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21.
S. Mardnio P. Lucena Randall Q. Snurr Clio L. Cavalcante Jr. 《Microporous and mesoporous materials》2008,111(1-3):89-96
The adsorption of xylene isomers in AlPO4-11 (AEL network) was investigated using biased grand canonical Monte Carlo (GCMC) simulations. Preferential o-xylene adsorption was predicted by the simulations, in agreement with previously reported experimental data. In AlPO4-11 the selective adsorption behavior comes from the smaller length of the o-xylene molecule along the crystallographic c-axis compared to p-xylene. This is in contrast to AlPO4-5 and AlPO4-8, where the ortho-selectivity is caused by the characteristic face-to-face positioning of o-xylene. Energy minimization studies were also performed in a flexible AlPO4-11 lattice to study the structural changes upon xylene adsorption. The energy minimization study showed that the AlPO4-11 crystal distorts upon p- and o-xylene adsorption. The distortion mechanism is related to the strong interaction between xylene methyl groups and the sieve oxygen atoms in the O3 position in the wide region of the pore. 相似文献
22.
Dong Zhang 《Korean Journal of Chemical Engineering》2008,25(5):1205-1207
Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release
and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce3+ and Ce4+. Several methods have recently been described to prepare the CeO2-ZrO2 solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO2-ZrO2 solid particles. The Ce-Zr alcogel is dried and calcined in flowing N2 not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high
surface area over 90 m2g−1, which drops to 40 m2g−1 following treatment at 900°C. 相似文献
23.
The Clopper-Pearson confidence interval has ever been documented as an exact approach in some statistics literature. More recently, such approach of interval estimation has been introduced to probabilistic control theory and has been referred as non-conservative in control community. In this note, we clarify the fact that the so-called exact approach is actually conservative. In particular, we derive analytic results demonstrating the extent of conservatism in the context of probabilistic robustness analysis. This investigation encourages seeking better methods of confidence interval construction for robust control purpose. 相似文献
24.
A method for constructing an approximation of the critical excitation that drives an elastoplastic system from rest to a target threshold at a specified time instant, referred to as the “suboptimal excitation,” is presented in this paper. It is based on the observations gained from study of the critical excitations in the companion paper. Essentially, for the usual case of interest where the failure time is not small compared to the natural period, the duration of the positive and negative pulses of the critical excitation are roughly equal to half of the natural period. This consideration allows for a simple intuitive approximation of the critical excitation. The amplitudes of the positive and negative pulses are obtained in closed forms using energy balance. Numerical investigations show that the critical excitations are well approximated by the suboptimal excitations. 相似文献
25.
This paper analyzes the running mechanism of flexible and thin tape above rotating protrusion through a numerical simulation.
The scope of analysis is confined to the phenomena of elastohydrodynamic lubrication between the rotating drum with a protrusion
and the running tape. This model is based on the modified Reynolds equation and the equation of plate considering the effect
of geometric nonlinearity and geometry of protrusion. Finite element method of Bubnov-Galerkin type is adopted as a numerical
simulation technique to solve the above two coupled nonlinear equations. In numerical simulation, the influences of tape tension
and protrusion velocity are evaluated in simple model. In complex models, the reciprocal action of two protrusions is simulated. 相似文献
26.
钻速模式动态辨识方法研究 总被引:1,自引:0,他引:1
目的:钻进过程是一个复杂的工艺过程,影响钻速的因素错综复杂。为钻井参数优化和实时控制,提出钻速动态模型。方法:对影响钻速的因素进行分析,用系统辨识方法建立钻速模式。结果:利用该方法建立了华北油田岔河集地区的钻速模型,取得满意结果。结论:此动态钻速模式能更准确、科学地描述钻进过程,并在钻井参数最优化、钻井过程的闭环控制等方面具有广阔的应用前景。 相似文献
27.
C/O测井响应随源距变化的理论研究 总被引:17,自引:7,他引:10
针对井内介质分别为水、油,地层分别为35%孔隙度饱和水砂和油砂的4种情况,采用蒙特卡罗方法模拟外径φ89碳氧比测井仪不同源距处的非弹性散射伽马能谱。通过分析地层或井内介质不同时的C/O差值随源距变化的关系,为设计仪器推荐源距参数。 相似文献
28.
29.
EGS程序图形化输入平台的开发 总被引:2,自引:2,他引:0
为了使EGS能够更加方便地被工程人员使用,使用VC^ 语言开发出一套运行于Windows下的EGSWIN程序,其中包括一个图形化的输入平台,通过使用本程序,用户可以仅仅进行简单而直观的输入几何实体的工作,就可以实现区域的定义。极大的提高了EGS的使用效率。 相似文献
30.