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41.
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Keizo Uematsu Masayori Miyashita Jin-Young Kim Zenji Kato Nozomu Uchida 《Journal of the American Ceramic Society》1991,74(9):2170-2174
Green bodies prepared by compaction of alumina granules were made transparent by an immersion liquid technique, and the internal structure was characterized with an optical microscope to study the effect of forming pressure on the internal structure. Clear images obtained by the technique provide more detailed information than other existing methods for structures ranging from one to tens of micrometers. Intergranular pores were present between unfractured granules. Their sizes and concentration tended to decrease with increasing forming pressure. However, pores were clearly present even in the green body prepared at 600 MPa. A rod- and needlelike feature was also found and was concluded to correspond to a high-density region. The significance of large pores and high-density regions on processing as well as the details of the technique is discussed. 相似文献
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John E. Lowther 《Journal of the American Ceramic Society》2002,85(1):55-58
Diamond and BN have common relatively soft precursor structures that are hexagonal. Electronic structure calculations have now revealed subtle energy differences between the two materials. Another hard material, stishovite, also has a relatively soft precursor phase, quartz, and here again electronic structure calculations have given insight into the nature of the phase transformation. On the other hand, with boron-related materials, the main focus is to connect basic icosahedra structures to produce a hard material. The structural aspects of these materials are examined and possible consequences for low- and high-coordination ultrahard nitrides considered. 相似文献
45.
本文针对结晶器与铸锭作相对移动的电渣重熔过程中对渣系的高温强度及塑性的要求,对10种CaF_2-CaO-MgO-Al_2O_3-SiO_2渣组成进行了渣的高温强度及塑性的测定,建立了渣组成—渣的岩相结构—渣高温强度及塑性间的对应关系,并选择出较合适的成分范围为CaF_2 35~60%,CaO 10~25%,Al_2O_3 10~20%,SiO_25~15%,MgO≈5%。对其中一个成分的渣进行了电渣热穿孔熔铸中空锭生产实验,并取得了良好的表面质量。 相似文献
46.
SynthesisandCrystalStructureofRE[CH2(CH2)4CONC4H9]3(NO3)3(RE=Dy,La)WangHanzhang(王汉章),XuQingfeng(徐庆锋),QianPu(钱朴)SunJianping(孙建... 相似文献
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The energies of various steps on the As-terminated GaAs(001)-2 × 4 surface are evaluated using a novel, approximate method of “linear combination of structural motifs”. It is based on the observation that previous total energy minimizations of semiconductor surfaces produced invariably equilibrium structures made of the same recurring local structural motifs, e.g. tetrahedral fourfold Ga, pyramidal threefold As, etc. Furthermore, such surface structures were found to obey consistently the octet rules as applied to the local motifs. We thus express the total energy of a given semiconductor surface as a sum of (i) the energies M of the local structural motifs appearing in the surface under consideration and (ii) an electrostatic term representing the Madelung energy of point charges resulting from application of the octet rule. The motif energies are derived from a set of pseudopotential total energy calculations for flat GaAs(001) surfaces and for point defects in bulk GaAs. This set of parameters suffices to reproduce the energies of other (001) surfaces, calculated using the same pseudopotential total energy approach. Application to GaAs(001)-2 × 4 surfaces with steps reveals the following. (i) “Primitive steps”, defined solely according to their geometries (i.e. step heights, widths and orientations) are often unstable. (ii) Additional, non-geometric factors beyond step geometries such as addition of surface adatoms, creation of vacancies and atomic rebonding at step edges are important to lower step energies. So is step-step interaction. (iii) The formation of steps is generally endothermic. (iv) The formation of steps with edges parallel to the direction of surface As dimers (A steps) is energetically favored over the formation of steps whose edges are perpendicular to the As dimers (B steps). 相似文献
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就用双辊铸轧机(TRC)生产薄、宽铸轧带技术进行研究并优化铸轧工艺。研究结果表明:3mm厚的铸轧带不仅表面变形.而且整个厚度内部层都发生变形,表面层的铝基中具有较高的合金元素饱和度。 相似文献