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21.
M WünschB.A Wolf 《Polymer》2002,43(18):5027-5034
Vapor pressures, phase equilibria and interfacial tensions σ were measured for solutions of poly(dimethylsiloxane) (PDMS, Mw[equals]75 kg/mol and Mn[equals]50 kg/mol) in mixed solvents of toluene (TL) and ethanol (EtOH) at 30, 40, 50 and 60 °C. The experimental ternary phase diagrams can be modeled quantitatively from the determined concentration and temperature dependent binary interaction parameters χij if the experimentally inaccessible composition dependence of χEtOH/PDMS is adjusted. The relations between σ and the equation of state of the system differ from that applying to single solvents. The exponents as well as the amplitude prefactors of the corresponding scaling laws (e.g. the dependencies of σ on the length of the tie lines or on the hump energy, i.e. on the intrusion into the two phase regime quantified in terms of Gibbs energies) change considerably with temperature. However, this variation can be reduced significantly by normalizing the independent variables. Dividing the length of the tie lines by the length for the corresponding binary subsystem proves more efficient than the distance of these tie lines from the critical point of the ternary system relative to the maximum distance of the binary subsystem. A combined normalization does not improve the situation. 相似文献
22.
R. Dula R. Janik T. Machej J. Stoch R. Grabowski E.M. Serwicka 《Catalysis Today》2007,119(1-4):327-331
Mg/Mn/Al mixed oxide systems of similar atomic ratios close to 2/0.5/1 were obtained by calcination of Mg,Al layered double hydroxide (LDH) type precursors containing Mn either in the cationic form within the brucite layer or as permanganate anions in the interlayer. The materials were characterised with PXRD, thermal analysis, XPS, ESR, TPR and BET. In mixed oxides derived from interlayer-doped precursor PXRD identified MgO–MnO solid solution and poorly crystalline Al-rich spinel phase, while those obtained from layer-doped LDH contained a better crystalline Mn-rich spinel. Surface of both materials was covered with poorly crystalline and/or amorphous Mn4+-containing phases. Higher reducibility of this surface coat in calcined layer-doped catalyst, as compared to interlayer-doped one, was attributed to the differences in the nature of underlying crystalline phases, and was considered the chief reason for the higher catalytic activity of this catalyst in the total oxidation of toluene. 相似文献
23.
该文分析了应用袋装炸药装填水孔爆破产生拒爆、"冲天炮"、根底偏高和爆破效果差等问题,然而应用乳化炸药混装车装填水孔可以解决这些问题,并且爆破后具有根底平整、大块率低、毒气少和综合效益高等优点.以三峡永久船闸旁侧泄水箱涵工程和江苏田湾核电站工程为例进行了分析. 相似文献
24.
25.
An algorithmic approach was used to select recoveries for non-sharp sequence designs. Simple distillation columns were employed. The non-key component distribution was modeled using the Fenske equation. The combination of producing impure products and allowing non-key component distribution, results in a large search space. With this large search space size and software limitations, five problems were solved (see summary table in the Design Examples sub-section). The optimal non-key component distribution was found to be significant but not necessarily maximal. Parallel processing was selected as optimal in contrast to the more traditional sequential processing. 相似文献
26.
Steady laminar binary mixed convection flow along a vertical circular cone under the combined buoyancy effects of thermal and species diffusion is studied analytically. The analysis is confined to mass diffusion processes with low concentration levels. In the analysis the surface of the cone is assumed to be at a uniform temperature and uniform concentration. Numerical results for the local Sherwood number, local Nusselt number and local friction factor are presented. Representative temperature, concentration and velocity profiles are also shown. The analysis covers the diffusion of common gases and vapours into air. Considerations are given to the situations where the buoyancy forces assist and oppose the forced convection flow for various possible combinations of the thermal and species diffusion processes. 相似文献
27.
在本文中,将微波功率分配器看做用多个两端口网络构成的多端口匹配网络,用集总与分布参数元件混合组成的模块来综合这种网络,从而得到了一种新型的混合集中分布参数微波功率分配器及其机助设计方法。 相似文献
28.
In the presence of mixed micelle of a cationic and a nonionic surfactants,the reaction of scandium(Ⅲ)with phenylfluorone or its derivatives results in a very sensitive colouration:furthermore this chromophoricsystem tolerates the existence of a considerable amount of masking agents,so that many interfering ions can bemasked and its selectivity would be further improved.After studying the optimum conditions and main charac-ters of some similar systems,the system of Sc(Ⅲ)—Orthonitrophenyuorone—CetyltrimethylammoniumBromide(CTMAB)—Triton X-200 is chosen for the spectrophotometric determination of microamount ofscandium.The proposed method shows not only high sensitivity(with a molar absorptivity of 2.12×1~sLmol~(-1)·cm~(-1))and selectivity,but also high tolerance of chromophoric conditions.Beer's law is obeyed over arange of 0~6.0 μg Sc/25ml.If the dual-wavelength method is applied,a much higher molar absorptivity o|"3.04×10~5L·mol~(-1)·cm~(-1)than those of other systems ever reported in the literatures can be attained:more-over.its linear range is extended to 0~8.0 μg Sc/25ml and its reproducibility is also improved. 相似文献
29.
混合溶剂对Ru(Ⅳ)萃取的研究 总被引:2,自引:0,他引:2
一、前言 在一定浓度盐酸介质中,Ru(Ⅳ)以RuCl_6~(2-)络阴离子状态存在,可被C类溶剂TOA(三辛胺)以离子缔合机制定量地萃入有机相。由实验得到在相同条件下,TOA对Ru(Ⅳ)的萃取率随稀释剂介电常数的增加而下降。 相似文献
30.
Tushar S. Deore Amid L. Sadgar Radha V. Jayaram 《Journal of surfactants and detergents》2021,24(1):185-190
Ionic liquids have been found to be suitable alternatives to volatile organic solvents in chemical transformation. Through a proper choice of cations and anions, the properties of an ionic liquid can be tuned so that it resembles an amphiphile. Such specially designed molecules are known as surface-active ionic liquids (SAIL). Like conventional surfactants, SAIL also form aggregates in an aqueous medium. Studies show that the mixing of SAIL with conventional surfactants leads to synergistic micellization. However, very few reports are available on the application of such systems as reaction media. Present study focuses on the application of mixed micelles of 1-tetradecyl-3-methylimidazol-1-ium bromide, ([C14mim]Br) with nonionic surfactant, Octylphenol ethoxylate with 10 moles of ethylene oxide (OPE-10). Enhanced solubilization and selective catalytic oxidation of toluene using hydrogen peroxide as an oxidant and tungstic acid as a catalyst have been studied in detail using this system. 相似文献