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排序方式: 共有1815条查询结果,搜索用时 281 毫秒
31.
基于生成氟硅酸钾沉淀和该沉淀水解均析出不同量酸,用碱滴定完成氟硅酸及氢氟酸的连续测定。该方法用于生产实践,结果令人满意。 相似文献
32.
在20~70℃之间,用浊点法测定了磷酸三丁酯在水、盐酸和硫酸溶液体系中的溶解度.水在TBP-煤油有机相中的溶解度D(H2O)是TBP在水中溶解度δ的60倍;随着温度升高纯TBP和煤油稀释的TBP在水相中的溶解度δ都增加,符合Apelblat溶解度模型,即纯TBP在水中的溶解度与温度的关系:lgδ=3.509 4-1 328.31/T;用煤油稀释TBP可以降低TBP在水相中的溶解度δ;随着盐酸和硫酸的浓度的增加,纯TBP在酸液中的溶解度也增加,盐酸的影响更显著. 相似文献
33.
34.
Eric R. MacamAuthor VitaeBryan M. BlackburnAuthor Vitae Eric D. WachsmanAuthor Vitae 《Sensors and actuators. B, Chemical》2011,158(1):304-312
The intent of this work is to look at the effects of varying the La2CuO4 electrode area and the asymmetry between the sensing and counter electrode in a solid state potentiometric sensor with respect to NOx sensitivity. NO2 sensitivity was observed at 500-600 °C with a maximum sensitivity of ∼22 mV/decade [NO2] observed at 500 °C for the sensor with a La2CuO4 electrode area of ∼30 mm2. The relationship between NO2 sensitivity and area is nearly parabolic at 500 °C, decreases linearly with increasing electrode area at 600 °C, and was a mixture of parabolic and linear behavior 550 °C. NO sensitivity varied non-linearly with electrode area with a minima (maximum sensitivity) of ∼−22 mV/decade [NO] at 450 °C for the sensor with a La2CuO4 electrode area of 16 mm2. The behavior at 400 °C was similar to that of 450 °C, but with smaller sensitivities due to a saturation effect. At 500 °C, NO sensitivity decreases linearly with area.We also used electrochemical impedance spectroscopy (EIS) to investigate the electrochemical processes that are affected when the sensing electrode area is changed. Changes in impedance with exposure to NOx were attributed to either changes in La2CuO4 conductivity due to gas adsorption (high frequency impedance) or electrocatalysis occurring at the electrode/electrolyte interface (total electrode impedance). NO2 caused a decrease in high frequency impedance while NO caused an increase. In contrast, NO2 and NO both caused a decrease in the total electrode impedance. The effect of area on both the potentiometric and impedance responses show relationships that can be explained through the mechanistic contributions included in differential electrode equilibria. 相似文献
35.
E.N. ArmstrongAuthor VitaeT. StrikerAuthor Vitae V. RamaswamyAuthor VitaeJ.A. RuudAuthor Vitae E.D. WachsmanAuthor Vitae 《Sensors and actuators. B, Chemical》2011,158(1):159-170
NOx adsorption behavior on LaFeO3 (LFO) and LaMnO3+δ (LMO) was characterized using temperature controlled methods and mass spectrometry. Temperature program desorption revealed decomposition of complex surface species formation when NO or NO2 was adsorbed on LFO and LMO. LFO exhibited higher adsorption capacity for NOx species than LMO and was shown to be more active for NOx surface conversion. Both effects were attributed to the different B-site cations, with iron in LFO in the 3+ valence state, and manganese in LMO in the 3+ and 4+ valence states. Results from diffuse reflectance infrared spectroscopy were used to identify specific nitrite and nitrate species that are formed on the surfaces of LFO and LMO at room temperature. Temperature programmed reaction revealed a complex NO2 decomposition mechanism to NO and O2 for LFO and LMO in which the formation of nitrite and nitrate species serve as intermediates below ∼600 °C. NOx sensing mechanisms were considered and predicted based on the types and quantities of surface species formed. 相似文献
36.
