal fluctuation characterized in this kind of environment makes the lamellar scale structures and sometimes breaks and peels off the scale, and thus accelerates the corrosion. On the basis of the above mentioned knowledge, a new corrosion model is presented.     

高钒高速钢碳化钒形态的数值化分析

针对碳化钒的不同形态,设计出定量分析软件,并利用形状因子K,实现了高钒高速钢不同碳化物形态数值化处理,当K介于0.785～1.000之间碳化钒形态为团球状;K≤0.223,碳化钒呈开花状.高钒高速钢当碳含量达到4.2%时,K为0.86和当量直径D为0.78μm,碳化物呈团球状均匀分布.     

Effects of electrical discharge surface modification of superalloy Haynes 230 with aluminum and molybdenum on oxidation behavior

The effects of the electrical discharge alloying (EDA) process on improving the high temperature oxidation resistance of the Ni-based superalloy Haynes 230 have been investigated. The 85 at.% Al and 15 at.% Mo composite electrode provided the surface alloying materials. An Al-rich layer is produced on the surface of the EDA specimen alloyed with positive electrode polarity, whereas, many discontinuous piled layers are attached to the surface of the EDA superalloy when negative electrode polarity is selected. The oxidation resistance of the specimen alloyed with positive electrode polarity is better than that of the unalloyed superalloy, and the effective temperature of oxidation resistance of the alloyed layer can be achieved to 1100 °C. Conversely, the oxidation resistance of the other EDA specimen alloyed with negative electrode polarity is even worse than that of the unalloyed superalloy.     

基于气动技术的高空擦玻璃机器人研究

研制了气动高空擦玻璃机器人,该机器人包括产生真空吸附功能的气动真空模块,用于实现类似于四足动物爬行的爬行模块,用于擦拭玻璃的擦拭模块,以及对以上所述模块进行控制的控制模块。它能实现在高层建筑物的玻璃外墙进行攀爬,同时对墙体进行彻底擦洗。     

基于贝叶斯的服务通告改装经济性决策方法

改装类服务通告的经济性决策是航空维修企业工程人员的一项重要工作内容。设计了改装类服务通告经济性决策程序;通过服务通告对飞机运营的经济性影响分析构建了成本分解结构,并对不同的成本项目建立了成本评估模型;针对模型的成本影响参数MTBUR和MTBF的估计采用了贝叶斯方法以解决小样本问题;通过投资回收期方法获得评价指标以决定是否进行服务通告改装投资。最后通过实例对决策方法的应用进行说明。此方法能够为航空企业的维修改装决策提供有效的技术支持。