FRP与混凝土组合结构研究综述

提出一种在塑性铰区域采用高延性纤维增强水泥基复合材料(ECC)替代混凝土来改善FRP筋-钢筋增强混凝土柱抗震性能的新方法。对FRP筋-钢筋增强ECC-混凝土构件进行了低周往复荷载试验,系统地考察了基体材料、筋材种类、轴压比对构件破坏模态、裂缝模式、承载力、残余变形、延性和耗能能力的影响。结果表明,将ECC替代塑性铰区域混凝土能够有效避免FRP筋的受压屈曲,进而显著提升组合柱的抗震性能。与钢筋增强ECC-混凝土组合柱相比,复合筋增强ECC-混凝土组合柱的残余变形明显更小,且屈服后的刚度更高。随着轴压比的增大,构件极限强度升高但变形能力降低。通过有限元参数分析可知,组合柱的承载力和变形能力均随着ECC抗压强度及总配筋率的增大而增大;在总配筋率不变的情况下,FRP筋占比越高,构件的延性越好。     

新型氧化钯在高真空多层绝热设备中不同数量级真空度下吸氢特性实验研究

氧化钯被公认为性能优良的吸氢剂之一。常应用于高真空多层绝热设备中维持真空。本文通过搭建实验台系统地研究新型氧化钯在不同数量级的真空度下吸氢性能、吸附速率、吸氢效率、吸附量以及平衡压强之间的关系。实验结果表明新型氧化钯最优维持的真空度为0.016 Pa,饱和吸附量为197.238 mL/g,吸附系数为60.473。并通过31组在1、10^-1和10^-2Pa不同数量级上反复加注氢气,观察其吸氢动态。结果表明初始加气压强2.7 Pa以下,吸氢动态曲线均呈现\     

柴油耦合氧化吸附脱硫的研究

采用氧化-吸附耦合技术,将硫化物氧化为极性较高的砜类,利用极性溶剂将大部分砜类化合物莘取出后,残留于油品中的古硫化合物经孔隙结构发达的活性炭纤维选择性吸附,从而实现柴油的深度脱硫,其脱硫率高达94％。色谱测试研究表明该工艺可脱除柴油中的绝大多数含硫化合物,尤其对加氧工艺难以脱除的二苯并噻吩类化合物具有很高的脱除率;且氧化吸附后的油品具有强的氧化安定性;与加氢工艺相比,此法操作简便,反应条件温和,勿需氧源,可深度脱硫。     

基于信息检索课的大学生信息检索行为调查研究

信息检索课程的系统化讲授,对于大学生优化信息检索行为,提高信息检索使用效率具有不容忽视的教学辅助作用.立足问卷调查形成的一系列相关数据,探讨大学生信息检索行为存在问题,最终在课程教学中提出优化大学生信息检索的对策:明确信息检索目的,提升实施效果;有效提升检索行为实施频率,增强综合质量;使得信息获取多元发展,优化成效凸显...     

大孔吸附树脂对酪蛋白非磷肽吸附性的研究

从12种大孔吸附树脂中筛选出一种对酪蛋白非磷肽（NPP）吸附性能强的树脂DA201-C,利用这种树脂研究了从缓冲液中纯化酪蛋白非磷肽。研究结果表明,NPP溶液的pH、NPP溶液流过吸附柱的速度、洗脱剂乙醇的浓度等因素都对NPP的回收率有影响。采用DA201-C大孔吸附树脂纯化NPP,回收率可达95.51%。      

外加水分对煤层瓦斯压力测定的影响分析

针对钻孔及煤岩层水对瓦斯压力测定的影响问题,从宏观影响和微观效应两方面分析了水对直接法测定煤层瓦斯压力的影响。宏观影响主要是由水的重力产生的,可以通过测试后计量钻孔中水分进行修正;微观效应通过实验室开展水对煤中瓦斯的置换实验进行分析。实验表明:水能够置换煤微孔隙中的瓦斯,使吸附态的瓦斯变为游离态瓦斯;在未饱和状态下,煤中含水率在2%～10%时,瓦斯的置换量随含水率的增大而增大,最终平衡的瓦斯压力也变大;从置换速率来看,初期置换速率迅速增加到最大,达到顶峰后进入衰减阶段,衰减趋势比较符合指数衰减规律;从卸压后的瓦斯解吸规律来看,煤样瓦斯解吸量随煤层含水率的增大而减小。考虑到现场测试时测压气室的体积、水对煤的润湿范围、煤的含水率等不确定影响因素,现场尚不能进行水对瓦斯压力影响的定量研究。     

Synthesis and testing of cellulose acetate nicotinate as adsorbent for rhodamine B dye

The esterification of cellulose hydroxyl groups with natural carboxylic acids in mild conditions represents an adequate pathway in obtaining cellulose derivatives with different useful properties. In this article, authors report the synthesis of new mixed ester of cellulose and cellulose acetate nicotinate (CAN) , in a homogenous medium using DMF as solvent, cellulose acetate (CA) as starting cellulosic material, and nicotinic acid as an esterification agent in the presence of p-toluenesulfonyl chloride and pyridine. FTIR and NMR techniques were used to prove the binding of nicotinoyl group at free hydroxyl groups of CA. The obtained CAN was electrospun by electrospinning technique to obtain adsorbent ultrafine fibers, evidenced by SEM images, with high specific surface area. Monolayer Langmuir and empirical Leundrich isotherms were used to assess the adsorption capacity for rhodamine B dye of electrospun CAN in comparison with that of electrospun CA used as starting material. Langmuir isotherm led to a better assessment of experimental data suggesting that the adsorption is mainly determined by hydrogen bonds formed between carboxylic OH hydrogen bonding donor and pyridine N hydrogen bonding acceptor. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47772.     

The dual capacity of the NiSn alloy/MWCNT nanocomposite for sodium and hydrogen ions storage using porous Cu foam as a current collector

A nanostructured NiSn alloy/multi-walled carbon nanotube (MWCNT) composite was successfully synthesized for highly reversible sodium and hydrogen ions storage by using an electrochemical deposition process on porous Cu foam. The surface morphology of the resulting NiSn alloy/MWCNT nanocomposite was characterized using a field-emission scanning electron microscope, indicating the formation of sphere-like NiSn alloy nanoparticles with an average size of 190 nm. On the other hand, X-ray diffraction analysis, energy dispersive and Fourier transform infrared spectroscopies were employed to determine the crystalline structure, elemental surface and chemical composition of the nanocomposite electrode. The initial sodium discharge capacity of the electrode was maximized at ∼550 mAh g⁻¹ under the current density of 1000 mA g⁻¹, and a high hydrogen discharge capacity of 5200 mAh g⁻¹ was obtained at 1100 mA g⁻¹ after 20 cycles. A comprehensive comparison between the sodium and hydrogen ions capacities in this study and those of the literature for different materials and structures was also performed. Accordingly, the resulting nanocomposite electrode with dual capacity may offer promising applications in both sodium-ion battery and hydrogen storage.     

基于联合节点行为策略的WSN覆盖控制算法

针对无线传感器网络在对移动目标节点覆盖过程中出现网络能量快速消耗问题，提出了一种基于联合节点行为策略的覆盖算法。根据网络模型建立传感器节点与目标节点从属关系，确定覆盖关联模型；利用概率理论求解邻居节点冗余覆盖度，确定最少传感器节点数量；给出了邻居节点覆盖期望值的求解方法；仿真实验表明，该算法与其他算法在网络覆盖率和网络生存周期两个性能指标上均提升了12.39%和15.01%，从而验证了算法的有效性。