Time-resolved spectroscopy of infrared active vibrations in 2,5-dioctyloxy poly(phenylene vinylene) films

We report on picosecond time resolved spectroscopy of photogenerated infrared active vibrations in thin films of 2,5-dioctyloxy poly(phenylene vinylene). We excited the films by ?4 ps long pulses of 565 nm laser light with 2×10¹³ photons/cm² per pulse and repetition rate of 76 MHz. We then followed the temporal evolution of the infrared active vibrational (IRAV) spectrum using a subsequent, variably delayed, weak tunable IR probe pulses of similar temporal duration. Under these conditions, we show clear spectroscopic evidence for photogenerated infrared active vibrations at times which are shorter than our temporal resolution (<4 ps). We suggest that the transient IRAV absorption is due to secondary polarons formation following exciton dissociation.     

MPID─TOF质谱的快速时间分辨微弱信号测试系统

把瞬态记录仪Ｂｉｏｍａｔｉｏｎ８ｌ００与微型计算机ＩＢＭ─ｐＣ／ＸＴ联接建成了一个高速数据采集系统，本文介绍了系统的硬件接口设计及软件设计。在超声分子束条件下，把它应用于环氧乙烷（Ｃ＿２Ｈ＿４Ｏ）的多光子电离与离解飞行时间（ＭＰＩＤ─ＴＯＦ）质谱的实验研究中，并给出了实验结果；本系统在微观基元化学反应动力学实验研究中广泛适用于对时间分辨微弱信号的探测。     

Modeling of Diffusion in Capillary Porous Materials During the Drying Process

This paper presents a model of heterogenous diffusion in capillary porous materials during the process of drying. The governing heat and mass transfer equations have been established using the liquid as well as vapor flow. Two models have been presented. Model 1 does not consider the heat conduction while the model 2 has been established by considering the conduction. The developed models and the numerical solutions of the resulting differential equations can take into account the moisture and temperature dependent thermophysical properties of the product. All equations have been established in spherical coordinates but the programme written for the purpose of calculations can be used for other geometries also. Numerical calculations have been performed for gas concrete and tiles using model 1, while model 2 has been used for gas concrete only because of the lack of data for thermophysical properties of the tile. For gas concrete it was seen that conduction has only marginal effect on the drying process and the numerical predictions of the drying process were reasonably accurate.     

高速往复式内燃机平衡轴低质量设计分析

分析了扇形和偏心圆两种平衡轴设计的要求以及平衡重低质量的设计原则。扇形平衡重半径及宽度应尽量大、夹角应尽量小。偏心圆平衡重的偏心圆半径应尽可能大 ,轴承半径应尽可能小。同样质量的扇形平衡重产生的平衡力比偏心圆平衡重要大。     

CMF300M355NU型质量流量计在油库汽车装车中的应用

介绍了质量流量计的工作原理有应用效果。这种新型质量流量计精度高，稳定性好，示值计量简便，可直接显示质量、流量、介质温度、密度等，维护量低，但必须正确安装、使用，才能发挥其应有的作用。     

Application of annexation principle of thermodynamic property of In-Pb-Sb and In-Bi-Pb melts

Based on the principle of annexation and phase diagrams, the structural units of In-Pb-Sb and In-Bi-Pb melts were determined, and their calculating models of mass action concentrations were formulated. Calculated results agree well with practical values, which in turn show that the models deduced can reflect the structural realities of corresponding melts and the principle of annexation is applicable not only to some binary metallic melts, but also to ternary metallic melts.     

对国际岩石力学委员会J_V公式的质疑

通过对国际岩石力学委员会JV 公式的论证 ,指出了该公式不符合数理逻辑。结合工程勘察实践 ,拟建了Ky新公式 ,提高了工程岩体完整程度评价方法的科学性。     

可持续发展战略指导下的轨道交通规划与评价

提出了轨道交通规划与评价在实施可持续发展战略过程中需要研究的问题，研究重点是轨道交通规划与评价方法体系和环境对策，研究了轨道交通规划目标的变化、轨道交通规划优化决策理论与方法、轨道交通规划中的环境影响评价、城市轨道交通网络的合理规划、城际轨道交通——客运专线/高速铁路线路基本走向的规划、轨道交通规划可持续发展的评价指标体系概念框架、轨道交通系统可持续发展的能力建设问题等，并通过实例验证了所建立的理论方法体系和模型体系；不仅进行了有关理论和方法的探讨，而且以面向实际应用为目标，开发了相应的软件系统，为轨道交