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51.
磷酸萃取是6万t磷铵料浆法流程的关键之一,重要的控制参数有矿浆、硫酸、返回淡磷酸的加入量及萃取槽的液位、压力、温度等。 相似文献
52.
Local equilibrium model described in Part I is used to stimulate both, the steady state operation conditions and transient regime after the start of PSA equipment. The effect of axial dispersion, adsorption isotherm nonlinearity and high pressure level is simulated. On the basis of numerical analysis, the operation of a classical two-bed oxygen generator is compared with two configurations having pressure equalizing step. The optimization strategy of the given PSA equipment has been proposed and the procedure is demonstrated on an example. The scaling-up condition for PSA equipments which can be described by local equilibrium model has been proposed on the basis of the theoretical analysis. 相似文献
53.
Cure kinetics and shrinkage model for epoxy-amine systems 总被引:1,自引:0,他引:1
Manufacture of most of epoxy resins implies that cure needs to be carried out under pressure. Due to the significance of knowing the influence of the pressure factor in cure kinetics, cure shrinkage of a stoichiometric epoxy-amine system was measured using a pressure-volume-temperature (PVT) analyzer. Recording the specific volume change in the range of temperature from 100 to 180 °C and a pressure of 200 bar we could model the cure kinetics. The Runge-Kutta method was applied to obtain the kinetic constants of the cure reaction. In addition, using the differential scanning calorimeter (DSC) for measurements of 1 bar and the PVT analyzer for pressures of 200, 400, and 600 bar, we also model the kinetic constants as a function of pressure. The results obtained show that the effect of the temperature on the kinetic constants is higher than the effect of pressure. Therefore, both PVT and DSC are complementary techniques to describe the full range of cure kinetic process of epoxy mixtures. 相似文献
54.
55.
Hsi-Jen Chen Shan-Huei Yang Shun-Hsing Huang Y.P. Chyou 《Journal of the Chinese Institute of Chemical Engineers》2007
This paper addresses an integrated design of paraffin-reformer, gas separations and the electricity production with a solid oxide fuel cell (SOFC). The overall design consists of three modules. First module is a system of paraffin reformer. In this module, the paraffin feed stream is to send to a steam-reformer. In the second module, the gas separations method illustrated is the combination of a methane-permeable membrane with a pressure-swing adsorption (PSA). In the third module, the purified hydrogen is fed to the SOFC unit. To be energy efficient, this paraffin-fueled SOFC system is designed with the consideration of heat integration. The intent of this paper is to provide a possible, alternative way of cogeneration systems for refinery and petrochemical plants. 相似文献
56.
57.
Based upon a new conception that the solid compressive pressure on a cake surface is not null, almost of all solid-liquid
separation operations have been re-examined. For cake filtration, the phenomenon caused by the solid compressive pressure
on a cake surface is discussed for thin cake. New expression and hindered sed-imentation theories are developed by above new
conception using Darcy’s equation. Application of the new conception to centrifugal filtration and tangential filtration is
also discussed. Above results lead to the conclusion that cake filtration, expression, hindered sedimentation, centrifugal
filtration and tangential filtration can be described with a unified theory, and the main difference between the operations
is only the boundary condition of cake. 相似文献
58.
Wang-Gi Kim Jaeyoung Yang Sangsup Han Chanhwi Cho Chang-Ha Lee Hanju Lee 《Korean Journal of Chemical Engineering》1995,12(5):503-511
An experimental and theoretical study is performed for bulk separation of H2/CO2 mixture (70/30 volume %) by PSA process with zeolite 5A, a process widely used commercially in conjunction with the catalytic
steam reforming of natural gas or naphtha. For the optimized adsorption conditions of PSA, the characteristics of adsorption/desorption
characteristics have been studied through breakthrough and desorption experiments under various conditions. The purge-to-feed
ratio is important to the H2 product purity only at a long adsorption step time. H2 could be concentrated from 70% in the feed to 99.99% at H2 recovery of 67.5%. The results of all five steps in PSA are successfully predicted by the LDF model considering an energy
balance and nonlinear isotherm. For the model, the effective diffusivities (D,) are obtained separately from the uptake curves
of H2 and CO2. The Langmuir-Freundlich isotherm is used to correlate the experimental equilibrium data and is very well fitted to the results. 相似文献
59.
勃劳特换热器的性能周绪美,陈建铭,张鹏远,冯元鼎,丁华(北京化工大学化学工程系)关键词勃劳特换热器;压降1引言在生产过程中,气体与气体之间进行热量交换的换热器,在性能评比时,应该用两项指标来衡量。其一是单位产品所需传热面积要小,其二是单位压降的传热膜... 相似文献
60.
孙见君 《化学工业与工程技术》1997,18(2):38-41
针对国产化过程中,邻二甲苯泵用机械密封工作时产生的故障,进行了失效分析。为邻二甲苯泵用机械密封的改造提供了依据。 相似文献