Photocatalytic properties of screen-printed titania

Nanocrystalline thin films of important surface roughness and complexity were prepared by screen-printing of commercial TiO₂ powder. The screen-printed titania films were tested in the photocatalytic decomposition reaction of methyl orange under UV light (350 nm). The photocatalytic activity strongly depends on the titania paste components and especially on the presence of a surface modifier (acetyl acetone) combined with a rheology controlling agent (ethyl cellulose). This results in improvement of the paste viscosity and optimization of the films morphology. Experiments under direct full sunlight illumination prove the importance of the screen-printed films for practical applications.     

20CrMnTiH钢水口堵塞机理研究与解决措施

研究了转炉生产20CrMnTiH钢时连铸水口堵塞的机理，主要通过精炼造CaO—Al2O3-SiO2-CaF2系渣，保持熔渣良好的流动性和高碱度、低熔点、低氧化铁，提高吸附夹杂能力并针对引起水口堵塞的物质，对钙处理、软吹及进站S含量进行严格的要求，成功解决了水口堵塞问题。     

河流二维水质模型与地理信息系统的集成研究

根据水质预测、管理的不同需求,提出基于二维对流扩散方程的三种水质计算模式:连续点源排放水质模型,瞬时点源排放水质模型,有限体积法求解的数值解水质模型。基于MO进行GIS系统的组件式开发,实现了GIS平台下河势贴体河道二维正交网格的自动生成,解决了二维水体的空间网格离散问题。在此基础上,将三种类型的二维水质模型模块与GIS平台集成,以更好满足水质预测与管理在水质模型计算方式选取、计算精度与实现效率等方面的需求。     

The identification of highly chlorinated ethers and diethers in river sediment near an epichlorohydrin plant

In harbour sediment samples taken near an epichlorohydrin production plant, a series of highly chlorinated ethers and diethers were detected viz. three isomeric bis(dichloropropyl)ethers, several structurally closely related ethers with 9 carbon atoms (C₉ ethers), a number of C₁₂ ethers and diethers, and finally several C₁₅ ethers. The formation of this new class of ether compounds can be explained on the basis of the chemistry of the addition of HOCl to allylchloride. After initial addition of Cl⁻, a reactive intermediate is formed which may react with the product dichloropropanol, to give the C₆ ethers, or may polymerize with the starting compound allylchloride followed by reaction with the product, to give the C₉, C₁₂ and C₁₅ ethers.     

对硝基苯偶氮2-羟基萘-3-甲酰烷基胺系聚丙烯纤维用红色染料的合成及应用

本文将2,3-酸在甲苯溶剂中用氯化亚砜酰氯化合成2-羟基萘-3-甲酰氯,将其分别和正丁胺、正辛胺、正十二胺和正十八胺反应制得4种不同碳链长度的2-羟基萘-3-甲酰烷基胺,用对硝基苯胺重氮盐与其偶合分别制得了对硝基苯偶氮2-羟基萘-3-甲酰正丁胺、对硝基苯偶氮2-羟基萘-3-甲酰正辛胺、对硝基苯偶氮2-羟基萘-3-甲酰正十二胺和对硝基苯偶氮2-羟基萘-3-甲酰正十八胺系聚丙烯纤维用红色染料。熔点分别为189.8℃、96.2℃、115.8℃和108.1℃;热分解点分别为273.1℃、216.0℃、258.0℃和221.0℃;最大吸收波长分别为515.8nm、516.8nm、513.6nm和514.2nm。在染色条件下,4支染料在聚丙烯纤维上的上染率分别37.6％、41.8％、42.4％和44.7％。     

ZrV2合金的吸、放氘性能研究

测定了ZrV2合金的吸、放氘P－C－T曲线、吸附（或离解）平衡压与温度的关系曲线、初始吸附速率曲线，确定了ZrV2合金的吸、放氘热力学参数，给出了ZrV2合金的吸附容量、室温吸附（或离解）平衡压，为该材料的应用提供了依据。     

长庆上古生界气层CO2增能压裂工艺

长庆上古气藏物性差,压力系数低,水锁伤害大,采用常规水力压裂,入井液返排困难,气井产量低。在储层改造地质研究的基础上,通过对CO2泡沫压裂技术进行室内攻关,引进开发了CO2泡沫压裂酸性交联技术,优化了CO2泡沫方案设计及现场施工工艺,配套了CO2增能压裂工艺技术。经过现场应用,充分说明了CO2增能压裂是一项行之有效的工艺技术,对于提高单井产量和长庆气田整体开发水平都是有益的。     

Feature-Based Parametric Design of a Gating System for a Die-Casting Die

This paper presents a semi-automated approach for designing the gating system of a die-casting die. This approach combines the P-Q 2 technique and feature-based parametric design for achieving the automatic generation of the geometries for the gating system. It also enables users to integrate their expertise in the design at an early stage. User-defined gating features are pre-defined and stored in a gating library, and are then retrieved from the library and applied to the gating part with the desired parameters and locations during the design process. Algorithms based on the P-Q 2 technique are proposed for calculating the related parameters of the gating system. A prototype design has been developed using this approach, and the system is able to shorten the time for constructing the 3D geometries of the gating elements such as the gate, runner, overflow, shot sleeve, sprue, etc.     

只读式超分辨光盘的膜层设计和分析

超分辨技术是一种无需减小记录波长或增大数值孔径而提高存储密度的方法。Ge Sb Te是一种良好的相变光存储材料 ,在超分辨光盘中可作为掩膜。利用多层膜反射率的矩阵法计算了掩膜为Ge2 Sb2 Te5薄膜的超分辨只读式光盘的光学参数与各膜层厚度之间的关系 ,最后得到了较为理想的膜层厚度匹配。采用磁控溅射法制备了只读式超分辨光盘 ,测量了光盘的光学性质。     

The influence of the ion content of whey on the pH-activity profile of the β-galactosidase from Aspergillus oryzae

The pH-dependence of the reaction kinetics of lactase (β-galactosidase) from Aspergillus oryzae in different reaction media is presented in terms of a two-parameter model. The lactase from A. oryzae seems to have replaced the A. niger lactase on the market owing to a better activity/price ratio and may be utilised for lactose hydrolysis in acid as well as in neutral milk products. Its pH optimum is around pH 4.5. However, in the neutral pH-range its activity depended strongly on the salt content of the substrate solution. For example, its activity in whey (pH 6.5) fell to only 30% of its expected activity in a pure lactose solution at the same pH. The whey effect was the same for both soluble and immobilised lactase. The two parameter kinetic model, which included a term for competitive product inhibition gave excellent agreement with experimental data, and may thus be useful for the prediction of reactor performance with this enzyme.