辽河催化裂化澄清油中间馏分热反应研究

采用先加入絮凝剂脱灰，再经减压蒸馏切割420～500℃馏分的方法，将辽河催化裂化澄清油预处理，考察了澄清油、加入絮凝剂脱灰后的澄清油以及脱灰后再减压蒸馏所得的中间馏分这3种原料在热转化过程中中间相的转化历程，并采用偏光显微镜观察热转化产物。结果表明，澄清油预处理效果明显，所得中间馏分具有较低的H／C原子比（nH／nC）和适宜的组成分布，是生产针状焦的理想原料。热转化产物的光学组织结构属于各向异性发达的广域-流线型结构。     

Influence of aggregate content on the migration coefficient of concrete materials using electrochemical method

In order to investigate the effect of coarse aggregate content on the chloride ion migration coefficient of concrete, specimens with different coarse aggregate volume fractions and two water/cement (w/c) ratios of mortar matrix were used. The chloride ion migration coefficient of concrete is obtained using the electrochemical technique to accelerate chloride ion migration in cement-based material and the experimental results were plotted as a function of the fine aggregate volume fraction. The results are analyzed comparing experimental results and theoretical models that represent the concretes as three-phase composite materials. The three phases are the mortar matrix, the coarse aggregate, and the interfacial transition zone between the two. The chloride ion migration coefficient is used to assess the dilution, tortuosity, interfacial transition zone (ITZ) and, percolation effects of coarse aggregate in concrete. It appears that the dilution and tortuosity effects are a dominant factor affecting the chloride ion migration coefficient of concrete in the low volume fraction of coarse aggregate. As the volume fraction of coarse aggregate increases to 40 and 20% in concrete of w/c ratio 0.35 and 0.45, respectively, the ITZ with percolation effects are significantly.     

海水冻融后轻骨料混凝土的双轴压压强度和变形性能

针对我国渤海湾北部海域轻骨料混凝土结构的工作环境和受力状态，进行了海水中不同冻融循环次数后轻骨料混凝土的双轴压压强度试验，考察了试件的破坏形态和表面裂缝的走向特征。根据试验结果，分析了极限抗压强度随冻融循环次数和应力比的变化规律，并在此基础上建立了考虑海水冻融影响的双轴压压强度准则。探讨了冻融循环作用后轻骨料混凝土的双轴压压变形性能，包括峰值应变、应力-应变关系随冻融循环次数和应力比的变化规律。研究结果说明，随冻融循环次数的增加各种应力比下的应力-应变关系曲线均逐渐扁平，峰值应力点明显下降并右移，说明混凝土的极限抗压强度逐渐降低。     

环己酮肟液相重排反应机理及动力学研究

研究了环己酮肟重排反应生成己内酰胺的机理及反应动力学方程。在建立用分光光度法测定环己酮肟浓度方法的基础上,实验研究了反应温度为20~45℃范围内的液相重排反应动力学。提出了此反应的化学反应动力学速率方程式: -r肟= k0exp (-E/RT)Ca肟Cb硫酸,其中环己酮肟反应级数a为2,硫酸反应级数b为1,活化能为-E/R = -19.86 kJmol-1, 频率因子k0为1.35×1027。通过实验研究证实了作为催化剂的硫酸参与重排反应的机理,认为重排反应过程中游离SO3不参与反应,仅作为水的吸收剂,此结论对环己酮肟液相重排反应的生产技术改造提供了有力依据,并在生产中得到了应用。     

Simon-Type Effects: Chronometric Evidence for Keypress Schemata in Typewriting.

In 4 experiments, chronometric evidence for keypress schemata in typing was sought by presenting stimuli to be typed in positions that were displaced from a central fixation point. Reaction times were shorter when stimulus positions corresponded to keyboard locations of the letters to be typed, suggesting that position was an important part of the internal representation of the response. Experiment 1 presented single letters left and right of fixation. Experiment 2 presented single letters above and below fixation. Experiment 3 presented words left and right of fixation and found evidence of parallel activation of keypress schemata. Experiment 4 found no effect of the eccentricity of the keyboard locations and responding fingers, suggesting that response-location codes are categorical, not metric. The results are consistent with D. E. Rumelhart and D. A. Norman's (1982) theory of typewriting. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

混凝土骨料二维分布的模拟和应用

通过在一个矩形截面上模拟混凝土骨料的实际分布，获得了该截面上任一点的骨料分布密度和骨料分布的统计特性。模拟结果表明，当模拟次数趋向于无穷大时，截面上任一点的骨料分布密度趋向于定值，对于不同的骨料面积百分数，骨料分布密度曲线的形状十分相似，均由上升段和水平段两部分组成。基于这些模拟结果，利用数学拟合获得了骨料分布密度的解析表达式，并被混凝土实验所初步证实。作为一个应用，本文计算了混凝土截面上各点的氯离子扩散系数。     

低熔融指数聚丙烯的开发生产

总结了开发生产低熔融指数聚丙烯的试验过程与结果，通过优选催化剂、优化操作过程、控制加氢量，生产出质量稳定可靠的熔融指数在0．2～0．5g/l0min之间的低熔融指数聚丙烯．     

以杂多酸为催化剂合成乙二醇-乙醚的研究

研究了杂多酸催化无水乙醇和环氧乙烷(EO)制备乙醇乙醚的醚化反应,考察了不同种类的杂多酸以及醚化反应工艺条件对反应活性和选择性的影响.结果表明,PW_(12)催化剂的反应活性高、反应温度低、选择性好,当用PW_(12)作催化剂,乙醇与环氧化乙烷之比为3.0(mol),反应温度45℃,反应时间1h时,转化率和选择性均超过97%.     

Action of chelators on solid iron in phosphate-containing aqueous solutions

To study the effect of strong iron-ligands on steel corrosion, mild steel electrodes were immersed in solutions containing 20 mM phosphate buffer (pH=7.2) and between 0.01 mM and 1 M of either the iron(II)-chelators 2,2^′-bipyridine or FerroZine, or the iron(III)-chelators citrate or acetylacetonate. Resulting surface reactions were investigated by quantifying the electrochemical potential (E), the electrochemical polarization resistance (R_p), the corrosion current (I_corr) and the release of iron into solution. The surface was further analyzed by scanning electron microscopy (SEM/SEM-EDAX) and atomic force microscopy. Concentrations of 0.1 mM of any of the chelators led to slight, temporary changes in E, I_corr and R_p. Concentrations of 10 mM resulted in characteristic changes of E, which were the same for all chelators and in the precipitation of FePO₄ in the case of citrate and acetylacetonate, or vivianite [Fe₃(PO₄)₂ · 8H₂O] in the case of bipyridine and FerroZine. Concentrations of 1 mM of both iron(III)-chelators led to a temporary drop of E similar to that found with 0.1 mM chelator. With iron(II)-chelators, E dropped to about −500 mV before oscillating for several days. The amplitudes of the oscillations were up to 200 mV with periods of 30 and 20-25 min for bipyridine and FerroZine, respectively.     

甲醛与甲酸甲酯的偶联反应 Ⅰ.杂多酸的催化作用

研究了４种杂多酸（磷钨酸、硅钨酸、磷钼酸和硅钼酸）对甲醛和甲酸甲酯偶联反应的催化作用；对反应条件进行了考察。结果表明，磷钨酸和硅钨酸对该反应具有较高的催化活性；而氧化性强的钼系杂多酸的活性较低。水对甲醛和甲酸甲酯的偶联反应具有不利影响。将杂多酸在３００℃进行热处理后，其活性显著增强。