Electrochemical gold deposition from sulfite solution: application for subsequent polyaniline layer formation

Electrochemical gold deposition from sulfite solutions was studied by means of voltammetry, EIS and EQCM. A gold film electrode was used for polyaniline layer formation by electrochemical oxidation of aniline. The standard electrochemical reduction potential of the reaction [Au(SO₃)₂]³⁻ + e⁻ = Au + 2 SO₃²⁻ was determined, and is equal to 0.116 V (vs. NHE). Both solution stirring and temperature increase accelerate the electrochemical reduction of gold, when the electrode potential is below −0.55 V. When the potential is above −0.55 V the electrochemical reduction proceeds via passive layer formation. Our study suggests that the passive layer consists of chemically adsorbed sulfite ions and sulfur. The gold film deposited from sulfite solution is a high quality substrate suitable for conducting polymer layer formation. This technique, where a polymer layer electrode is prepared by thin gold film deposition onto a metal surface and by subsequent polymer layer formation, can be applied in sensor research and technology.     

对苯二甲酸加氢精制钯炭催化剂硫中毒原因初探

通过在实验室中进行对苯二甲酸加氢精制钯炭催化剂的硫中毒试验,初步探讨了钯炭催化剂在对苯二甲酸加氢精制反应过程中发生硫中毒的可能原因和机理。     

中国煤中硫氮的赋存状态研究

煤中的硫、氮在煤利用转化过程中的释放对环境和生物健康影响巨大。笔者从煤中硫、氮的分布、结构,同位素研究等几方面对中国煤中硫、氮的赋存状态研究进行了总结,并提出了今后的研究方向和热点问题。     

11 New Rubber Standards in China Going into Effect from March 1

正Since March 1,11 standards of China's rubber industry came into effect,including 6 state standards and 5 industry standards.6 state standards include:Conveyer Belts and Marks(GB/T 5752-2013),Steel Cord Conveyor Belts,Cord-to-coating Bond Test and Initial Test and After Thermal Treatment(GB/T 5755-2013),Conveyor Belts and Adhesive Strength Between Constitutive Elements     

Sulfur addition to aldimines: thioamides,not thiaziridines,as products; revision of an old report

The reaction of 4-(phenylimino)butan-2-ol with ammonium polysulfide in refluxing EtOH yields 3-hydroxy-N-phenylbutanethioamide as the only isolated product. The structure has been established by single-crystal X-ray diffraction. Treatment of N-benzylidenamines with ammonium polysulfide has proven a general method for the preparation of thiobenzamides.     

关于如何对低硫灰口铸铁进行孕育处理的探讨

研究了低硫情况下电炉熔炼如何改进孕育效果的方法．研究表明，对含硫较低铸铁的孕育方法的改进，不一定非要通过补硫或改善孕育剂的方法来实现；通过增加原有孕育剂的数量、改进孕育方法同样能改善孕育效果．     

循环流化床锅炉脱硫的工业试验及模型预测

通过在７５ｔ／ｈ循环流化床锅炉上所进行的试验研究,取得了加石灰石脱硫的动态特性。依据循环流化床锅炉运行特点,对原有的循环流化床锅炉脱硫模型进行了部分改进,成为已建的循环流化床锅炉总体数学模型的一个子模型。运用该模型对循环流化床锅炉炉内ＳＯ２的生成和脱除进行模拟,模拟结果与工业试验结果吻合。模拟结果还揭示了加石灰石脱硫对循环流化床锅炉运行的影响。     

Effect of the composition of some sulphide minerals on cyanidation and use of lead nitrate and oxygen to alleviate their impact

