Sr_2Al_6O_(11):Eu~(2+),Dy~(3+)蓝色发光材料制备

用高温固相法合成Sr2Al6O11:Eu2+,Dy3+蓝色发光材料,研究了合成温度、保温时间、B2O3加入量对该材料物相组成和发光性能的影响。结果表明,只有在掺入一定量的B2O3(5%~15%)的条件下,通过控制温度(1000℃~1150℃)和保温时间(1h~2h)能够合成Sr2Al6O11:Eu2+,Dy3+蓝色发光材料。     

蜂窝陶瓷型La0．8Sr0.2MnO3催化剂VOCs催化燃烧反应活性

以堇青石(CH)为第一载体,六铝酸盐(HA)为第二载体(washcoat),La0.8Sr0.2MnO3(LSM)为活性物种,制备了LSM/HA/CH催化剂.XRD表征发现,LSM具有完善的钙钛矿晶型.SEM观察表明,活性物种在涂层表面分散均匀.通过对苯、甲苯、二甲苯、乙酸乙酯、丙酮和乙醇六种有机物的性能测试,发现LSM/HA/CH对上述六种有机物均具有很好的催化活性,特别是对乙酸乙酯等含氧有机物表现出更好的燃烧性能,在10000 h-1空速下,反应温度为240℃时即可将含氧有机物完全燃烧.     

Sintering behaviour of La1−xSrxFeO3−δ mixed conductors

The sintering properties of La_1−xSr_xFeO_3−δ (x = 0.1, 0.25) mixed conductors have been investigated with particular emphasis on the effect of secondary phases due to cation non-stoichiometry (±5 mol% La excess and deficiency). Secondary phases, located at grain boundaries in cation non-stoichiometric materials, increased the sintering temperature compared to single-phase materials. Extensive swelling in final stage of sintering was observed in all materials, which resulted in micro-porous materials. The swelling was most pronounced in the phase pure and two-phase materials due to La-deficiency, while refractory secondary phases in La-excess materials inhibited both sintering, grain growth and swelling. In La-deficient materials, formation of molten secondary phases resulted in rapid swelling due to viscous flow. The present findings demonstrated the importance of controlling sintering temperature and time, as well as careful control of the cation stoichiometry of La_1−xSr_xFeO_3−δ in order to achieve fully dense and homogenous La_1−xSr_xFeO_3−δ ceramics.     

Sr对Mg-1.7Si合金中初生和共晶Mg_2Si相的变质作用

为了获得性能优良的耐热镁合金,研究了Sr对初生和共晶Mg_2Si相的变质作用,并利用扫描电子显微镜观察了Mg_2Si相的形貌特征与Mg-1.7Si-x Sr合金的微观组织.结果表明,当Sr的质量分数处于1.0%~1.5%范围内时,可对初生和共晶Mg_2Si相进行有效变质.Sr的吸附作用可以诱发孪晶沟槽、旋转晶界等原子扩展台阶的出现,引起原子堆砌方式和晶体生长方向的改变,因而Sr可对初生Mg_2Si相起到变质作用.Sr的添加还可将Mg+Mg_2Si共晶的长大方式由合作长大模式变为以重新形核为主兼有合作长大的混合模式,使得Mg_2Si相的生长形态产生改变,因而Sr可对共晶Mg_2Si起到变质作用.     

微波辅助溶胶燃烧法制备Sr2MgSi2O7:Tb3+荧光粉

采用高温固相法和微波辅助溶胶燃烧法分别合成了Sr2MgSi2O7:Tb3+荧光粉。通过综合热分析、X射线衍射(XRD)、扫描电镜(SEM)和光谱分析等手段对试样进行表征.结果表明:微波辅助溶胶燃烧法合成的Sr2MgSi2O7:Tb3+荧光粉颗粒大小均匀,呈类球形,且合成温度比固相法降低了700℃;Sr2MgSi2O7:Tb3+荧光粉的激发光谱在300~500nm之间,主峰位于377nm处,在377nm近紫外光激发下,采用微波辅助溶胶燃烧法合成的Sr1.995MgSi2O7:005Tb3+荧光粉比高温法合成样品的发射强度高.     

锶和钙在镁-铝系合金中的应用及研究进展

论述了耐热镁合金的研究现状。介绍了碱土元素Ca和Sr对Mg-Al系合金的铸造性能、微观组织、拉伸性能和抗蠕变性能的影响。同时对Ca、Sr在镁合金中应用前景作了展望。     

锶对消失模铸造B319铝合金铜相的影响

在消失模铸造慢冷条件下，B319铝合金组织中除存在α—Al枝晶及Si相外，还存在珊瑚状的A12Cu相及针状的β—Fe相，且Si相及针状β-Fe相可以作为Al2Cu的形核基底。Sr变质引起了离异共晶反应，使A12Cu相在缺乏Si相的区域析出，并促使Si在Cu相中溶解。研究还表明，采用0．03％Sr可以获得较好的变质效果，并使A1—Si共晶温度从575．9℃下降到566．4℃，从Cu相析出温度从520．4℃下降到512．5℃。     

微量元素Sr对Al-Mg-Si-Cu基合金车身板腐蚀性能的影响

采用全浸腐蚀实验、盐雾实验和电化学实验研究了微量元素Sr对Al-Mg-Si-Cu合金车身板腐蚀性能的影响.全浸腐蚀实验结果表明:合金加入Sr后,其质量损失速度由2.76 mg/(h·cm2)降为1.39 mg/(h·cm2),盐雾实验结果表明:合金加入Sr后,其质量损失速度由8.56×10-3mg/(h·cm2)降为5.90×10-3mg/(h·cm2),Sr可以明显减缓合金的腐蚀速度.电化学实验结果表明:合金加入Sr后,合金稳定电位较负,稳定时间长,合金钝化区较短,腐蚀电位ψcorr更负,且腐蚀电流密度较小.     

Mg-6Al-2Sr-xNd镁合金的显微组织和力学性能

研究了Mg-6Al-2Sr-xNd镁合金的显微组织和常温力学性能,探讨了合金中Nd与Sr复合添加后的存在形式及不同含量的Nd对合金常温力学性能的影响.结果表明：Al4Sr相呈网状沿晶界分布,而Al11Nd3相呈颗粒状或针状,在晶内、晶界均有析出.Al4Sr相在晶界起到了阻止晶界滑移的作用,Al11Nd3相在晶内有钉扎位错的作用,晶界晶内的双重强化提高了合金的强度.合金的抗拉强度、屈服强度和伸长率均在含Nd量为1.0%时达到了峰值.     

Effects of B2O3-SiO2 doping on electrical properties of Ba0. 65 Sr0. 35 TiO3 ceramics

Ba0. 65 Sr0. 35 TiOa ceramics doped with B2O3-SiO2 glass composition were prepared by using conventional solid-state reaction method. The effects of glass dopant on the dielectric and ferroelectric properties were investigated. The results show that the dielectric constant decreases while the dielectric loss increases after doping. And as the glass content increases the dielectric constant decreases while the dielectric loss changes slightly. From the complex impedance analysis the resistance and the relaxation time of the grain and the grain boundary can be calculated.Comparing the P--E hysteresis loop of undoped Ba0.65 Sr0.35 TiO3 ceramics with that of B2O3-SiO2 doped Ba0.65 Sr0.35 TiO3 ceramics, it can be seen that the remanent polarization decreases when the B2O3-SiO2 content is lower than 8% (molar fraction), and the coercive field increases with the increase of B2O3-SiO2 content.