Syed M. Usman AliAuthor Vitae N.H. AlviAuthor VitaeZafar IbupotoAuthor Vitae Omer NurAuthor VitaeMagnus WillanderAuthor Vitae Bengt DanielssonAuthor Vitae 《Sensors and actuators. B, Chemical》2011,152(2):241-247
In this study, a potentiometric uric acid biosensor was fabricated by immobilization of uricase onto zinc oxide (ZnO) nanowires. Zinc oxide nanowires with 80-150 nm in diameter and 900 nm to 1.5 μm in lengths were grown on the surface of a gold coated flexible plastic substrate. Uricase was electrostatically immobilized on the surface of well aligned ZnO nanowires resulting in a sensitive, selective, stable and reproducible uric acid biosensor. The potentiometric response of the ZnO sensor vs Ag/AgCl reference electrode was found to be linear over a relatively wide logarithmic concentration range (1-650 μM) suitable for human blood serum. By applying a Nafion® membrane on the sensor the linear range could be extended to 1-1000 μM at the expense of an increased response time from 6.25 s to less than 9 s. On the other hand the membrane increased the sensor durability considerably. The sensor response was unaffected by normal concentrations of common interferents such as ascorbic acid, glucose, and urea. 相似文献
37.
Detection of sulfur dioxide (SO2) at high temperature (600–750 °C) in the presence of some interferents found in combustion exhausts (NO2, NO, CO2, CO, and hydrocarbon (C3H6)) is described. The detection scheme involves use of a catalytic filter in front of a non-Nernstian (mixed-potential) sensing element. The catalytic filter was a Ni:Cr powder bed operating at 850 °C, and the sensing elements were pairs of platinum (Pt) and oxide (Ba-promoted copper chromite ((Ba,Cu)xCryOz) or Sr-modified lanthanum ferrite (LSF)) electrodes on yttria-stabilized zirconia. The Ni:Cr powder bed was capable of reducing the sensing element response to NO2, NO, CO, and C3H6, but the presence of NO2 or NO (“NOx”, at 100 ppm by volume) still interfered with the SO2 response of the Pt–(Ba,Cu)xCryOz sensing element at 600 °C, causing approximately a 7 mV (20%) reduction in the response to 120 ppm SO2 and a response equivalent to about 20 ppm SO2 in the absence of SO2. The Pt–LSF sensing element, operated at 750 °C, did not suffer from this NOx interference but at the cost of a reduced SO2 response magnitude (120 ppm SO2 yielded 10 mV, in contrast to 30 mV for the Pt-(Ba,Cu)xCryOz sensing element). The powder bed and Pt–LSF sensing element were operated continuously over approximately 350 h, and the response to SO2 drifted downward by about 7%, with most of this change occurring during the initial 100 h of operation. 相似文献
38.
基于测定推进剂A现有分析方法准确度低,神经网络法对仪器要求高等不足,提出了的一种新的分析方法。该方法利用已知酸的电位滴定数据建立多元线性回归数学模型,利用化学因子分解该模型,对未知样进行浓度测定。实际测定结果表明本方法的最大分析误差不超过0.17%,标准偏差不超过1.9%,满足样品分析要求。 相似文献
39.
多元分析法在沉淀滴定中的应用 总被引:1,自引:0,他引:1
将多元分析法应用于沉淀滴定之中 ,提出固定电位的方法 ,建立了沉淀滴定中各组分浓度与体积之间关系的数学模型 ,对卤素和硫氰酸盐混合体系进行了测定。 相似文献
40.
以库仑滴定法测定工业废水中微量砷,以死停终点法确定滴定终点,最后以EXCEL处理实验数据,本方法具有灵敏度高,准确,简便快速,仪器便宜,易于推广的特点,特别适用于工厂及县级以下环境监测站进行水中微量砷的检测,方法的回收率为99.3%。 相似文献