3-甲硫基-1-丙醇的合成研究

研究了以 3 氯 1 丙醇和甲硫醇钠为原料 ,在相转移催化剂四甲基溴化铵的作用下 ,在 0℃下反应 1h ,然后升温至 30℃ ,并在此温度下反应 0 .5h ,合成了 3 甲硫基 1 丙醇 ,并用气相色谱、红外光谱和气质联用对其结构进行了确定。该方法工艺简单 ,条件温和 ,反应时间短 ,易于工业化 ,环境污染少 ,也适应于合成其他甲硫基化合物。     

从481—2B型废催化剂中回收钼工艺述评

钼酸铵是一种主要的化工原料，本文对从工业生产的废催化剂中回收钼的工艺进行了比较系统的概括，对各种工艺进行了比较，并给出了最佳的工艺条件。     

原位聚合改性交联LLDPE介电性能的研究

利用原位聚合聚丙烯酸钠(PNaAA)改性交联聚乙烯,增加聚乙烯的极性。采用FTIR和DSC表征了原位聚合后交联聚乙烯的结构形态。讨论了PNaAA、DCP用量对体系力学性能、介电性能的影响,结果表明:随着PNaAA用量的增加,体系拉伸强度略有增加,断裂伸长率下降,体积电阻率随PNaAA用量增加而变小;随着DCP用量的增加,拉伸强度出现一个最大值后开始下降,体系断裂伸长率随DCP用量的增加而下降。从体系组成及分子结构方面分析了介电性能随PNaAA用量增加而变化的原因。     

利用金属钠制备甲醇钠的生产工艺

介绍了甲醇钠的合成方法、理化性质以及安全保护应该注意的问题。研究了用金属钠制备液体甲醇钠的生产工艺，建立了生产工艺流程。用该工艺制备的甲醇钠溶液的产率达到98％以上，游离碱含量小于0．5％，产品可满足制药行业的特殊需要，它比传统氢氧化钠制取甲醇钠有明显的技术性能优势。同时也对甲醇钠的测定方法进行了深入研究，建立了一种准确、可靠的分析甲醇钠的方法。     

海藻酸钠与纳米晶纤维素共混膜制备与性能研究

借助冷冻干燥技术制备了海藻酸钠与纳米晶纤维素共混膜以达到增强目的;探讨了不同含量的纳米晶纤维素与海藻酸钠共混膜的微观形貌、力学性能、吸水性能及孔隙率的变化;综合评价确定最佳的纳米晶纤维素含量在0.75%至1.00%之间。     

不同改良剂对不同含砂率粉土改良性质研究

通过人工室内配制不同含砂率(10%、20%、40%)粉土,对其进行改良试验,研究在不同改良剂(石灰+水玻璃、石灰+粉煤灰)、不同配比作用下3种含砂率粉土的改良效果,研究结果表明:随着含砂率的增加,无论是素土还是改良土,其最大干密度均增大;对于石灰+水玻璃改良土,其最大干密度较素土有明显的降低,而石灰+粉煤灰改良土与之相反;石灰+水玻璃改良土最优含水率与素土略有差别,而石灰+粉煤灰改良土与素土最优含水率基本一致;在同一含砂率下,对于不同配比的石灰+水玻璃改良土,其最大压实度和最优含水率并未发生较大变化,10%石灰+20%粉煤灰的压实度高于其他配比情况;在恒定压实度(95%)下,改良土的无侧限抗压强度明显高于素土的无侧限抗压强度,改良剂对粉土起到一定的"维稳"效果,改良剂掺量才是决定无侧限抗压强度的关键因素。     

海藻酸盐纤维的开发和应用

海藻是海洋中最大的植物群,其生物质资源为化纤行业提供了一个巨大的可再生资源宝库。从海藻中提取出的海藻酸经过湿法纺丝后制备的海藻酸盐纤维是一种具有优良生物活性的功能纤维材料,可以与多种金属离子结合后形成富含金属离子的纤维材料,使纤维具有优良的阻燃及屏蔽电磁波的性能。以海藻酸钙纤维为原料制备的针刺和水刺无纺布在与体液接触后通过离子交换形成柔软的凝胶,适用于制备功能性医用敷料、面膜基材、吸湿垫等医用卫生材料,具有很高的应用价值。     

Investigation into the flotation response of refractory molybdenum ore to depressant mixtures:A case study

In this paper, bulk flotation followed by separation was investigated to concentrate purified molybdenite product from Jinduicheng molybdenum ores(Shanxi province, China). The bench scale tests mainly focussed on separation of molybdenite from other sulfide minerals using the new type of depressants.The effect of each single depressant, including organic depressant-modified dextrin(MD), P-Nokes reagent(PN) and sodium trithiocarbonate(ST), and their mixtures on galena, chalcopyrite and other sulfide ores, was examined in turn by changing the concentrations used in cleaner flotation tests. Closed circuit experiments were carried out under the optimal condition and satisfying recovery and grade of molybdenite concentrate could be achieved(86.294% and 53.157%, respectively). A potential reagent regime was developed, with more environmental friendly and more economical advantages due to the introduction of modified dextrin.     

Supercritical carbon dioxide assisted fabrication of biomimetic sodium alginate/silk fibroin nanofibrous scaffolds

In this study, biomimetic sodium alginate (SA)/silk fibroin (SF) scaffolds were successfully fabricated by supercritical CO₂ technology. The SA/SF scaffolds exhibited an interconnected porous and extracellular matrix (ECM)-like nanofibrous structures. Moreover, the SA microparticles were embedded in the SF scaffolds. Increasing the content of SA microparticles could improve tensile strength and compressive strength of the SF scaffolds and reduce the porosity of the SF scaffolds. The addition of the SA microparticles could also regulate the degradation rate of the SA/SF scaffolds. Furthermore, the results of in vitro biocompatibility evaluation, indicated that the SA/SF scaffolds exhibited no obvious cytotoxicity and higher cell adhesion ability and were more favorable for L929 fibroblasts proliferation than pure SF scaffolds. Therefore, the SA/SF scaffolds with ECM-like nanofibrous and interconnected porous structure have potential application in skin tissue engineering.     

Development of sodium hybrid quasi-solid electrolytes based on porous NASICON and ionic liquids

Lithium-ion batteries are currently the alternative of choice to overcome the increasing demand of energy. However, besides the scarcity of lithium and limited geolocation, it is believed that such batteries have already reached their maximum maturity. Sodium batteries emerge as an alternative to produce the new, so called, post-lithium batteries. In this study, we explore (i) the effect of sodium content and sintering temperature in solid electrolytes based in NASICON-type compounds and (ii) the use of two methodologies to obtain porous NASICON samples: application of natural substances and organic materials as pore-formers and freeze casting. The main purpose is the attainment of hybrid quasi-solid state electrolytes, with enhanced room temperature conductivity, based on porous ceramic electrolyte layers infiltrated with ionic liquids. Using this approach, porous samples with different microstructure and porous morphology and distribution were achieved, providing an enhancement in conductivity (ranging from 0.45 to 0.96 mS cm⁻¹ at 30 °C) of one order of magnitude for infiltrated samples respect to pore-free samples. According to these results the porous NASICON might be considered as a functional macroporous inorganic separator that can act as a Na⁺ reservoir.