氟碳飞机蒙皮涂料的研制

介绍了目前国内飞机蒙皮涂料的发展及存在的问题 ,分析讨论了性能优异的氟碳涂料在飞机蒙皮中应用的意义。     

SMS与飞机维修单位安全管理机制建设

SMS的核心理念是运用安全管理模式建立自我监督、自我完善、自我激励的安全机制,这种特性决定了按照传统自上而下的推进方式不能完全发挥出SMS“自系统”的优势,达到系统控制风险的目的。     

μ C/OS-II在车桥总成配置数据管理系统终端中的应用

基于Cortex-M3内核的ARM芯片STM32F107构建的车桥总成数据远程传输终端,包括了CAN通信、串口通信、人机接口、状态指示、电源等单元。CAN驱动芯片MCP2551实现CAN通信驱动,PS2键盘用于数据的录入与修改,LCM屏提供了人机接口对话。软件上嵌入μC/OS-II实时操作系统,建立CAN总线通信、串口通信、人机接口等多任务。实验表明,车桥总成配置数据的录入与修改操作简便,人机对话界面友好,CAN总线数据传输实时准确。     

Self‐assembling metal coatings from phosphated and siloxane‐modified polyurethane dispersions: An analysis of the coating–air interface

Polyurethane dispersion coatings containing phosphate and siloxane chains were evaluated for their self‐assembling properties for a single‐coating system. Dynamic contact angles (DCAs) and X‐ray photoelectron spectroscopy (XPS) were used to study the coating–air interface. The siloxane chains were the predominant species on the surfaces of the coatings. The wetting properties of the coating–air interface were reversed when the coated panels were immersed in an ionic solution, and the decrease in hydrophobicity was linear with time. Results from XPS and DCA analyses were similar. The self‐assembling properties of the coatings could be useful in the development of hydrophobic coatings from hydrophilic polymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 893–899, 2003     

Electrochemical study of a hydrogen diffusion anode-membrane assembly for membrane electrolysis

The membrane electrode assembly (MEA) studied was constituted with a gas diffusion electrode (E-TEK) impregnated with Nafion^® solution which was assembled with a Nafion^® 117 cation exchange membrane under heat and pressure. The MEA was used as anode in a membrane electrolysis (ME) cell with the objective to regenerate HCl and NaOH from NaCl. Current efficiency for hydrogen oxidation was determined and its value is 100%, which indicates that the only reaction occurring at the anode is the oxidation of hydrogen. Current-potential curves, recorded in different conditions, showed a linear variation in the range 0-3000 A m⁻² when hydrochloric acid concentration is below 2 mol dm⁻³. In this case, the overvoltage was shown to be mainly due to the ohmic drop in the membrane and in the layer where Nafion^® impregnation was performed. MEA overvoltage necessary to reach 3000 A m⁻² current density was about 0.12 V. For high HCl concentration (6-8 mol dm⁻³), the MEA overvoltage increased sharply with current density due to the adsorption of chloride anions on platinum catalyst.     

A glue method for fabricating membrane electrode assemblies for direct methanol fuel cells

We present a simple glue method for fabricating membrane electrode assemblies (MEA) for direct methanol fuel cells (DMFC). Rather than the conventional “dry” hot-pressing method that relies solely on hot-pressing at a high pressure and temperature to form a MEA, the “wet” method developed in this work introduces a binding agent, consisting of Nafion^® solution, between a polymer electrolyte membrane (PEM) and an anode/cathode. The introduced binding agent can provide a better adhesion and stronger binding force between a membrane and an electrode, thereby facilitating a better interfacial contact between the electrode and the Nafion^® membrane, which has been proved by scanning electron microscopy (SEM) analyses to the cross-sectional morphology of the MEA after long-term operation. The cell performance characterization showed the MEA fabricated by the glue method was more stable in cell performance than that fabricated by the conventional hot-pressing method. Cyclic voltammetry (CV) results also demonstrated the MEA fabricated by the glue method exhibited a higher electrochemical surface area (ESA) as a result of the improved interfacial contact between the Nafion^® membrane and the electrodes. Finally, the DMFC with the MEA fabricated by the glue method was characterized by the electrochemical impedance spectroscopy (EIS).     

Synthesis and physicochemical characterization of amphiphilic block copolymer self‐aggregates formed by poly(ethylene glycol)‐block‐poly(ϵ‐caprolactone)

Diblock copolymers with different poly(ε‐caprolactone) (PCL) block lengths were synthesized by ring‐opening polymerization of ε‐caprolactone in the presence of monomethoxy poly(ethylene glycol) (mPEG‐OH, MW 2000) as initiator. The self‐aggregation behaviors and microscopic characteristics of the diblock copolymer self‐aggregates, prepared by the diafiltration method, were investigated by using ¹H NMR, dynamic light scattering (DLS), and fluorescence spectroscopy. The PEG–PCL block copolymers formed the self‐aggregate in an aqueous environment by intra‐ and/or intermolecular association between hydrophobic PCL chains. The critical aggregation concentrations of the block copolymer self‐aggregate became lower with increasing hydrophobic PCL block length. On the other hand, reverse trends of mean hydrodynamic diameters were measured by DLS owing to the increasing bulkiness of the hydrophobic chains and hydrophobic interaction between the PCL microdomains. The partition equilibrium constants (K_v) of pyrene, measured by fluorescence spectroscopy, revealed that the inner core hydrophobicity of the nanoparticles increased with increasing PCL chain length. The aggregation number of PCL chain per one hydrophobic microdomain, investigated by the fluorescence quenching method using cetylpyridinium chloride as a quencher, revealed that 4–20 block copolymer chains were needed to form a hydrophobic microdomain, depending on PCL block length. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3520–3527, 2006     

民用飞机发动机用耐高温防腐涂料

以环氧改性有机硅树脂为基料，加入耐高温、耐油、防火、隔热的颜填料和N-11固化剂，配成GT系列防腐涂料。该涂料具有常温固化、长期耐高温、耐油、隔热防火等性能，可用作民用飞机发动机的耐高温防腐涂料。     

复合材料弹道冲击性能研究进展

本文总结了近年来复合材料弹道冲击研究的进展,着重从纤维集合体的结构对弹道冲击损伤机理的影响、弹道冲击的分析模型及数值模拟做了概述,总结了人们为提高复合材料弹道冲击性能所做的努力,最后指出了几个尚需深入解决的问题.     

混合装配线过程平衡研究与仿真

生产过程的混合装配线平衡问题,分为在确定条件下的最小生产循环单元的静态平衡问题和不确定条件修正过后的动平衡问题.针对确定工位条件下的混装生产线,构建其静态平衡模型,分析不确定因素,并以操作工人的操作时间不确定性为例,研究时间不确定性动态平衡.利用Flexsim软件,通过仿真进行了验证.相关实验验证了上述方法和结论的正确性.