消元法在开链机器人运动学逆解中的应用

用指数积公式法表示开链机器人的运动学方程,将吴消元法引入运动学逆问题的求解。通过吴消元法的特征列思想和符号运算的结合,实现了开链机器人运动学逆解的解析计算。结合实例说明了吴消元法在开链机器人运动学逆问题求解中的有效性。     

大豆乳清蛋白的乳化特性及水解条件

为考察大豆乳清蛋白乳化特性及胰蛋白酶水解技术,采用截留分子量(MWCO)为10000 u再生纤维膜(PXC)进行试验,考察大豆乳清蛋白乳化性(EAI)、乳化稳定性(ESI)、胰蛋白酶水解技术及其最佳控制条件.结果表明:大豆乳清蛋白ESI效果影响因素及最佳条件是:时间(25 min)>质量分数(5%)>温度(40℃)>pH(9),EAI效果最佳条件是:质量分数(5%)>温度(40℃)>pH(9)>时间(25 min).大豆乳清蛋白的胰蛋白酶水解技术可行,水解条件为:底物质量分数2%,酶用量4000 u/100g.pro,水解时间4 h,温度60℃.     

高浓度超稠油乳化废水预处理工艺与实践

超稠油在加工过程中产生大量高浓度乳化废水,常规炼油污水处理场难以处理并导致外排水严重超标.以某稠油加工企业高浓度超稠油乳化废水为研究对象,对其物理化学性质,沉降、破乳、絮凝条件进行了系统研究,并在大量试验的基础上开发出预处理工艺.相应装置建成后运行平稳高效,废水得到高效的处理与污油资源回收.     

Biomimetic micropatterning of silica by surface-initiated polymerization and microcontact printing

Micropatterns of silica on a gold substrate were generated by a biomimetic approach, namely, the biosilicification of silicic acids. The procedure consists of three simple steps: pattern generation of a polymerization initiator, (BrC(CH(3))(2)COO(CH(2))(11)S)(2), by microcontact printing; surface-initiated, atom-transfer radical polymerization of 2-(dimethylamino)ethyl methacrylate (DMAEMA) from the patterned area; and polycondensation of silicic acids. The tertiary amine-containing polymer, pDMAEMA, aided in the spatially controlled polycondensation of silicic acids on surfaces in the presence of phosphate ions, and micropatterns of silica on a gold substrate were successfully generated in combination with the technique of microcontact printing. The procedure could be extended to the controlled fabrication of silica patterns with any size, shape, or thickness.     

炸药乳化器安全监测方法及其发展

文章回顾了几种现行的乳化器安全运行检测方法,分析了各自的优缺点,介绍了一种使用现代振动监测诊断技术对乳化炸药生产线的关键设备乳化器进行在线安全监测的基本原理和功能,讨论了乳化器安全监测系统的发展方向.     

P(MMA-AN)/TiO2复合粒子的制备及光催化性能

采用原位乳液聚合方法制备了基于共价键结合的P(MMA-AN)/TiO2复合粒子,红外光谱和热失重分析结果表明P(MMA-AN)在TiO2表面接枝率为15.9%。以甲基橙溶液为目标污染物,研究了P(MMA-AN)/TiO2复合粒子和TiO2对甲基橙的吸附和光催化降解甲基橙溶液的性能,结果表明:两种粒子对甲基橙的吸附都很少;在相同时间内,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解性能优于TiO2,紫外光照180 min后,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解率达到了88%,而TiO2仅为74%。     

低临界胶束浓度PEGMA-b-PCL的制备及其 药物缓释性能

以ε-己内酯（ε-CL）为疏水链段,聚乙二醇甲醚甲基丙烯酸酯（PEGMA）为亲水链段,4-氰基-4-[(十二烷基硫基硫羰基)硫基]戊酸（CDPA）为可逆加成-断裂链转移（RAFT）试剂,在以甲苯为溶剂、N2氛围、80 ℃、反应24 h的条件下,通过RAFT聚合法制备了两嵌段聚合物PEGMA-b-PCL。将其自组装为胶束用作纳米药物载体,并以姜黄素（Cur）为胶束负载药物。考察了两嵌段聚合物结构、分子量及分布,表征了胶束载体粒径、形貌,测试了胶束载体的载药和释药性能。结果表明,不同嵌段聚合物相对分子质量范围为478~7318,此类聚合物具有较低的临界胶束浓度（CMC）,在常规条件下（pH=7.4）其范围为0.920~1.600 μg/mL。胶束载体粒径范围为:68.34~186.30 nm。当n(CDPA)∶n(ε-CL)=1∶200时,胶束载药量和包封率最高,可达12.05%和75.26%。在不同pH值环境下,药物缓释性能可达15 d,其中pH=5.0时释药量可达35.38%。     

兰州石化分公司新建30万t/a聚丙烯装置概况及特点

介绍了中国石油兰州石化分公司采用Basell公司Spheripol-Ⅱ技术新建30万t/a聚丙烯装置的工艺特点和产品方案.     

The influence of surfactants on the flow characterization of heavy oil

Flow characteristic of oil-in-water emulsion for heavy oil in porous media was studied. A surfactant was screened out and subsequently utilized as the emulsifier in sandpack flooding experiments with different oil-water ratio and permeability. The dual sandpack flooding experiment was conducted to investigate the effect of emulsion in porous media and the ability to enhance oil recovery. Results indicated that the selected surfactant gave a remarkable flow resistance in porous media. Higher oil-water ratio and lower permeability resulted in higher flow resistance. The surfactant increased ultimate recovery of 7.7% by diverting the fluid into low permeability sandpack.