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In this work, we examine the effect of small additions of cationic quaternary ammonium salts (QAS) of different molecular weight on the rheology of an industrial ceramic suspension deflocculated with sodium polyacrylate and sodium metasilicate. The observed shear thinning behaviors obey the typical power law of fluid rheology. In order to characterize the rheological behavior of these slurries, three new parameters are introduced: a low shear rate consistency index and two transient viscosities, distant from the equilibrium, after increasing and decreasing the shear rates. These parameters vary with polyacrylate molecular weight and on additions of small quantities of QAS, which we found to be useful for decreasing the slurry viscosity. 相似文献
13.
Vjacheslav V. Zuev 《Journal of Polymer Research》2008,15(5):351-356
Functionalized polyanilines containing biphenyl, terphenyl, carbazole, anthracene, and 4-n-hexylphenyl moieties were synthesized though the reaction of polyaniline in emeraldine base form with sodium salt of corresponding
vinylketoaromatics with quantitative yields. Polymers were characterized with Fourier transform infrared spectroscopy, proton
nuclear magnetic resonance spectroscopy, and thermogravimetry. The emission characteristics of these polymers in N-methyl-2-pyrrolidone solution were examined. The functionalized polyanilines exhibited an intense green emission. 相似文献
14.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
15.
文章采用氢氧化钠碱熔试样,经硫酸中和后,在1+1盐酸介质中蒸馏分离锗,使大部分干扰元素经蒸馏分离,并在1+1盐酸介质中用碘酸钾容量法滴定锗。该法滴定终点明显,准确率高。标准回收率为95.52%~105.78%,变异系数为3.18%~4.42%。适用于锗渣中高含量的锗的测定分析。 相似文献
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Nourh ne Boudhrioua Bertrand Broyart Catherine Bonazzi Jean-Dominique Daudin 《Drying Technology》2005,23(12):2313-2335
A method is presented for computing the values of apparent diffusivity in solids with respect to the concentration of the diffusing substance (water or sodium chloride). This method does not require any assumption upon the mathematical relationship between diffusivity and concentration. It can be applied to experimental measurements of local concentration versus position within the solid (profiles) with relatively few measurements (circa 10) and a mathematical smoothing of the experimental data by using an artificial neural network model. The method was first validated on simulated data obtained by using a constant diffusivity value and on experimental profiles when the relation between diffusivity and concentration was given. It was then applied to original experimental moisture profiles obtained by putting gelatin gels with different initial moisture contents into contact for up to 14 days. The method was also successfully applied to five sets of experimental moisture and sodium chloride profiles taken from the literature and obtained from different food products. Apparent diffusivities calculated by our method were found in agreement with those obtained by authors using different numerical methods to compute the diffusivity values. 相似文献
18.
用流动微量量热法研究了十二烷基硫酸钠(SDDS)和十二碳羧酸钠(SL)在克拉玛依油田九区和乌尔禾区油砂上的吸附,简要地计论了吸附机理。所得实验结果表明,SL 在油砂上的吸附强度比 SDDS 的要大,在相当低的浓度下即可迟到饱和吸附。 相似文献
19.
Adrian Thomas Christopher D. Gilson Tanveer Ahmed 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,64(1):73-79
Equipment was developed to measure the time for complete gelling of sodium alginate fibres in calcium chloride solution, taken as the time to achieve maximum tensile strength. The effects of fibre diameter, alginate concentration, alginate composition and calcium chloride concentration on gelling time were investigated. A diffusional model, developed to predict the gelling time, agreed with experimental results except for the effect of calcium ion concentration which was modelled empirically. 相似文献
20.
动态光散射法研究海藻酸钠凝胶松弛行为 总被引:5,自引:0,他引:5
在前文的基础上,用相关函数轮廓分析的方法剖析了运动模型模式的复杂性。通过海藻酸钠水溶液在0.1mol/LCaCl2水溶液透析凝胶化过程中交联网络的松弛时间谱表明它不是单一的峰,有两上特征运动模式,并随透析向更慢的运动模式发展,这很慢的运动模式估计与区域的结构的生成有关。 相似文献