雅砻江楞古水电站场址区宋玉断层活动性研究

楞古水电站位于区域构造复杂的雅砻江中游, 场址周边断裂构造较发育, 场址区内发育有较大的宋玉断层, 研 究其活动性对枢纽建筑布置和工程抗震设防措施均具有重要意义。在遥感解译的基础上, 通过野外验证和追踪调 查, 结合断层构造岩石英形貌扫描、 电子自旋共振(ESR) 测龄和近代地震震中分析, 确定了宋玉断裂的活动年代, 得 出了宋玉断层不属于工程活动断层的结论。     

A spatio‐temporal water quality assessment of the Beas and Sutlej Rivers at the Harike Wetland: A Ramsar site in Punjab,India

Lakes play a vital role in regulating water storage, flow of river water, and ultimately maintaining a balanced ecosystem. Spatial and temporal variations in physicochemical parameters of water in Harike Wetland, a Ramsar site in the northwestern state of Punjab, India, were studied. This study was conducted on a monthly basis from January to December 2015. The water quality was studied at ten locations from sites 1 to 10 upstream, central and downstream from Harike Lake for ten physicochemical parameters, including temperature, pH, electrical conductivity, turbidity, dissolved oxygen concentration biological oxygen demand, nitrate and phosphate concentrations and salinity. The findings of this study revealed that, except for temperature and pH, all parameters exhibited relatively higher values for the Sutlej River, compared with the Beas River, with sampling sites 5 to site 7 exhibiting intermediate results. The mean seasonal temperature variations ranged from 16.9 to 26.6 °C, the pH from 7.7 to 8.2, electrical conductivity from 223 to 303 μS cm^?1 and TDS concentration from 148.7 to 180.4 ppm. Correlation analysis was conducted to assess the relations between the variables. The electrical conductivity exhibited a high positive correlation with salinity and biological oxygen demand, whereas it correlated negatively with the dissolved oxygen concentration. Box and whisker plots were also plotted for the study results to better examine the data distribution.     

相转移催化法合成多聚乙二醇二环氧甘油醚

以多聚乙二醇和环氧氯丙烷为原料合成了多聚乙二醇二环氧甘油醚。NaOH为催化剂,季铵盐为相转移催化剂。结论为:作为催化剂NaOH固体效果优于NaOH溶液;四正丁基硫酸氢铵(TBAS)催化醚化反应效果最佳,GC监测表明,二醚的选择性达98％以上;n(多聚乙二醇):n(环氧氯丙烷):n(NaOH):n(TBAS)= 1:10:7:0．08;反应温度55-60℃;反应时间1．5 h;产率83％。     

杀虫植物的研究新进展及应用发展前景

介绍了近几年杀虫植物研究的新进展，主要包括楝科、卫矛科、豆科、菊科、胡椒科、百部科、瑞香科等科杀虫植物的作用方式和部分植物的有效成分与作用机制及杀虫植物的应用概况，并分析了其应用发展前景。     

基于磁流变阻尼器的车辆悬架系统模糊半主动控制

在对磁流变液和磁流变阻尼器的研究基础上 ,以磁流变阻尼器作为半主动控制元件组成模糊半主动悬架系统。运用数值仿真和试验研究等方法对基于磁流变阻尼器的模糊半主动悬架进行了研究。数值仿真和试验结果表明 ,设计的模糊半主动控制算法可对基于磁流变阻尼器的半主动控制悬架实现有效的控制     

Role of Acetic Acid Added to the Reaction Media for the Enantio-differentiating Hydrogenation of Methyl Acetoacetate Over a Tartaric Acid-modified Nickel Catalyst

The role of acetic acid added to the reaction media for the enantio-differentiating hydrogenation of methyl acetoacetate over a (R,R)-tartaric acid-in-situ-modified nickel catalyst was studied from the viewpoint of the hydrogenation rate during repeated runs. The hydrogenation of methyl acetoacetate on the “enantio-differentiating sites” of a tartaric acid-modified nickel catalyst was specifically accelerated by the acetic acid added to the reaction media to increase the enantio-differentiating ability of the catalyst. In order to increase the enantio-differentiating ability, the addition of acetic acid to the reaction media was required in each run during the repeated use of the catalyst.     

A molecular level mechanism ofn-butane oxidation to maleic anhydride over vanadyl pyrophosphate

A molecular level mechanism is proposed for the highly selective 14-e^– oxidative transformation ofn-butane to maleic anhydride on the surface of vanadyl pyrophosphate. The mechanism suggests that the dimeric active sites assume at any given time, one of four possible interconvertible states which differ from each other in the number of available oxygen atoms and the formal oxidation states of the individual vanadium atoms. The relative ratios of active sites in each of the four possible states are dictated by the reaction conditions, the redox properties of the reacting gases and the structure of the vanadyl pyrophosphate active surface. A crucial feature of the mechanism is a pseudo-ozonide surface species formed by the interaction of a chemisorbed dioxygen molecule and an adjacent metal-oxo group. This unusual species is responsible for the initial activation of then-butane, which occurs when the chemisorbed dioxygen abstracts an H-atom from the alkane and the adjacent metal-oxo group reacts with the incipient alkyl radical to form an alkoxy group. The proposed mechanism is entirely consistent with literature reports describing the behaviour of (VO)₂P₂O₇ in flow, pulse and TAP reactors.     

跨国化工企业在我国的投资现状

由于市场、人力资源及成本的优势,跨过公司在我国的投资不断增加,我国已成为全球研发投资项目的最大积聚地。介绍了近几年跨国化工企业在我国投资的项目情况,新一轮的投资主要集中在长江三角洲地区。随着众多跨国公司的签约,催生了南京化学工业园区、上海化学工业区、泉州泉港石化工业区,惠州大亚湾石油化学工业区,同时也将一体化基地的理念带入中国。     

乙酰乙酸乙酯与乙二醇在活性炭负载磷钨酸催化剂上合反应

表面活性剂处理的活性炭（C）过量浸渍负载磷钨杂多酸（PW）制备活性炭负载磷钨酸催化剂（PW／c）；氨气程序升温脱咐对催化剂酸性质表征，结果显示，负载质量分数为30％，催化剂30％PW／C具有最大酸量。反应测试表明，磷钨酸负载量为30％时催化剂具有最大活性，苹果酯收率为87．5％，适宜的原料配比。（乙酰乙酸乙酯）：n（乙二醇）=1：1.5，最佳反应温度80℃，最佳反应时间30min，表面活性剂处理过的催化剂连续使用9次，苹果酯的收率保持在85％以上。     

工业有害废物填埋场渗析液处理设计

根据工业有害废物填埋场渗析液中含有多组份重金属以及水量的不连续性和出水回用的特点 ,采用化学处理法与过滤、吸附相结合的方法处理此渗析液 ,使出水达到国标“农业浇灌用水”标准的要求