Sr掺杂对12CaO·7Al2O3电子化合物电输运及发射性能的影响

12CaO·7Al₂O₃电子化合物(C12A7:e ^-)是一种具有低工作温度和低逸出功等优点的新型电子化合物阴极材料。通过高温固相反应结合放电等离子烧结制备Sr掺杂(Ca_1-xSr_x)12A7 (0≤x≤0.05)块体, 并在1100 ℃采用Ti颗粒还原20 h成功制得电子化合物(Ca_1-xSr_x)12A7:e ^-。第一性原理计算结果表明, (Ca_1-xSr_x)12A7:e ^-与C12A7:e ^-相比, 框架导带下移, 费米能级附近态密度增加, 这将有利于电输运和发射性能的优化。室温电输运测试结果表明, Sr掺杂有利于C12A7:e ^-电输运性能的优化, 其中(Ca_0.96Sr_0.04)12A7:e ^-样品在室温下具有最高电导率(1136 S/cm)以及最高载流子浓度(2.13×10 ²¹ cm ^-3), 与相同条件下制备的C12A7:e ^-样品相比, 载流子浓度提高近2个数量级, 表明Sr掺杂可以有效缩短制备C12A7:e ^-的制备时间。热电子发射性能测试结果表明, 随着Sr掺杂量的增加, 热电子发射性能逐渐提高, 其中(Ca_0.96Sr_0.04)12A7:e ^-样品具有最佳的热发射性能, 在1100 ℃外加电压3500 V时, 发射电流密度达到1.45 A/cm ², 零场发射电流密度达到0.74 A/cm ², 理查生逸出功降低至1.86 eV。     

硅衬底Sr_(1-x)La_xTiO_3薄膜光敏特性研究

利用氩离子束镀膜技术在 Si O2 / Si衬底上淀积钛酸镧锶 (Sr1 - x L ax Ti O3)膜 ,并制成平面型电阻器。研究了薄膜电阻器的光电流与照度、电压和电极间距的关系以及薄膜在调制光下的频率特性 ,计算出薄膜中载流子寿命约为 2 9ms。结果表明 ,Sr1 - x L ax Ti O3薄膜在可见光区域具有较好的光敏特性 ,其灵敏度和光电导增益都比较高。在弱照度下 ,光电流随照度变化较快 ,主要与单分子复合过程相关 ;而在强照度下 ,变化趋于缓慢 ,这与双分子复合过程有关     

Nd:YAG激光、锶90β射线与压迫综合治疗耳垂增殖性瘢痕

目的：了解Nd：YAG激光、锶^90β射线与压迫综合治疗耳垂增殖性瘢痕的疗效。方法：将耳垂增殖性瘢痕病人69例分为两组，A组手术切除后采用Nd：YAG激光、锶^90β射线和压迫综合治疗，B组手术后仅使用锶^90β射线与压迫治疗，随访观察比较临床效果。结果：A组总有效率为82．86％，B组总有效率为67．64％。A组有效率高于B组。结论：手术后采用Nd：YAG激光、锶^90β射线和压迫综合治疗耳垂增殖性瘢痕效果明显。     

未掺杂与Sr掺杂的LaMnO_3钙钛矿氧化物热力学计算(英文)

计算了未掺杂与Sr掺杂的LaMnO3 钙钛矿氧化物的热力学数据 .计算与实验结果吻合较好 .这些热力学数据可以用来估计复合物的化学稳定性值以及与其它材料间的化学反应性 .     

XPS Studies on Rare Earth Oxide LSCO／YSZ Electrodes

The X-ray diffraction spectra and X-my photoelectron spectroscopy were measured for Sr-doped Lal-xSrx CoO3 materials with perovskite structure prepared by the solid-state reaction method. The influence of heat-treatment tempera-ture on the average crystal size of Lal-xSrx CoO3 was studied. The surface chemical states of Lal-xSrxCoO3 cathodes with different Sr-doped content were discussed. The experimental results show that average crystal size of Lal-xSrxCoO3 under the condition of heat-treatment in the range of 900- 1200℃ is larger than that at other temperatures, which is of benefit to forming porous electrodes. When La is replaced by Sr gradually, the oxygen vacancy concentration increases. It is of benefit to enhancing the transport property of oxygen ion.     

