Catalytic wall reactor: Catalytic coatings of stainless steel by VOx/TiO2 and Co/SiO2 catalysts

Catalytic wall (structured) reactors and structured supports are suitable to study the catalytic properties of nanosized materials. The coating of metallic (aluminum and stainless steel) plates by thin layers of active phase is presented in two cases, VO_x/TiO₂ and Co/SiO₂, catalysts used in the oxidative dehydrogenation (ODH) of propane and in Fischer–Tropsch synthesis (FTS) of clean fuels, respectively. The preparation of coated plates and their characterisation by various methods of physicochemical analysis are described. Both chemical and physical methods were used for coating. VO_x/TiO₂ layers were obtained by grafting of Ti (on Al or stainless-steel plates) and V (on TiO₂) alkoxides and use of sol–gel media or suspension. A silica primer was deposited (on stainless-steel plate) by plasma-assisted chemical vapour deposition (PACVD) onto which Co oxide and silica were coprecipitated from sol–gel. The catalytic experiments in the respective reactions were carried out in special plate reactors and compared with those of catalytic powders. The study shows that the coating of a metallic substrate by a catalyst is not straightforward and requires specific studies dealing with both chemistry (chemical affinity between substrate and catalytic layers) and catalytic engineering (catalytic performance in taylor-made reactors).     

计算机网络安全与防护技术研究

本文主要对计算机网络安全产生的根源和存在的风险进行了初步分析,对目前常用的网络安全技术进行了较为深入的研究,并阐述了防火墙技术与入侵检测技术在计算机网路中联合部署的方法和步骤.     

Heat transfer of gas flow through a packed bed

This paper reports an experimental study of both the transient and steady-state heat transfer behaviour of a gas flowing through a packed bed under the constant wall temperature conditions. Effective thermal conductivities and convective heat transfer coefficient are derived based on the steady-state measurements and the two-dimensional axial dispersion plug flow (2DADPF) model. The results reveal a large temperature drop at the wall region and the temperature drop depends on the axial distance from the inlet. The 2DADPF model predicts the axial temperature distribution fairly well, but the prediction is poor for the radial temperature distribution. Length-dependent behaviour of the effective heat transfer parameters and non-uniform flow behaviour are proposed to be responsible. A comparison with previously published correlations and data in the literature shows that the relationships proposed by Bunnell et al. and Demirel et al. agree well with the measured effective radial thermal conductivity, whereas the wall-fluid heat transfer coefficient is better represented by the Li-Finlayson correlation.     

高压旋喷灌浆在锦屏二级电站进水口围堰防渗中的运用

锦屏二级水电站进水口纵向围堰防渗设计采用塑性砼防渗墙,施工中发现,防渗墙实际施工深度远远超过设计深度,这将意味着增加施工成本,延长施工工期．为解决这一问题,在施工中将部分深槽段修改为悬挂式塑性砼防渗墙,针对其未达到截渗的目的,在塑性砼防渗墙中预埋钢管,对其下部进行高压旋喷灌浆,形成高喷防渗墙,经检测防渗效果满足要求,达到了节约投资,缩短工期的目的．     

钢板剪力墙的分类及性能

对钢板剪力墙结构进行分类讨论,分析了墙板本身的力学性能、使用性能以及与框架的相互作用;探讨了内嵌钢板与框架栓接或焊接的典型连接方式,并从制作安装、使用性能和对墙板性能的影响3个方面比较了栓接与焊接的优劣;分析了各类钢板剪力墙的特点和适用范围,为设计人员在工程应用中选择恰当的钢板剪力墙类型提供了参考。     

地下连续墙施工变形监测与结果分析

以抚州市电力大厦为例,监测其地下连续墙的水平位移和沉降监测。从水平位移监测值来看,北侧的水平位移较大,D8的位移达到预警值,D5临近预警值,为此,在1层开挖位移增加值较大处（深度为4．2m）加大对部分观测点的观测频数,并加强北面的支护体系,增加角支撑,并在长边增加2根对撑。沉降变化曲线表明：地下连续墙墙顶在整个开挖过程中存在一个波浪式的抬升现象。除第V阶段开挖过程因开挖面积及土方量均较小、反应不明显外,伴随着每次挖土过程地下连续墙墙顶均有一次明显的抬升过程,在楼板的制作和养护期间,墙顶先下沉后逐渐趋于稳定,大底板浇筑后墙顶又逐渐下沉。     

填充墙作用框架结构动力分析

目的 为了解填充墙对框架结构振动周期、振动形态、动力反应等的影响特点,给结构设计提供参考和建议.方法 建立了29个带填充墙的框架结构空间有限元对比分析模型,研究了结构的自振周期、振型特点,并且输入三种不同的地震波进行了时程分析.结果 填充墙体对结构振动形态的影响不明显,但是当因减少填充墙体造成的"薄弱楼层"在建筑底部时,对结构的整体振动形态影响较大.随着填充材料刚度的减小,填充墙较少楼层处的刚度突变减弱,振型曲线更趋平滑;通过对比有限元方法 和简化手算方法 所得结构自振周期,认为考虑填充墙体影响时框架的自振周期折减系数取0.6较为合适;填充墙体的材料、位置、布置方式等对框架结构的动力时程反应均有一定影响.结论 在进行框架结构填充墙体布置时应注意将其均匀分布于框架结构中,并尽量不在中部楼层设置过少的墙体;在结构计算时对填充墙框架自振周期应进行折减.     

高强钢筋高强混凝土剪力墙抗震性能试验

目的 研究高强混凝土剪力墙的抗震性能、破坏形式和机理.方法 通过在剪力墙中配置高强钢筋,利用高强钢筋高强度、低松弛、强握裹力以及良好塑性性能等特点,增强对高强混凝土的约束,提高高强混凝土剪力墙的承栽和变形能力.通过5片高强混凝土剪力墙试件的拟静力试验,研究不同的混凝土强度、轴压比和剪跨比等参数对其抗震性能的影响.将1 280MPa预应力钢棒作为箍筋和纵筋配置在剪力墙的边部约束构件(暗柱)以及墙体的分布钢筋中.通过对比研究配置高强钢筋对高强混凝土剪力墙抗震性能的提高效果.结果 明确了高强混凝土剪力墙的不同破坏形态和过程,得出了影响高强混凝土剪力墙抗震性能的主要因素和影响规律.位移延性系数可达3.9,满足结构抗震要求.结论 试验结果 证明在高强混凝土中合理适当地配置高强钢筋,可增强其变形能力.     

夏季极端环境下住宅墙体EPS保温体系热结构耦合分析

以居住建筑保温工程中一个典型开间的外墙为研究对象,采用有限元数值模拟方法,分析了EPS板薄抹灰外墙外保温复合墙体在夏季极端高温、骤降暴雨环境下的热结构耦合反应,结果表明:外界不利环境是引起裂缝或脱落的主要因素之一;聚苯板具有良好的隔热效果;窗洞四角变形较大,是容易出现问题的地方,应当引起重视;由于砂浆与EPS板的交界处变形不协调,裂缝会首先出现在砂浆层或者与EPS板的交界处.     

冲击钻技术在大坝混凝土防渗墙中的应用

文章以香山水库坝体防渗墙施工为例,介绍了冲击钻技术在实际防渗墙中的应用,提出了一套在防渗墙施工中切实可行的施工方法.