氟硅酸溶液中氟硅酸及氢氟酸含量的测定

基于生成氟硅酸钾沉淀和该沉淀水解均析出不同量酸，用碱滴定完成氟硅酸及氢氟酸的连续测定。该方法用于生产实践，结果令人满意。     

A/O法废水处理碱源的研究与实践

从理论到实践阐述了以具有价格优势的 Na OH替代 Na2 CO3做碱源 ,解决 A / O法运行成本高的问题。     

Evaluating the role of composition and local structure on alkali out-diffusion in glasses for thin-film solar cells

The presence of alkali ions has reportedly improved the performance of CIGS/CZTS–based thin-film solar cells. The out-diffusion of the alkali ion, in particular, Na, from the glass substrate offers a facile scalable route of supplying the alkali ions during the growth of the absorber layer. In this work, we demonstrate the diffusion of different alkali ions (Li/Na/K) from composition tuned glasses with intentionally incorporated excess alkali ions into a thin Mo film, typically used as a bottom electrode in solar cells. We also evaluate the physical, mechanical, and thermal properties of the glasses for suitability as a substrate in thin-film deposition. The out-diffusion of alkali ions to the overlayer is found to be critically influenced by the composition and the local structure of the glasses. The Na ions exhibit the highest extent of diffusion among the alkali ions present in glass substrates, while that for the K-ions is the lowest. For the glasses with mixed alkali ions, the presence of Li facilitated the out-diffusion of Na, whereas K ions appear to inhibit the same. Differently with the existing reports, we show that the activation energy and the presence of Ca ions as additional modifiers play a crucial role in the transport mechanism of the ions. In addition, the synthesized glasses exhibit hardness of the order 5-7 GPa, density ~2.55 g cm^-3. The glass transition temperature lies between 535 and 580°C and the coefficient of thermal expansion 8.5-10 ppm/K, which is highly suitable for use as substrates in thin-film solar cells.     

Erosion-corrosion investigation of high chromium cast irons using newly designed jet type tester

A jet type erosion-corrosion tester was developed for the erosion-corrosion investigation of high-chromium cast irons. During tests the size and the shape of particles in the slurry can be maintained stable. The jet velocity and attack angle can be accurately controlled. The repeatability and ranking consistency of the test results are satisfactory. The test parameters can be adjusted in a wide range, so that the tester can simulate various practical working conditions. Electrochemical test data can be automatically collected and processed. Dynamic polarization curves can be obtained during erosion-corrosion test, which can be used to study the dynamic corrosion characteristics.Two high chromium cast irons were studied in hot concentrated alkaline slurry. The results show that the erosioncorrosion mass loss rate and dynamic corrosion rate of 295Cr26 iron is lower than that of 185Cr13 under the conditions similar to alumyte processing. The mechanism of erosion-corrosion of 295Cr26 and 185Cr13 was studied by using the tester. The interaction between erosion and corrosion was also quantitatively evaluated.     

COMPUTERIZED SIMULATION OF MOLTEN SALT SOLUTION OF Li,KF,Cl SYSTEM BY MOLECULAR DYNAMIC METHOD

The structure and properties of molten salt solution o J Li,K|F,Cl system have been investigedby computerized simulation of molecular dynamic method.The partial RDF,the partial molarenergy of mixing and the diffusion coeffients of Li~+,K~+,F~- and Cl~- have been calculated.The results are in agreement with the experimental values.The regularities of the distributionof ions and mieroscopic holes are discussed based on the results of computerized simulation.     

高浓度铝离子酸碱废液的分析与处理

对高浓度酸碱废液中Al3+的存在形态和特征进行了分析,解决了Al(OH)3难以分离的问题,提出了Al(OH)3分离过程中需注意的一些事项。     

石英砂岩骨料碱活性抑制试验研究

在某水电工程对混凝土骨料料源的选择阶段,初步选定的1#料场石英砂岩骨料被鉴定为具有潜在危害性的碱-硅酸反应(ASR)活性的可疑骨料。通过抑制骨料碱活性效能试验表明,采用低碱水泥取代高碱水泥,或掺一定比例掺合料于高碱水泥中,对骨料的ASR反应都有一定的抑制效果[1],并对几种方法的抑制效果进行了对比分析。研究成果可为其他类似工程提供参考。     

南水北调TJ4-1标工程低碱混凝土试验研究

南水北调工程是国家重点工程,对施工质量要求极高,许多标准要求超过了现行国家标准。TK4-1标工程主要以明挖现浇混凝土3孔箱涵为主,地下水化学类型比较复杂,为防止环境水的腐蚀,必须严格控制原材料及混凝土碱含量。结合混凝土的施工工艺和方法,介绍低碱混凝土配合比的设计及主要参数的选择,从而获得较为合理的混凝土施工配合比。     

DCS控制系统在蒸发工段的应用

分析了碱回收蒸发工段的工艺流程和控制要求,从硬件配置和软件设计等方面对碱回收蒸发工段进行了详细的叙述,同时采取软测量的方法测量黑液浓度,提出黑液浓度-压力串级控制方法;根据工艺要求设计出一种新型的DCS控制方法,它是由西门子公司的SIMATIC 400系列PLC连接ET200系列的分布式I/O系统及标准伺服控制系统组成的DP控制网络,通过相应的智能仪表及阀门对现场信号进行采集和控制;由此对碱回收蒸发工段实施集散控制的优化控制法案;工程实践表明,该系统在江苏甲乙粘胶公司生产线上投用,各种控制性指标能够很好地满足公司的要求。