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121.
122.
Yue Baohua Zhou Renxian Sha Feng Zheng Xiaoming 《中国稀土学报(英文版)》2006,24(1):28-28
Methane Combustion and TPR/TPO Properties of Pd/Ce_xZr_ 1-xO_2/Al_2O_3 Catalysts 相似文献
123.
胡延平 《苏州科技学院学报(工程技术版)》2002,15(1):25-28
文章研究了用把单膦配体络合物催化氯苄双羰基化反应生成苯基丙酮酸甲酯的催化反应。考察了反应温度、反应压力及催化剂用量对反应产率和选择性的影响。结果表明反应压力达6.0 MPa后产率无明显变化;反应温度在373 K时,产率和选择性都达到最大值;催化剂用量有一最适宜值,配体不同此值也不同。并探讨了体系的双羰基化反应机理。 相似文献
124.
P.L. Cabot A. Forn M. Vilarrasa J.A. Picas F.J. Gil J.M. Costa 《Journal of Applied Electrochemistry》2000,30(6):717-722
The effect of heat treatment of Ti and Ti–0.2 Pd alloys on their anodic oxidation was studied in deaerated 1% NaCl by means of anodic linear sweep voltammetry, SEM, TEM, EDS, optical microscopy and microhardness measurements. The specimens, as fabricated, consisted of -phase only. The -phase, intergranular or with a Widmansttäten type growth, was produced by heat treatment of the Ti–0.2 Pd alloys at the temperature range from 750 to 850 C. The -phase was transformed into the -phase during quenching. The current density against voltage curves for pure Ti and Ti–0.2 Pd, as fabricated or heat-treated, presented an initial plateau at about 1.5 V vs Ag/AgCl/KCl (3 M), an anodic peak at about 4.5 V and a current increase due to the pitting attack at about 10 V. The anodic peak was related to an oxide growth together with a solution electrolysis. Current spikes appeared at random from potentials about 8.3 V, which were related to film breakdown and repair events. The passive films of the alloys oxidized up to about 10 V presented oxidation bands parallel to the surface, with different oxygen content and microhardness, together with a structural transformation of the -phase under the titanium oxide layer. The similar behaviour of pure Ti and Ti–0.2 Pd alloys in front of pitting corrosion in chloride was due to such a structural transformation. 相似文献
125.
孙承永 《西安电子科技大学学报(自然科学版)》1992,19(2):59-63
淀积合金薄膜的 Si 片退火时,通过固相反应在界面处生成接触过渡层,其组分与结构均不同于一般条件下生成的硅化物.本文介绍了 Pd 合金/Si接触过渡层的形成工艺,对接触过渡层的结构组分进行了分析与讨论.基于“相分层”效应,可用掺氮或掺氧的方法提高阻挡层的质量. 相似文献
126.
We have used STM imaging in situ to demonstrate two fundamental steps in catalytic processes on model catalysts at elevated temperature. We show that Pd nanoparticles on sub-stoichiometric TiO2(110) dissociatively adsorb O2 at 673 K which spills over onto the support where further reaction takes place. The spillover oxygen re-oxidises the surface by removing Tin+ interstitial ions trapped in the crystal lattice, preferentially re-growing TiO2 around and over the particles. The identification of the metal enhanced re-oxidation mechanism may have important and general consequences for the understanding of catalysis and gas sensing. 相似文献
127.
TIAN Qi-feng ZHANG Yao TAN Zhi-cheng XU Fen SUN Li-xian ZHANG Tao Yuan Hua-tang 《中国有色金属学会会刊》2006,16(3)
1 Introduction MgNi-based amorphous hydrogen storage alloys have drawn much attention in the last ten years. Compared with AB5 or AB2 type electrode alloys, the alloy candidates for the negative electrode of Ni-MH batteries possess several advantages, su… 相似文献
128.
N. Cioffi L. Traversa N. Ditaranto A.M. Taurino M. Epifani P. Siciliano T. Bleve-Zacheo L. Sabbatini L. Torsi P.G. Zambonin 《Microelectronics Journal》2006,37(12):1620-1628
A two-step bottom up preparation protocol is proposed as a useful tool for the controlled modification of tin oxide films by means of Pd nanoparticles (PdNPs). Colloidal palladium is prepared via an electrolytic process that affords for a core-shell particle structure, while nanostructured tin oxide films are prepared following a sol–gel process. Pd/SnOx composite layers are obtained adding a proper aliquot of pre-formed PdNPs to the tin oxide precursor solution. The nanomaterials surface chemical composition is addressed by X-ray Photoelectron Spectroscopy. Preliminary results on the application of Pd/SnOx as active layers in chemiresistor-type gas-sensing devices are reported, as well. 相似文献
129.
Toshihiro KondoKazuhisa Tamura Masamitu TakahasiJun-ichiro Mizuki Kohei Uosaki 《Electrochimica acta》2002,47(19):3075-3080
A newly designed spectroelectrochemical cell was constructed for surface X-ray scattering (SXS) to study single crystal electrodes. Electrochemical characteristics of a specific face of a single crystal electrode can be investigated in the meniscus mode, and SXS measurement can be easily carried out using the spectroelectrochemical cell. The usefulness of the present cell was demonstrated by studying the electrochemical deposition of thin Pd layers on Au(111) and Au(100) that require precise amounts of Pd deposits. 相似文献
130.
Pd/C催化剂的制备条件对制备二甲基叔胺的影响 总被引:1,自引:0,他引:1
通过浸渍法制备了钯炭催化剂,用于脂肪腈催化加氢制备单烷基二甲基叔胺。通过N2-吸附、透射电子显微镜、X射线衍射等测试手段对催化剂进行物性表征,而且用气相色谱对叔胺产品进行定性分析。在反应温度120℃、反应时间5 h、二甲胺间歇式进料的反应条件下,通过对钯炭催化剂制备条件的优化,表明在pH7.9、浸渍时间15 h的条件下,叔胺含量可以达到95%以上。 相似文献