Evaluation of high Ni-Cr-Mo alloys for the construction of sulfur dioxide scrubber plants

Corrosion in wet lime/limestone systems used for flue gas desulfurization in thermal power plants is of great concern. The frequent variations in acidity and in chloride and fluoride ion concentrations experienced by such systems pose a serious threat to the materials of construction. Currently used materials mostly type 316L stainless steel often fail to meet their life expectancy. The present study evaluates the performance of advanced Ni- Cr- Mo alloys 59 and C- 276 in a simulated sulfur dioxide scrubber environment. Accelerated tests showed that high Ni- Cr- Mo alloys have little tendency to leach metal ions such as chromium, nickel, and molybdenum at different impressed potentials. Scanning electron microscopy was used to examine the morphology of pitting attack.     

Ag—AgI指示电极电位滴定法测定钯

研究了铂、钯、金、铂镀金、石墨及Ag—AgI指示电极,提出了一个用Ag～AgI指示电极(vs.SCE),碘化钾电位滴定钯的方法。该方法可应用于钯合金、氯化钯、钯催化剂中钯的测定。对于含钯60％和O.5％的物料,变异系数分别为0.5％和4％。     

Lubrication and Friction of Magnesium Alloys in Warm Forging

In order to realize precision forging of magnesium alloys, the frictional behavior of ZK60 (Mg-6%Zn-0.5%Zr) is studied. At room temperature, the friction test of ZK60 sliding over the surfaces of cemented carbide tool with and without TiC+TiCN+TiN and DLC (diamond like carbon) coating is carried out. It is found that the DLC coated film is effective to reduce the coefficient of friction and the oxide film of magnesium increases friction. For warm forging, ring compression tests are carried out at temperatures from 200 °C to 300 °C. Several liquid lubricants are applied onto the tool surfaces by controlling the film thickness and the effect of lubrication on friction is examined. Some methods for heating and lubrication for warm forging of magnesium alloys are suggested.     

耐蚀钛合金的发展与应用

由于工业纯钛难于适应化工、采油等苛刻环境应用，促进了耐蚀钛合金的发展。本文对耐蚀钛合金的设计理论与试验作了分析，并对近期开发的耐蚀钛合金作了介绍，展望了耐蚀钛合金的应用。     

Cr3Si／Crl3Ni5Si2金属间化合物合金组织与高温滑动磨损性能的研究

利用水冷铜模激光熔炼炉制得了由初生枝晶Cr3Si和枝晶间Cr3Si／Crl3Ni5Si2共晶组成的金属间化合物合金。利用OM，SEM，TEM，EDS和XRD分析了该金属间化合物的显微组织，在400℃，500℃和600℃条件下测试了其耐磨性能。结果表明，由于Cr3Si和Crl3NisSi2硬度高、原子键合力强、组织细小、均匀，在高温滑动磨损条件下具有优良的耐磨性能。     

钛及钛合金电弧钎焊及接头强度

用Ti—Cu—Ni，Ti-Cr-Zr钎料在TIG电弧加热条件对TA2和Ti—6Al—4V钛合金进行钎焊。结果表明：用Ti—Cu—Ni钎料钎焊TA2和Ti—6Al—4V钛合金的搭接接头强度分别是418．3MPa和439．6MPa；用Ti—Cr—Zr钎料钎焊TA2和Ti—6Al—4V钛合金的搭接接头强度分别是575．2MPa和656．1MPa。对Ti-Cu-Ni钎料／母材界面分析认为固液异分化合物η相((Cu，Ni)Ti2)生成时呈笋状生长，嵌入钎缝对钎缝的强度提高有利。对Ti-Cr-Zr钎料／母材界面分析，认为主要是固溶体β-Ti(Cr)存在提高了钎缝强度。     

Ti—Al二元合金的成分对组织和力学性能的影响

用金相、扫描电镜和X射线衍射研究了6种不同Al含量Ti-Al二元合金铸态和退火态的组织结构和相组成的特征和变化。从结晶动力学的观点,分析了合金的结晶凝固过程。采用三点弯曲方法研究了合金的抗弯性能同Al含量的关系。结果表明,Al含量为34 wt%,经1100℃/30 h退火的合金抗弯性能最好,Al含量偏离34wt%,都对合金的力学性能不利。     

Zn-Al系二元相图的研究

利用高温X射线衍射法（XRD）、示差扫描量热分析法（DSC）、热膨胀法（PRD）等方法重新测定Zn-Al二元体系相图。在XRD曲线图中β（ZnAl）相的存在，表明存在β（ZnAl）固溶单相区；DSC曲线图表明在274～279℃范围内存在共析相变反应；PRD曲线图表明在340℃不存在相变反应。综合XRD、DSC和PRD结果，绘制了部分Zn-Al二元体系相图，为高铝锌基合金的实际相变应用提供参考。     

镁合金表面热喷铝工艺及防腐性研究

简述了在镁合金上的热喷铝工艺，并对表面喷铝层的耐腐蚀性进行了分析研究。对腐蚀后的表面进行了形貌观察及成分分析。结果表明，经热喷铝处理后，镁合金的耐腐蚀性能得到了极大的提高。     

微量稀土和硼在铜及其合金中的作用

介绍了近年来微量稀土和硼在其合金中的应用，稀土在铜和铜合金中去除杂质，净化晶界，细化组织，消除柱状晶的作用，从而改善铜和铜合金的导电性，力学性能，冷热加工性能和耐磨性性能，硼在铜和铜合金中有比稀土更显著的细化晶粒作用。