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991.
992.
993.
利用石油裂解副产品C9生产苯乙烯-茚树脂 总被引:3,自引:0,他引:3
本文着重介绍用石油裂解副产物C9采用截取馏份,脱色,聚合,蒸馏等方法,选用高效催化剂生产苯乙烯-茚树脂,实验表明,采用本文所介绍工艺生产的苯乙烯-茚树脂色相,软化点等重要指导完全达到质量标准,可应用于了午线轮胎生产。 相似文献
994.
六甲基磷酰三胺增韧改性MC尼龙 总被引:5,自引:6,他引:5
介绍在己内酰胺阴离子催化聚合反应中,添加六甲基磷酰三胺作增韧改性剂制备改性MC尼龙。用DSC法研究了增韧改性MC尼龙的热性能,结果表明,随着六甲基磷酰三胺组分的增加,MC尼龙的熔融温度、熔融热焓、结晶度等均降低,材料力学性能变化的趋向与传热性能变化相吻合。 相似文献
995.
HE Zhiyong PENG Xiaoyan LIU Kaiqi LI Lin 《中国耐火材料》2007,16(4):21-23
B4C was added into the low-carbon MgO-C materials in order to improve the oxidation resistance. The results show adding 0. 3wt% B4C can get the best oxidation resistance and adding 0. 2 wt% B4C can get the highest hot modulus of rupture. Altogether, adding 0. 2wt% B,C into the low-carbon MgO-C materials can get better oxidation resistance and hot strength. 相似文献
996.
研究了以三甲胺作亲核催化剂、季铵盐A作相转移催化剂、水和极性有机溶剂B作双溶剂、亲核—相转移复合催化法合成对硫磷的方法,收率可达99%。 相似文献
997.
分光光度法快速测定蔬菜水果中VC的含量 总被引:2,自引:0,他引:2
通过吸收光谱曲线法确定VC的水溶液的最大吸收波长为267 nm,进而通过工作曲线法快速测定蔬菜水果中VC的含量,本方法与常规方法比较,具有快速、准确、简便、试剂易得等优点. 相似文献
998.
Yan Liu Shigenori Mitsushima Ken-ichiro Ota Nobuyuki Kamiya 《Electrochimica acta》2006,51(28):6503-6509
The electro-oxidation of dimethyl ether (DME) on PtMe/Cs (Me = Ru, Sn, Mo, Cr, Ni, Co, and W) and Pt/C electro-catalysts were investigated in an aqueous half-cell, and compared to the methanol oxidation. The addition of a second metal enhanced the tolerance of Pt to the poisonous species during the DME oxidation reaction (DOR). The PtRu/C electro-catalyst showed the best electro-catalytic activity and the highest tolerance to the poisonous species in the low over-potential range (<0.55 V, 50 °C) among the binary electro-catalysts and the Pt/C, but at the higher potential (>ca. 0.55 V, 50 °C), the Pt/C behaved better than PtRu/C. The apparent activation energy for the DOR decreased in the order: PtRu/C (57 kJ mol−1) > Pt3Sn/C (48 kJ mol−1) ≈ Pt/C (46 kJ mol−1). On the other hand, the activation energy for the MOR showed a different turn, decreased in the following order: Pt/C (43 kJ mol−1) > Pt3Sn/C (35 kJ mol−1) ≈ PtRu/C (34 kJ mol−1). The temperature dependence of the DOR was greater than that of the oxidation of methanol (MOR) on the PtRu/C. 相似文献
999.
The hydrogenation of C, CO, and CO2 has been studied on polycrystalline cobalt foils using a combination of UHV studies and atmospheric pressure reactions in temperature range from 475 to 575 K at 101 kPa total pressure. The reactions produce mainly methane but with selectivities of 98, 80, and 99 wt% at 525 K for C, CO, and CO2, respectively. In the C and CO2 hydrogenation the rest is ethane, whereas in CO hydrogenation hydrocarbons up to C4 were detected. The activation energies of methane formation are 57, 86, and 158 kJ/mol from C, CO, and CO2, respectively. The partial pressure dependencies of the CO and CO2 hydrogenation indicate roughly first order dependence on hydrogen pressure (1.5 and 0.9), negative first order on CO (–0.75) and zero order on CO2 (–0.05). Post reaction spectroscopy revealed carbon deposition from CO and oxygen deposition from CO2 on the surface above 540 K. The reduction of cobalt oxide formed after dissociation of C-O bonds on the surface is proposed to be the rate limiting step in CO and CO2 hydrogenation. 相似文献
1000.
Liquid phase hydrodechlorination of chlorophenols over Pd/C and Pd/Al2O3: a consideration of HCl/catalyst interactions and solution pH effects 总被引:1,自引:0,他引:1
The liquid phase hydrodechlorination (HDC) of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP) has been studied over 1% (w/w) Pd/C and Pd/Al2O3 under conditions of minimal mass transport constraints. The HDC of 2,4-DCP generated HCl and 2-CP as the only intermediate partially dechlorinated product which reacts further to yield phenol; cyclohexanone was formed over Pd/Al2O3, but not over Pd/C, prior to complete dechlorination. Pd/Al2O3 is characterized (on the basis of TEM analysis) by a narrow distribution of smaller Pd particles to give a surface area weighted mean particle DIAMETER = 2.4 nm that is appreciably lower than the value of 13.2 nm established for Pd/C, where the latter is characterized by a broader distribution of larger (spherical) particles. The addition of NaOH served to increase fractional dechlorination by suppressing HDC inhibition due to the HCl that is generated. Reuse of the catalysts revealed an appreciable deactivation of Pd/C and a limited loss of activity in the case of Pd/Al2O3. Deactivation of Pd/C can be linked to a decrease (up to ca. 60%) in the initial BET surface area allied to appreciable leaching (up to ca. 40%) of the starting Pd content through the corrosive action of HCl and, while the average Pd diameter is essentially unaffected, there is evidence of a preferred leaching of larger Pd particles. The stronger metal/support interactions prevalent in Pd/Al2O3 results in limited Pd leaching and comparable initial HDC activities during catalyst reuse with/without NaOH addition. Inclusion of HCl in the reaction mixture (pH 5–1.5) resulted in a marked decline in the initial HDC rate associated with Pd/Al2O3 and a lesser drop in HDC activity for Pd/C. The difference in response to bulk solution pH variations are discussed in terms of the nature of the reactive species in solution and the amphoteric behavior of the Pd supports. 相似文献