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Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present. 相似文献
24.
The overall behavior of concrete depends on its meso structures such as aggregate shape, interface status, and mortar matrix
property. The two key meso structure characters of concrete, bond status of interface and nonlinear property of matrix, are
considered in focus. The variational structure principle is adopted to establish the macro-meso constitutive law of concrete.
Specially, a linear reference composite material is selected to make its effective behavior approach the nonlinear overall
behavior of concrete. And the overall property of linear reference composite can be estimated by classical estimation method
such as self-consistent estimates method and Mori-Tanaka method. This variational structure method involves an optimum problem
ultimately. Finally, the macro-meso constitutive law of concrete is established by optimizing the shear modulus of matrix
of the linear reference composite. By analyzing the constitutive relation of concrete established, we find that the brittleness
of concrete stems from the imperfect interface and the shear dilation property of concrete comes from the micro holes contained
in concrete.
Supported by the National Natural Science Foundation of China (Grant Nos. 50679022, 90510017, 50539090) and National Basic
Research Program of China (Grant No. 2007CB714104) 相似文献
25.
研制了高粘结强度、低电阻率、高渗透性能接头栓,并说明了改进的目标和方向。研究了电极接头栓的使用性能、主要作用和选用接头栓补救电极和接头连接质量的优点;研究了电极接头栓的原料选择、原料配比、添加剂和发泡剂的选取;确定了电极接头栓的生产技术要求和生产工艺流程。试验证明,研制的高性能接头栓具有高粘结、强固结、有效补强的作用。 相似文献
26.
Butt joints between Mg alloy AZ31 B and pure Al 1 060 sheets were produced via metal inert gas welding process with Zn-Cd alloy foil. Crack-free Al/Mg butt joints between AZ31 B Mg alloy and pure Al 1060 sheets were obtained. Intermetallic compound layer 1 and layer 2 had formed in fusion zone/Mg alloy and the average thickness of the layer 1 was about 50 μm. The intermetallic compound layer 1 consisted of Al12Mg17 and Mg2Si phases while layer 2 consisted of Al12Mg17, Mg2Si and Mg Zn2 phases. The crack started from the IMC layer at the bottom of the joint and propagated along the brittle IMC layer, then expanded into weld metal during the SEM in situ tensile test. The highest tensile strength of the dissimilar metal butt joints could reach 46.8 MPa and the effect ofinterfacial IMC layer on mechanical property of the joint was discussed in detail in the present study. 相似文献
27.
Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%. 相似文献
28.
低碳低合金铸钢力学性能的研究 总被引:2,自引:1,他引:2
利用Olympus光学显微镜、扫描电镜(SEM)及能谱分析(EDAX)探讨了等温淬火工艺对低碳低合金CrMnSi铸钢力学性能的影响,并通过XRD定量分析了相的组成.结果表明,合适的等温淬火工艺,可获得一定数量的贝氏体和残余奥氏体(约6%)的复合组织,冲击断口形貌由解理刻面变为韧窝状,铸造成形无缺口试样(10 mm×10 mm×55 mm)的冲击韧度由ακ≤30 J/cm2增加至ακ≥170 J/cm2,硬度HRC≥40,具有较高硬度和冲击韧度的配合. 相似文献
29.
数控机床位置伺服在线调试与动态性能分析研究 总被引:2,自引:0,他引:2
介绍一种在数控机床位置伺服系统在线调试中应用系统动态性能分析方法的基本原理,给出了一种位置伺服系统动态响应曲线、动态性能分析及其主要技术指标的实例。 相似文献
30.
THERMODYNAMICSANDPHASEEQUILIBRIUMOFCu-Y-O,Cu-Y-S,Cu-Y-O-SLIQUIDSOLUTIONS¥Du,Ting;Li,Guodong(CentralIronandSteelResearchinstit... 相似文献