The surface morphologies of (Pb, Sr) TiO3 thin film fabricated on Si-buffered Pt/Ti/SiO2/Si substrate

(Pb, Sr)TiO3 (PST) thin film are fabricated by RF magnetron sputtering on Si-buffered Pt/Ti/SiO2/Si substrates with different buffer layer deposition time. Surface morphologies of the buffer layer indicate an improving surface roughness and larger grains with the prolongation of sputtering time. Deposition of PST thin films shows excellent surface fluctuation filling ability to improve the surface roughness of substrates. PST surface morphologies exhibit apparently different grain forms according to the preparation time durance of buffer layer.     

纳滤法去除模拟放射性废水中Sr~(2+)的研究

采用XN45聚酰胺复合纳滤膜处理含锶(Sr2+)的模拟放射性废水.考察了初始离子浓度、溶液pH、离子强度和投加络合剂等情况下对Sr2+截留率的影响.结果表明,Sr2+截留率随着初始离子浓度和离子强度的增加而有所降低;pH升高时,截留率在一定pH范围内先降低后升高,在等电点(pH 5)附近达到最小值;在分别以聚丙烯酸和乙二胺四乙酸二钠(EDTA-2Na)作为络合剂的情况下,Sr2+的截留率均得到了提高,其中在[PAA]/[Sr](质量浓度比,下同)=5,pH7或[EDTA-2Na]/[Sr]=4,pH=9的情况下,Sr2+截留率均达到98%以上.     

Ca和Sr对AZ91D镁合金低周疲劳性能的影响

研究了合金元素Ca、Sr复合添加对金属型铸造镁合金AZ91D的低周疲劳性能的影响。通过运用控制总应变幅0.05 mm～0.25 mm范围内,在应力比R=-1条件下施加拉-压载荷,测试不同状态下合金的低周疲劳性能,并利用光学电子显微镜观察了材料在不同状态下的显微组织及低周疲劳断口特征。结果表明:Ca、Sr元素的添加能细化铸态AZ91D镁合金的晶粒,复合加入0.4%Ca和0.3%Sr,可以提高镁合金的低周疲劳性能。     

Nest-like structures of Sr doped Bi2WO6: Synthesis and enhanced photocatalytic properties

A series of Sr-doped Bi₂WO₆ with three-dimensional (3D) nest-like structures were synthesized through simple hydrothermal route and characterized by XRD, FESEM, TEM, XPS, UV-vis DRS, etc. Morphology observation revealed that the as-synthesized Bi₂WO₆ were self-assembled three-dimensional (3D) nest-like structures, which were constructed from nanoplates. UV-vis diffuse reflectance spectra indicated that the samples had absorption in both UV and visible light areas. Their photocatalytic activities were evaluated by photodegradation of rhodamine B (RhB) under UV and visible light irradiation (λ > 420 nm). The photocatalytic properties were enhanced after Sr doping. Samples subsequently thermal treated at 500 °C showed higher photocatalytic activities. The reasons for the differences in the photocatalytic activities of these nest-like Bi₂WO₆ microstructures were further investigated.     

Mg-TiB2中间合金和Sr对AZ91D镁合金显微组织的细化

采用SEM、EDS和XRD等测试手段研究了粉末原位合成法制备的Mg-50%TiB2(质量分数,下同)中间合金的组织和结构,以及Mg-50%TiB2和Sr对AZ91D镁合金显微组织的细化效果。结果表明,1.4%(Mg-50%TiB2)中间合金和0.1%Sr的复合添加可使AZ91D镁合金的α-Mg晶粒尺寸由基体合金的240μm降至49μm。通过面错配度计算证实TiB2可成为初生-αMg的良好异质核心。加入碱土元素Sr引起合金成分过冷度增加,从而激活固/液界面前沿潜在的TiB2核心,提高TiB2的形核率。