调光保温聚乙烯农膜的光色效应研究

研制了含荧光色素、有机颜料、矿物填料的聚乙烯农膜,进行了两年的农田应用和光色效应研究,结果表明：与使用普通聚乙烯农膜相比,可提高棚内红光或蓝光强度,增加棚内温度,促进作物光合作用,提高作物的产量和品质。     

The Analysis of Photocuring Behavior of Polyester Acrylate by Means of Differential Photo Calorimeter (DPC) and Rigid-Body Pendulum Rheometer (RPT)

This study aims to understand the different photocuring behaviors of acrylated polyester by adding different photoinitiators and monomers. Differential photo calorimeter (DPC) is used to understand the exothermal effects during photocuring. The self-catalyst model of dynamic analysis software was then used to obtain the relationships between reaction speed, reaction extent, and rate of reaction. In addition, this study also tried to understand the formation of photocuring resin from the rigid-body pendulum rheometer (RPT) experiment. The results showed that the extent of reaction, conversion rate and speed varies directly with the concentration of the photoinitiator and monomer. The reaction level of propoxylated pentaerithritol triacrylate was higher than propoxylated neopentyl-glycol diacrylate. Moreover, the method using RPT shows better view of the molecule reaction status inside the photopolymer.     

利用锰矿酸浸废渣制备免烧砖的研究

以酸浸锰渣、石灰和水泥为主要原料,用河砂作为骨料,采用压力成型的方法制备锰渣免蒸免烧砖的研究。采用单因子试验法确定了最佳的成型压力,并对影响强度的胶砂比进行了分析。采用正交试验法研究了原料的最佳配合比。通过测试免烧砖的抗压强度和利用扫描电镜、x射线衍射分析（XRD）研究了免烧砖性能与强度形成机理。最佳成型压力为25MPa,原料配比为：酸浸锰渣35％、河砂45％、水泥13％、生石灰7％,水固比0.3。     

Ionomeric polyurethanes of pyridinium type with side azobenzene groups

New polyurethane cationomers synthesized by a two‐step substitution postreaction of urethane hydrogen atoms with nitroazobenzene groups were studied. As a starting polymer, a polyurethane based on poly(tetramethylene oxide)diol, isophorone diisocyanate, and 2,6‐bis(hydroximethyl)pyridine was used. After a preliminary metalation of the above polymer with natrium hydride, by reaction of polyurethane N‐sodate with 4‐nitro‐4′(β–iodoethylurethane)azobenzene, chromophoric groups between 2.85 and 10.53 wt % could be incorporated instead of hydrogen. Such polymers partially functionalized with azobenzene and further quaternized with methyl iodide led to the formation of pyridinium polyurethane cationomers N‐modified with nitroazo groups. The photosensible properties of the azobenzene chromophore in a polymer solution and film state indicated important differences in their photoresponse. In the polymer solution, the trans–cis photoisomerization of the chromophore is accompanied by an irreversible photobleaching effect, while under the same UV irradiation conditions, the ionomeric films exhibited an enhanced photostability. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1240–1247, 2002     

数码成像时代的传统卤化银技术及其在新的成像体系中的应用

依据东西方卤化银国际会议上发表的文章,对传统卤化银技术的未来走势作出判断,同时对卤化 银和以卤化银为基础的热敏成像等新技术做了介绍。     

In:Fe:LiNbO3晶体的生长及其在全息关联存储中的应用

用提拉法生长1％（摩尔分数,下同）In ：Fe ：LiNbO3（LN）,2％In ：Fe ：LN,3％In ：Fe ：LN和Fe ：LN晶体,配料中掺入0．03％（质量分数）Fe2O3。采用光斑畸变法测试晶体的光损伤阈值。结果表明：1％In ：Fe ：LN和2％In ：Fe ：LN晶体的光损伤阈值比Fe ：LN晶体高1个数量级以上。3％In ：Fe ：LN晶体的光折变阈值比Fe ：LN晶体高2个数量级以上。晶体的位相共轭效应测试结果表明,1％In ：Fe ：LN晶体的位相共轭反射率（R1=185％）高于3％In ：Fe ：LN晶体（R3=120％）。以3％In ：Fe ：LN晶体作为存储元件,1％In ：Fe ：LN晶体作为位相共轭镜．进行全息关联存储实验．其再现图像清晰完整,噪音小。     

微反应器控制的化学反应的选择性

研究利用分子筛、Ｎａｆｉｏｎ薄膜、低密度聚乙烯薄膜和囊泡作为微反应器控制有机光化学反应的方向,提高反应的选择性和可能性。在ＮａＹ沸石或低密度聚乙烯薄膜中,带有长烷基链或醚链的二芳基化合物光二聚只生成分子内的加成产物,而不生成分子间的加成产物,从而在底物浓度很大的情况下,高选择性地合成了大环化合物。通过控制底物和敏化剂分子在ＺＳＭ－５沸石、Ｎａｆｉｏｎ薄膜和囊泡中的分布高选择性地控制烯烃光敏氧化反应