全文获取类型
收费全文 | 22225篇 |
免费 | 1465篇 |
国内免费 | 463篇 |
专业分类
电工技术 | 118篇 |
综合类 | 999篇 |
化学工业 | 13352篇 |
金属工艺 | 330篇 |
机械仪表 | 401篇 |
建筑科学 | 452篇 |
矿业工程 | 341篇 |
能源动力 | 232篇 |
轻工业 | 1861篇 |
水利工程 | 34篇 |
石油天然气 | 1521篇 |
武器工业 | 63篇 |
无线电 | 522篇 |
一般工业技术 | 2936篇 |
冶金工业 | 198篇 |
原子能技术 | 151篇 |
自动化技术 | 642篇 |
出版年
2024年 | 84篇 |
2023年 | 226篇 |
2022年 | 312篇 |
2021年 | 416篇 |
2020年 | 420篇 |
2019年 | 488篇 |
2018年 | 436篇 |
2017年 | 557篇 |
2016年 | 577篇 |
2015年 | 636篇 |
2014年 | 1006篇 |
2013年 | 1157篇 |
2012年 | 1385篇 |
2011年 | 1490篇 |
2010年 | 1157篇 |
2009年 | 1264篇 |
2008年 | 1172篇 |
2007年 | 1420篇 |
2006年 | 1514篇 |
2005年 | 1272篇 |
2004年 | 1109篇 |
2003年 | 1023篇 |
2002年 | 782篇 |
2001年 | 706篇 |
2000年 | 621篇 |
1999年 | 590篇 |
1998年 | 451篇 |
1997年 | 385篇 |
1996年 | 249篇 |
1995年 | 238篇 |
1994年 | 223篇 |
1993年 | 214篇 |
1992年 | 156篇 |
1991年 | 101篇 |
1990年 | 60篇 |
1989年 | 69篇 |
1988年 | 31篇 |
1987年 | 21篇 |
1986年 | 14篇 |
1985年 | 27篇 |
1984年 | 27篇 |
1983年 | 22篇 |
1982年 | 27篇 |
1981年 | 2篇 |
1980年 | 6篇 |
1978年 | 1篇 |
1951年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
The ring-opening polymerization of hexamethylcyclodisilazane (D2NMe), initiated by methyl triflate in 1,2-dichloroethane, forms in the first, fast kinetic step both linear polymer and cyclic dimer (D4NMe). Subsequently a slow depolymerization process occurs leading to exclusively cyclotrisilazane (D3NMe). On the basis of kinetic measurements carried out using an adiabatic calorimetric technique and complementary experiments, mechanisms of both propagation, cyclization and back-biting reactions are proposed. The influence of the reaction temperature was also studied; it is demonstrated that, at low temperature, polymerization does not lead to cyclic oligomer formation. In such conditions, the polymerization presents a ‘living’ character. 相似文献
52.
53.
Emulsifying Capacity and Emulsion Stability of Soy Proteins Compared with Corn Germ Protein Flour 总被引:1,自引:0,他引:1
Both emulsifying capacity (EC) and emulsion stability (ES) increased with increasing concentrations from 0.4% to 0.8% of soy flour (SF), soy concentrate (SC), soy isolate (SI) and corn germ protein flour (CGPF) when studied by response surface methodology. EC and ES increased as pH increased from 6 to 8 in all samples. Increasing incubation temperatures of protein solutions from 20–70°C or from 4–20°C did not affect EC or ES, respectively. SF had the highest EC, followd by SI, SC, and CGPF. 相似文献
54.
Mudadi Albert Nhamoiesu Benhura & Cathrine Katayi Chidewe 《International Journal of Food Science & Technology》2004,39(5):579-583
Polysaccharide was isolated from Cordia abyssinica and its effect, at differing concentrations, on its emulsifying ability was determined. Emulsions of vegetable oil containing up to 1% of the polysaccharide in phosphate pH 7.4 buffer, were prepared by using a hand piston homogenizer. Emulsification was assessed by diluting samples of the emulsions in sodium dodecyl sulphate and measuring absorbance at 500 nm. Addition of increasing concentrations of the polysaccharide up to 1% enhanced emulsification and emulsion stability. Above 1% concentration the polysaccharide solutions were too viscous for making emulsions conveniently. At a constant concentration of the polysaccharide, addition of up to a 1% concentration of salt enhanced emulsion formation. Further addition of salt above 1% resulted in no further changes in emulsifying ability, but the stability of the emulsions formed decreased on increasing the concentration of salt above 1%. The effect of pH on emulsifying ability was investigated by preparing emulsions using buffers of different pH, from pH 3 to pH 13. The polysaccharide had poor emulsifying ability below pH 7. Emulsifying ability increased with pH between pH 7 and 11. At pH above 11 there was a decrease in emulsifying ability. 相似文献
55.
