模拟多孔介质中质量输运现象有限颗粒法的应用

有限颗粒法是一种新的颗粒跟踪法,特别适合模拟污染物的运移过程。用有限颗粒法对多孔介质中纵向弥散度进行识别。纵向弥散度是表征含水层中介质弥散特征的重要参数．也是一个很难确定的参数。给出具体算例,并做进一步的讨论。     

乳化液泵站变频调速系统的设计

针对传统的乳化液泵站调速系统存在机械损耗比较大的问题,提出了一种乳化液泵站变频调速系统的设计方案;给出了该系统的硬件结构,详细介绍了该系统的工作模式及软件设计。实际应用表明,该系统运行稳定、机械损耗小。     

FTIR investigation of ethylene coordination and polymerization on reduced Cr/SiO2 catalyst

FTIR spectroscopy was applied to study the initial steps of ethylene polymerization on reduced chromia-silica (0.5 wt% Cr/SiO₂). To decrease the speed of the reaction small doses of gas were introduced to the catalyst in each run and C₂D₄ was used to confirm band assignments. At the initial steps of the reaction only ethylene molecules coordinated to probably Cr _A ²⁺ cations were observed. The concentration of such complexes was estimated to be about 50% of the total amount of Cr atoms in the sample. The FTIR spectrum of the polymer formed at the initial doses of C₂H₄ (when [C₂H₄] [Cr]) was found to be slightly different from that formed after excess ethylene was introduced onto the catalyst ([C₂H₄] > [Cr]).     

Natural Polysaccharides as Multifunctional Components for One-Step 3D Printing Tough Hydrogels

Natural polysaccharides (NPS) are regarded as biomolecular and structural components for preparing high-performance tough hydrogels. But the one-step fabrication of NPS-containing hydrogels in seconds and the template-free design of complicated high-resolution structures are still significant challenges in this field. To meet these requirements, various NPS-containing tough hydrogels are fabricated and processed into 2D/3D structures via the combination of Ru(bpy)₃²⁺-mediated photochemistry and extrusion 3D printing technique. The whole fabrication process is one-step, completed in tens of seconds under visible light irradiation. It is found that the used NPS plays a key role in achieving the fabrication of high-performance structured tough hydrogels. The high reactivity of functional groups in the used NPS can shorten their gelation times. Long rigid chains of the used NPS, their hierarchical assemblies, and contrasting multinetworks benefit from the efficient dissipation of mechanical energy and enhancement of its operational stability. Strong supramolecular interactions enable hydrogel precursors to have high viscosities, therefore providing good controllability to design high-resolution and complicated tough hydrogel structures via extrusion 3D printing. It is anticipated that this straightforward fabrication strategy and findings will open new horizons for NPS-containing materials.     

镍系聚丁二烯橡胶生产技术进展

介绍了近几年国内外镍系顺丁橡胶生产技术的进展情况，内容涉及分子量调节技术、催化剂配置技术、节能降耗的气相聚合、本体聚合工艺及橡胶后处理过程中使用的热泵技术、螺杆挤压工艺，同时也对国内外顺丁橡胶新型防老剂的使用情况及其新品种的开发进行了简要介绍。     

Properties of poly(n‐butyl methacrylate) prepared by reverse atom transfer radical polymerization in an aqueous dispersed system

Reverse atom transfer radical polymerization (ATRP) of n‐butyl methacrylate (BMA) in waterborne media using Cu(II) complexes with azo initiators (i.e., reverse ATRP) was conducted. The influence of several factors, such as surfactant, catalyst, and reaction time, on the stability of the emulsion, the particle size, the morphology of the emulsion particles, and the control of the polymerization was investigated. The results showed great differences between ATRP and conventional emulsion polymerization, especially the nucleation mechanism and the kinetics. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1542–1547, 2003     

改性丙烯酸-环氧树脂纳米乳液的制备及应用

介绍了水性丙烯酸-环氧树脂纳米乳液的制备及其在油罐防腐工程中的应用。讨论了亲水侧链聚乙二醇相对分子质量大小对涂膜性能的影响以及乳化剂各组分的用量对乳液粒径的影响。     

两性聚丙烯酰胺的合成方法及应用进展

结合国内外研究情况，从技术路线和实施方法两个角度着重阐述了制备两性聚丙烯酰胺的方法，同时简单介绍了其应用情况，并对今后的研究工作提出了一些建议。     

A Semi‐Batch Process for Nitroxide Mediated Radical Polymerization

Summary: A semi‐batch process using nitroxide mediated polymerization, was explored for the design of low molecular weight solvent‐borne coatings, typical of those used in the automotive industry. While living radical polymerization (LRP) offers many advantages in the control of polymer chain microstructure that may confer important physical and chemical property benefits to coatings, adapting LRP to a semi‐batch process poses significant challenges in the design and operation of the process. Using styrene monomer, various two‐component initiating systems (free radical initiator, 4‐hydroxy‐TEMPO) were studied to understand the effects of different initiators on the course of polymerization. In addition, an alkoxyamine was synthesized and used as the initiating source. The initiators Luperox 7M75 and Luperox 231 give higher polymerization rates and reasonable control over polymerization, while benzoyl peroxide (BPO), Vazo 67, and the alkoxyamine are less effective. The number of polymer chains in the final product is always less than the theoretical value, reflecting poor initiation efficiency, probably resulting from undesirable termination reactions that become important due to the nature of the semi‐batch process. Adding camphorsulfonic acid (CSA) or charging initiator concurrently with monomer during semi‐batch feed, can increase the polymerization rate while maintaining the living character of the polymerization. The copolymerization of styrene and butyl acrylate is also shown to exhibit living character.

Schematic representation of the exchange reaction to produce N‐TEMPO capped polymer chains.     

VAc/AA改性的VAE乳液高速接嘴卷烟胶的研制

介绍了VAc/AA改性的VAE乳液高速接嘴卷烟胶的制备方法。研究了各种因素对胶粘剂性能的影响。结果表明 :VAc/AA用量增加 ,VAE乳液的粘接性能增强。选择与VAE乳液相适应的乳化剂和控制适宜的pH值 ,可以增加VAE乳液的稳定性。采用滴加引发剂和混合单体的方法 ,可以避免过速反应产生及大粒径胶粒生成