锅炉对流管爆裂原因分析

采用化学分析、金相检验及力学性能测定等方法，对锅炉对流管爆裂原因进行了分析。结果表明，长期超温运行而引起的蠕变是导致爆裂的主要原因。     

激光熔覆Ni基SiC合金涂层组织与性能的研究

利用5kWCO2连续波激光器在16Mn钢基材表面对含20%(体积比)SiC陶瓷粉末的镍基自熔性合金粉末进行激光熔覆得到Ni基SiC合金涂层(NiSiC)。研究了合金涂层的组织形貌及相结构,并用单纯的镍基合金涂层(Ni60)进行了显微硬度及滑动磨损性能的对比试验。结果表明,NiSiC合金涂层由γ枝晶及其间的共晶组织组成,主要组成相为γ-Ni,γ-(Ni,Fe)固溶体和(Cr,Fe)7C3,Cr23C6及(Cr,Si)3Ni3Si等化合物。添加SiC的镍基合金涂层NiSiC比单纯的镍基合金涂层Ni60具有较高的硬度和耐磨性。     

Interfacial reactions in In-Sn/Ni couples and phase equilibria of the In-Sn-Ni system

The In-Sn-Ni alloys of various compositions were prepared and annealed at 160°C and 240°C. No ternary compounds were found; however, most of the binary compounds had extensive ternary solubility. There was a continuous solid solution between the Ni₃Sn phase and Ni₃In phase. The Sn-In/Ni couples, made of Sn-In alloys with various compositions, were reacted at 160°C and 240°C and formed only one compound for all the Sn-In alloys/Ni couples reacted up to 8 h. At 240°C, Ni₂₈In₇₂ phase formed in the couples made with pure indium, In-10at.%Sn and In-11at.%Sn alloys, while Ni₃Sn₄ phase formed in the couples made of alloys with compositions varied from pure Sn to In-12at.%Sn. At 160°C, except in the In/Ni couple, Ni₃Sn₄ formed by interfacial reaction.     

可靠性试验样本量和截尾时间的计算

可靠性寿命试验中，一般都因受到费用和时间的限制，因此要用截尾试验获得信息，再据此对其可靠性进行统计推断，用非参数估计的方法探讨了进行可靠性试验的样本量或截尾时间的估计方法。     

絮凝剂品种对水下不分散混凝土性能影响的比较

通过电荷中和、吸附架桥和表面吸附分析了絮凝剂作用机理 ,运用絮凝机理进一步分析了絮凝剂在水泥体系中的作用以及絮凝剂对流动度的影响 ,从而对掺加JHP (纤维素类 )和Pj (丙烯类 )絮凝剂的水下不分散混凝土性能作了综合比较。掺Pj絮凝剂的混凝土 ,其坍扩度损失大 ,抗分散性能不如掺JHP絮凝剂的好 ;掺JHP絮凝剂的混凝土坍扩度在 3h内损失很小     

KZON-50/120空分设备的安装调试及设计改造

在KZON-50/120空分设备的安装调试和试运行过程中,对其机械和电器部分进行了多处改造,克服了原设计中存在的不足之处。改造后,机械和电器性能更加趋于合理,操作简单,便于维护,降低了制气费用,提高了制气纯度和经济效益,保证了空分设备更加安全可靠运行。     

锂离子电池有机电解液成膜添加剂的研究现状

文章综述了锂离子电池有机电解液成膜添加剂的作用原理，具体介绍了CO2、SO2、VC化合物、卤化物、有机铜盐以及马来酐等添加剂的研究现状。     

Epoxy paint failure in B-52 fuel tanks: Part II. Influence of DIEGME concentration in the fuel on the failure process

A model has been proposed to explain the failure of the original BMS10-39 epoxy paint on upper vertical surfaces in B-52 fuel tanks. The model involves interaction of the paint with DIEGME, a fuel system ice inhibitor (FSII) in jet fuel, that is distilled from the liquid fuel. In this communication, distillation experiments used to support the model are refined to better match the mass transfer of vapor from fuel in a B-52 fuel tank at close to room temperature. The interaction of these lower temperature distillates with the paint affirms the earlier model. On the basis of these experiments it is proposed that paint failure may be controlled or eliminated by reducing the level of DIEGME in the fuel. Proposed changes in military jet fuel composition are detailed.     

Ni catalyst promotion of a Cis-selective Pd catalyst for canola oil hydrogenation

A Ni catalyst was added to a cis-selective Pd catalyst in an attempt to further improve the Pd catalyst's cis-selectivity and activity for canola oil hydrogenation. The system was tested under reaction conditions known to be suitable for cis-selective hydrogenation with the Pd catalyst (50 ppm Pd, 70 °C, and 5.2 MPa). Although inactive on its own under these conditions, the addition of 100 ppm Ni increased the hydrogenation activity (from 2.12 to 2.49 10⁻² min⁻¹). Further addition of Ni up to 1000 ppm resulted in no further improvements in activity. The trans isomer contents of the oils hydrogenated with Pd and the Pd/Ni systems were similar. The level of conjugated dienes decreased rapidly during hydrogenation with both Pd alone and with the Pd/Ni combination and no changes in conjugation were detected in the presence of the Ni catalyst alone. The increased activity of the Pd/Ni system over Pd alone was attributed to adsorption of catalyst poisons from the oil by Ni.     

L-抗坏血酸亚铁的合成及表征

研究了VeCO3的制备以及利用自制的FeCO3与L-抗坏血酸作用合成L-抗坏血酸亚铁.主要探讨了溶剂的用量、反应时间以及温度对产物收率和产品质量的影响.确定了最佳反应条件为:溶剂用量为20mL,时间为120min,反应温度为100℃,产率可达68.1%.并通过x射线能谱和红外吸收光谱等测试手段对产品进行了表征.