56.
用两亲聚合物制备大颗粒苯丙乳液 总被引:10,自引:0,他引:10
分别以两亲聚合物P(C9-AA)和P(DCPD-St-α-St-AA)作乳化荆,研究了制备大颗粒(约1μm)及具有一定稳定性的苯丙乳液的方法,讨论了乳化剂,温度及引发剂用量对乳液性能的影响。结果表明,以P(C9-AA)作乳化剂时,引发剂用量为单体质量的1.2%,90℃时可以合成性能良好的苯丙乳液;以P(DCPD-St-α-St-AA)作乳化荆时,引发剂用量为单体质量的1.2%,80℃时可以合成性能良好的苯丙乳液。 相似文献
57.
Bionanoparticles of starch obtained by submitting native potato starch granules to acid hydrolysis conditions. The resulted starch nanoparticles were used as core or macro initiator for polymerization of ε‐caprolactone (CL). Starch nanoparticle‐g‐polycaprolactone was synthesized through ring‐opening polymerization (ROP) of CL in the presence of Sn(Oct)2 as initiator. The detailed microstructure of the resulted copolymer was characterized with NMR spectroscopy. Thermal characteristic of the copolymer was investigated using DSC and TGA. By introducing PCL, the range of melting temperature for starch was increased and degradation of copolymer occurred in a broader region. X‐ray diffraction and TEM micrographs confirmed that there was no alteration of starch crystalline structure and morphology of nanoparticles, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
58.
Associations (dimer or aggregate) of anthracene (An) fluorophores tend to interrupt the monomer emission and reduce the quantum yield (ΦPL); therefore, poly(methyl methacrylate) (PMMA) chain was used in this study to chemically link to anthracene and to block the mutual associations among the anthracene fluorophores. With this aim, the target polymers were prepared by anionic polymerizations with 9,10‐dibromoanthracene/s‐butyllithium as initiating system to proceed polymerizations of methyl methacrylate (MMA) directly or in the presence of 1,1‐diphenylethylene (DPE). Use of DPE before addition of MMA produces stable initiating anionic species and avoids potential side reactions during polymerization; however, it also introduces four β‐phenylene rings around the central anthracene ring, which interfere with the corresponding emission pattern and reduce the ΦPL (32%) value due to potential interactions between phenylene rings and anthracene. On the contrast, polymerization without participation of DPE results in polymer with central anthracene ring directly connected to two PMMA chains, which gives clean vibronic emission pattern with limited association emissions and enhanced ΦPL (52%) value. Physical blending of anthracene by PMMA is less efficient to restrain the associations and results in a film of lower ΦPL (20%). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
59.
Branched polyacrylonitrile (PAN) was prepared through a self‐condensing vinyl copolymerization of acrylonitrile and 2‐(2‐bromopropionyloxy)ethyl acrylate (BPEA). The branched architecture of the product was confirmed by NMR spectra and the average degree of branching (DB ) was estimated. Through a comparison of the intrinsic viscosity of the product with that of its linear analogue, the contraction factor g′ was calculated. It was found that the viscosity of the branched PAN was obviously lower that that of linear PAN. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
60.
Environmentally responsive hydrogels have become attractive research subjects for many applications. In this work, a series of pH‐sensitive and color‐changing nanoparticles (nanogels) with core–shell structures were synthesized. The cores were blue latex particles synthesized by a miniemulsion technique with styrene and methacrylic acid as monomers and Neozapon Blue 807 as a dye. The shell was a pH‐sensitive polymer that was precipitation‐polymerized onto the core from 2‐(diethylamino) ethyl methacrylate with N,N′‐methylenebisacrylamide, poly(propylene glycol) diacrylate, and divinylbenzene as crosslinking agents. In the resultant latexes, the color was observed to change from deep blue to pale blue as the pH of the system was changed from a high of 10 to a low of 3. The synthesized latexes and particles (gels) were then characterized with an ultraviolet–visible spectrometer, dynamic light scattering, Fourier transform infrared, and nuclear magnetic resonance. Atomic force microscopy was also used to investigate the different morphologies of the particles after the synthesized latexes were dried at different pH values. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献