An investigation was carried out on synthetic ores containing high purity pyrite, pyrrhotite and chalcopyrite and on two gold ores currently processed to evaluate the impact of cyanicides on cyanidation and to improve the leaching performance by using a pre-leaching, injecting oxygen and adding lead nitrate. With regard to the synthetic ores, it was found that pyrrhotite did not generate a high cyanide consumption while pyrite and chalcopyrite were detrimental. Pre-leaching was deleterious for the ore containing chalcopyrite while pre-leaching with lead nitrate was very efficient to decrease the reactivity of the ore containing pyrite. The two gold ores studied had very different compositions. The low sulphide ore had a low sulphide content (1.36% S), present as pyrrhotite while the second had a very high sulphide content (20.2% S), in the form of pyrite, pyrrhotite and chalcopyrite. The efficiency of the process conditions was peculiar to the ores. The high sulphide ore required a stronger, longer pre-leaching period (12 h) with greater amounts of lime (7.0 kg/t) and lead nitrate (600 g/t) than the low-sulphide ore. The ore with a low sulphide content required a pre-leaching of only 1 h with a small quantity of Pb(NO₃)₂ (50 g/t) and leaching can be performed at 360 ppm NaCN to allow a recovery of 96.4% Au and a low cyanide consumption at 0.18 kg/t. As for the high sulphide ore, cyanidation had to be conducted at 560 ppm NaCN to recover 88.4% Au with a cyanide consumption of 0.80 kg/t. An increase in the amount of lime enhanced oxidation of soluble sulphides. Lead nitrate stabilized copper and iron dissolution by forming a passivation layer at the surface of sulphide minerals. Lead nitrate also prevented the formation of a passive layer at the surface of gold.     

Nitrate Removal in Sulfur: Limestone Pond Reactors

The feasibility of using sulfur:limestone autotrophic denitrification (SLAD) pond reactors to treat nitrate-contaminated water or wastewater after secondary treatment was investigated with four lab-scale continuously fed SLAD ponds. The start-up period, temperature effects, and effects of different feed solutions were evaluated. With an influent concentration of 30 mg NO3?–N/L at an HRT of 30 days, the pond reactors had an overall nitrate removal efficiency of 85–100%. Effluent nitrite concentrations were <0.2 mg N/L in all tests. Aerobic conditions could result in a decrease of the SLAD pH of the pond by 2 to 3 units and a large increase in sulfate production ( ～ 1600–1800?mg-SO42?/L). Under unmixed (anoxic) conditions, the pH and sulfate produced were maintained at approximately 5.5 to 5.6 and 400–600?mg-SO42?/L, respectively, in all the SLAD ponds. Temperature affected the pond reactors adversely. By assuming that a first-order reaction occurred in a SLAD pond reactor, the temperature-activity coefficient, θ was found to be 1.068. Treatment of nitrate-contaminated surface water and wastewater using SLAD pond systems is feasible only if (1) the chemical oxygen demand (COD)/nitrate–N (COD/N) ratio is low (<1.2 with an initial NO3? concentration of 30 mg-N/L), (2) sulfur:limestone granules are not covered by sediment, and (3) sulfur-utilizing but nondenitrifying bacteria (SUNDB) are greatly inhibited due to the lack of DO in the pond systems. The SLAD ponds are not feasible for the treatment of raw wastewater or surface water if they contain high concentrations of organic matters due to the possible inhibition of sulfur-based autotrophic denitrifiers by heterotrophs (including heterotrophic denitrifiers). In addition, a high sulfate and low DO concentration as well as a low pH in the SLAD effluent of the pond (even when the pond is operated in an unmixed mode) also will limit the application of SLAD pond processes.     

大冶铁矿分离浮选药剂对硫精矿脱水过程的影响

在实验室条件下对影响硫精矿滤饼水份的原理进行了研究。研究表明大冶铁矿分离浮选所用的药剂对硫精矿的脱水过程有影响,影响硫精矿滤饼水份的主要因素是分离浮选中作为黄铁矿抑制剂使用的石灰,同时Ｚ－２００＃捕收剂对硫精矿的滤饼水份也有不利影响,但其影响程度比石灰要小。用硫酸调节硫精矿矿浆的ＰＨ值可以降低其滤饼水份。