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41.
S. Yildirim R. G. Fuentes R. Evangelista Z. L. Nikoloy 《Journal of the American Oil Chemists' Society》2002,79(8):809-814
Two germ-separation methods, dry-milling and density separation by flotation, were evaluated for recovering recombinant β-glucuronidase
(rGUS) that accumulated primarily in the germ of transgenic corn. The dry-milling process consisted of (i) seed tempering,
(ii) degerming with a horizontal-drum degermer/dehuller, (iii) particle size fractionation with standard sieves, (iv) germ
and endosperm separation by roller milling and sifting, and (v) removal of hulls by aspiration. Sieves nos. 5, 6, and 7 retained
the majority of germ, and subfractions from these sieves were pooled as a germ-rich fraction. Mass balances showed that the
germ-rich fraction, which constituted 17% of the total dry-milled corn weight, contained 49% of rGUS activity and 64% of the
total recoverable oil. Germ fractionation by flotation was tested as a proof-of-concept method aimed at separating corn fractions
based on their difference in specific gravity (sp gr). The process consisted of impact-grinding of corn kernels followed by
density separation using 1.15 or 1.3 specific gravity sodium nitrate solution. The oil-containing germ fraction floated, whereas
the heavier endosperm fraction sedimented. The flotation method was simpler and resulted in higher enzyme recovery, that is,
the germ-rich fraction was 20% (w/w) of the initial corn weight, and accounted for 80% of rGUS activity and 77% of total oil.
The sodium nitrate solution did not have an adverse effect on the enzyme activity. 相似文献
42.
43.
通过煤泥窄粒级浮选速率实验,以煤泥浮选一级动力学为基础,对煤泥浮选动力学的关键参数进行研究,包括最大可燃体回收率ε∞的计算、浮选级数n的确定、浮选速率常数K的变化.结果表明:浮选动力学模型中ε∞的经验解比模型解更符合实际;窄粒级煤泥的浮选动力学级数最符合一级动力学;窄粒级煤泥的浮选速率常数K是时间的函数,可用幂函数或经验公式表达,先求出ε∞的经验解,再求解K(t)函数,所得模型非常符合煤泥浮选特征的浮选动力学模型. 相似文献
44.
Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated. To evaluate the performance of a frother, an apparatus to measure the bubble size is a basic necessity. McGill Bubble Size Analyzer (MBSA) or bubble viewer that has been developed and completed by McGill University's Mineral Processing Group during the last decade is a unique instrument to serve this purpose. Two parameters which are thought to influence the bubble size measurements by McGill bubble viewer include water quality and frother concentration in the chamber. Results show that there is no difference in Sauter mean (D32) when tap or de-ionized water was used instead of process water. However, the frother concentration, in this research DowFroth 250 (DF250), inside the chamber exhibited a pronounced effect on bubble size. Frother concentration below a certain point can not prevent coalescence inside the chamber and therefore caution must be taken in plant applications. It was also noted that the frother concentration which has been so far practiced in plant measurements (CCC75-CCC95) is high enough to prevent coalescence with the bubble viewer. 相似文献
45.
The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved. Meanwhile, it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation, as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst. This causes the increased concentration in the froth compared to the bulk concentration, named as frother partitioning. Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known. There currently exists no such a topic aiming to link these two key parameters. To fill this vacancy, the correspondence between bubble size and frother partitioning was examined. Bubble size was measured by sampling-for-imaging (SFI) technique. Using total organic carbon (TOC) analysis to measure the frother partitioning between froth and bulk phases was determined. Measurements have shown, with no exceptions including four different frothers, higher frother concentration is in the bulk than in the froth. The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two, represented byCFroth/CBulk andD32. TheCFroth/CBulk andD32 curves show similar exponential decay relationships as a function of added frother in the system, strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction. 相似文献
46.
柯家骏 《稀有金属(英文版)》1992,(3)
Scandium was recovered from dilute chloride solutions with potassium salt of saturated C_8~C_(12)fattyacids as surfactant by Ion flotation.The optimum comprehensive results of physical properties,stability andscandium concentration of the foam formed with potassium caprate CH_3(CH_2)_8 COOK can be obtained.Re-covery of scandium in the foam was 98% at pH 3.8~5.0 and 25~55℃.The experimental results of 0.3 L/minairflow rate was satisfactory for flotation column.It is of a great potential for using ion flotation technique toconcentrate scandium from dilute solutions. 相似文献
47.
1 INTRODUCTIONThereservesofniobium containingmineralsinChinatakethesecondplaceintheworld ,anddis tributemainlyinBaiyuneboofInnerMongolia ,TaimeiofGuangdongProvinceandYichunofJiangxiProvince ,etc .Niobium containingmineralsweredis coveredover 130kinds ,butonlyafewofthemhadindustrialvalue .Fersmiteisoneoftheseveralvaluedindustrialniobium containingminerals[1,2 ] .Theprocessingofniobium containingmineralsistoodifficultduetotheirfinesizeandnumerousspeciesandcomplexcomposing .Inmiddleperi… 相似文献
48.
49.
Activation of sphalerite ZnS, (Zn, Fe)S, (Zn, Cu)S were carried out using the density functional theory (DFT) method. The electronic structures and related properties of three kind of zinc sulfide compounds were investigated. In addition, the relation between electronic structure and flotation behavior was discussed. The results show that, ZnS has a broader band gap than (Zn,Cu)S and (Zn,Fe)S do, and it has low electrochemistry activity to react with flotation collectors to render the surface hydrophobic. When the Zn atom in ZnS is replaced by Cu atom,the band gap will be reduced, and the top valence band will be occupied by Cu 3d orbit, thus it is beneficial to the interaction between mineral surface and collector. 相似文献
50.
氯化钠对铝硅矿物浮选的影响及其作用机理 总被引:4,自引:0,他引:4
采用季铵盐DTAL作捕收剂,研究了氯化钠对一水硬铝石和叶蜡石浮选的影响及其作用机理.随着氯化钠浓度的增加,叶蜡石的浮选回收率显著提高,而一水硬铝石的可浮性受其影响很小.机理研究表明:氯化钠对一水硬铝石的zeta-电位没有影响,而能显著降低叶蜡石的zeta-电位,增强捕收剂与叶腊石的静电作用,促进捕收剂的吸附而活化其浮选;叶蜡石表面电位的降低是因为氯离子对叶蜡石存在选择性吸附作用并对其结构进行插层,使得叶蜡石的层间距从0.93 nm增大至1.40 nm.溶液化学计算表明:氯化钠改变溶液的离子强度,显著降低了季铵盐阳离子表面活性剂的临界胶束浓度,使得吸附了捕收剂的矿物表面更容易疏水上浮. 相似文献