型腔体组件装配尺寸检测技术分析与运用

为解决型腔体组件装配尺寸的检测问题,以某枪型的型腔体组件为例,分析该型腔体组件的结构特点,设计组合型检测装置,实现准确检测目的.归纳总结了型腔体组件装配尺寸检测技术运用过程中检测装置的设计要领,采用设计与被测型腔体组件相匹配的组合型检测装置,有效解决了型腔体组件装配尺寸检测过程中的定位困难、操作繁琐、检测准确性差等问题.该检测技术对确保型腔体组件装配尺寸的检测稳定性、检测可操作性、检测准确性等方面具有现实的指导意义.     

反应堆流场分析的数值模拟

运用CFD分析工具对反应堆内的流场分布进行数值模拟,给出反应堆燃料组件入口处流场的速度和流量分配情况.通过对计算结果的比较分析,对核电厂反应堆内的流动特性有比较全面的了解,从而为反应堆堆内构件的设计和优化提供分析依据.结果表明反应堆内流场采用CFD技术进行模拟计算是可行的.     

石墨烯基气凝胶的制备及油吸附性能研究进展

海上漏油的频繁发生以及采油废水、工业含油污水的大量排放造成水资源大片污染和生态系统平衡的严重破坏。目前，从水体中分离油品和有机污染物已受到越来越多的商业和学术的关注。石墨烯基气凝胶是由二维石墨烯片层组装成的三维宏观材料，因其孔隙率高、比表面积大、密度低、机械性能强等特点在油水分离领域具有广阔的应用前景，已成为当今的研究热点之一。本文结合最新研究进展系统地总结了石墨烯基气凝胶的结构设计、组装及干燥方法，归纳了近年来其在油水分离中的应用进展，并对石墨烯基气凝胶在油水分离领域的研究现状和未来研究方向做了简要评述，以期为该领域的深入探索提供新的视角。     

氟碳飞机蒙皮涂料的研制

介绍了目前国内飞机蒙皮涂料的发展及存在的问题 ,分析讨论了性能优异的氟碳涂料在飞机蒙皮中应用的意义。     

SMS与飞机维修单位安全管理机制建设

SMS的核心理念是运用安全管理模式建立自我监督、自我完善、自我激励的安全机制,这种特性决定了按照传统自上而下的推进方式不能完全发挥出SMS“自系统”的优势,达到系统控制风险的目的。     

μ C/OS-II在车桥总成配置数据管理系统终端中的应用

基于Cortex-M3内核的ARM芯片STM32F107构建的车桥总成数据远程传输终端,包括了CAN通信、串口通信、人机接口、状态指示、电源等单元。CAN驱动芯片MCP2551实现CAN通信驱动,PS2键盘用于数据的录入与修改,LCM屏提供了人机接口对话。软件上嵌入μC/OS-II实时操作系统,建立CAN总线通信、串口通信、人机接口等多任务。实验表明,车桥总成配置数据的录入与修改操作简便,人机对话界面友好,CAN总线数据传输实时准确。     

Self‐assembling metal coatings from phosphated and siloxane‐modified polyurethane dispersions: An analysis of the coating–air interface

Polyurethane dispersion coatings containing phosphate and siloxane chains were evaluated for their self‐assembling properties for a single‐coating system. Dynamic contact angles (DCAs) and X‐ray photoelectron spectroscopy (XPS) were used to study the coating–air interface. The siloxane chains were the predominant species on the surfaces of the coatings. The wetting properties of the coating–air interface were reversed when the coated panels were immersed in an ionic solution, and the decrease in hydrophobicity was linear with time. Results from XPS and DCA analyses were similar. The self‐assembling properties of the coatings could be useful in the development of hydrophobic coatings from hydrophilic polymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 893–899, 2003     

Electrochemical study of a hydrogen diffusion anode-membrane assembly for membrane electrolysis

The membrane electrode assembly (MEA) studied was constituted with a gas diffusion electrode (E-TEK) impregnated with Nafion^® solution which was assembled with a Nafion^® 117 cation exchange membrane under heat and pressure. The MEA was used as anode in a membrane electrolysis (ME) cell with the objective to regenerate HCl and NaOH from NaCl. Current efficiency for hydrogen oxidation was determined and its value is 100%, which indicates that the only reaction occurring at the anode is the oxidation of hydrogen. Current-potential curves, recorded in different conditions, showed a linear variation in the range 0-3000 A m⁻² when hydrochloric acid concentration is below 2 mol dm⁻³. In this case, the overvoltage was shown to be mainly due to the ohmic drop in the membrane and in the layer where Nafion^® impregnation was performed. MEA overvoltage necessary to reach 3000 A m⁻² current density was about 0.12 V. For high HCl concentration (6-8 mol dm⁻³), the MEA overvoltage increased sharply with current density due to the adsorption of chloride anions on platinum catalyst.     

A glue method for fabricating membrane electrode assemblies for direct methanol fuel cells

We present a simple glue method for fabricating membrane electrode assemblies (MEA) for direct methanol fuel cells (DMFC). Rather than the conventional “dry” hot-pressing method that relies solely on hot-pressing at a high pressure and temperature to form a MEA, the “wet” method developed in this work introduces a binding agent, consisting of Nafion^® solution, between a polymer electrolyte membrane (PEM) and an anode/cathode. The introduced binding agent can provide a better adhesion and stronger binding force between a membrane and an electrode, thereby facilitating a better interfacial contact between the electrode and the Nafion^® membrane, which has been proved by scanning electron microscopy (SEM) analyses to the cross-sectional morphology of the MEA after long-term operation. The cell performance characterization showed the MEA fabricated by the glue method was more stable in cell performance than that fabricated by the conventional hot-pressing method. Cyclic voltammetry (CV) results also demonstrated the MEA fabricated by the glue method exhibited a higher electrochemical surface area (ESA) as a result of the improved interfacial contact between the Nafion^® membrane and the electrodes. Finally, the DMFC with the MEA fabricated by the glue method was characterized by the electrochemical impedance spectroscopy (EIS).     

Synthesis and physicochemical characterization of amphiphilic block copolymer self‐aggregates formed by poly(ethylene glycol)‐block‐poly(ϵ‐caprolactone)

Diblock copolymers with different poly(ε‐caprolactone) (PCL) block lengths were synthesized by ring‐opening polymerization of ε‐caprolactone in the presence of monomethoxy poly(ethylene glycol) (mPEG‐OH, MW 2000) as initiator. The self‐aggregation behaviors and microscopic characteristics of the diblock copolymer self‐aggregates, prepared by the diafiltration method, were investigated by using ¹H NMR, dynamic light scattering (DLS), and fluorescence spectroscopy. The PEG–PCL block copolymers formed the self‐aggregate in an aqueous environment by intra‐ and/or intermolecular association between hydrophobic PCL chains. The critical aggregation concentrations of the block copolymer self‐aggregate became lower with increasing hydrophobic PCL block length. On the other hand, reverse trends of mean hydrodynamic diameters were measured by DLS owing to the increasing bulkiness of the hydrophobic chains and hydrophobic interaction between the PCL microdomains. The partition equilibrium constants (K_v) of pyrene, measured by fluorescence spectroscopy, revealed that the inner core hydrophobicity of the nanoparticles increased with increasing PCL chain length. The aggregation number of PCL chain per one hydrophobic microdomain, investigated by the fluorescence quenching method using cetylpyridinium chloride as a quencher, revealed that 4–20 block copolymer chains were needed to form a hydrophobic microdomain, depending on PCL block length. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3520–3527, 2006