TM-Gd合金系非晶形成能力的热力学研究（I）

在Co-Gd二元系合金体系的热力学优化评估的基础之上,应用CALPHAD （ CALculation of PHAse Diagram）技术,研究此二元非晶合金的玻璃形成能力。本文分析了700 K、800 K时Co-Gd合金中各元素含量对非晶形成能力的影响,预测了非晶形成的最优成分,计算过冷液相中的结晶相形成驱动力。通过与部分实验和非晶共晶点准则的比较可见,本文所做的热力学分析对此二元合金的非晶制备具有一定的理论指导意义。     

Lithium disilicate glass produced at high pressure: Characterization of structural,thermal and mechanical properties

In this work, high-density lithium disilicate (LS₂) vitreous systems were produced by melting and quenching under high pressure (7.7 GPa) following two distinct experimental routes. In the first case, LS₂ glass was remelted at 7.7 GPa and 1600°C and, then, quenched. In the second case, a stoichiometric mixture of precursor oxides (Li₂O and SiO₂) was melted at 1600°C and 7.7 GPa before quenching. A reference LS₂ glass sample was produced at atmospheric pressure using conventional melting and quenching procedure. The samples were characterized by X-ray diffraction, differential thermal analysis, and instrumented ultramicro hardness measurements. X-ray diffraction confirmed that all samples were amorphous and thermal analysis suggests that different glassy structures were produced depending on the route of synthesis. Hardness and elastic modulus of the glasses produced under high pressure were higher than those of the reference glass, reflecting the irreversible densification effect induced by the high-pressure processing.     

Electrocatalytic properties of Ni-S-Co coating electrode for hydrogen evolution in alkaline medium

Amorphous Ni-S-Co alloy was prepared by means of chemical electro-deposition method on the foam nickel matrix. The surface morphology and microstructure of Ni-S-Co coatings were studied usmg SEM and XRD, and the electrochemical properties were tested by electrochemical methods. The results show that the coating has amorphous structure and the particles of the surface are fine with large specific surface area. The Ni-S-Co alloy is more active with lower potential for hydrogen evolution, higher exchange current density and lower activation energy compared with Ni and Ni-S electrode. Its hydrogen evolution reaction（HER） is enhanced, the size of particles of surface decreases and the surface area increases after being activated by KOH alkaline solution.     

合金化对非晶形成能力影响的电子理论计算

根据分子动力学理论建立了非晶Ni64Pd16Al20的结构模型，利用Recursion方法计算了Ni64X17Al20系非晶及相应晶态的电子结构。结果表明，Ni64X16Al20合金的非晶形成能力与过渡元素局域电子态密度的双峰位置、电子得失形成的离子键及非晶与晶态合金的总结构能差有关。局域电子态密度的结果表明，A1与过渡元素间存在电子耦合一共价相互作用，合金元素使Ni64X16Al2合金非晶形成能力从强到弱的顺序是：Ir，Pt，Rh，Pd，Au，Ag，Cu；Ni64X16Al20合金中离子键的存在使其非晶形成能力增强。非晶与晶态合金的总结构能差越小的过渡元素使其形成非晶的驱动力越强，对非晶形成越有利，由此得出的规律与上述共价键的作用规律一致。     

EFFECT OF COMPOSITION ON PHYSICAL PROPERTIES OF AMORPHOUS Fe-Si-B ALLOYS

ＥＦＦＥＣＴＯＦＣＯＭＰＯＳＩＴＩＯＮＯＮＰＨＹＳＩＣＡＬＰＲＯＰＥＲＴＩＥＳＯＦＡＭＯＲＰＨＯＵＳＦｅＳｉＢＡＬＬＯＹＳ①ＷａｎｇＬｉｎｇｌｉｎｇ，ＺｈａｏＬｉｈｕａ，ＨｕＷａｎｇｙｕ，ＷｕＬｉｊｕｎ，ＺｈａｎｇＢａｎｇｗｅｉＤｅｐａｒｔｍｅ...     

Formation and crystallization of bulk Pd_(82)Si_(18) amorphous alloys

1　INTRODUCTIONMetallicglassisregardedasastatethatisofdis orderunlikecrystalalloyswith periodicatomstruc ture.Soitshowsexcellentcapabilitiesofsoftmag netism ,mechanics ,corrosionresistance ,etc .How ever ,mostofamorphousalloyswereproducedbyus ingrapidsolidificationmethodssuchassplatquench ing ,meltspinning ,andsoon ,withcharacteristiccoolingratesof 10 4 10 6 K/s .Becauseamorphousal loysarepreparedwithsilk ,powderandribbon ,itisgreatlylimitedinengineeringapplication .Recently ,severalbulk…     

Deformation of metallic glasses with special emphasis in supercooled liquid region

1　ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｔｅｎｓｉｖｅｅｆｆｏｒｔｓｈａｖｅｂｅｅｎｃａｒｒｉｅｄｏｕｔｏｖｅｒｔｈｅｐａｓｔｄｅｃａｄｅｔｏｄｅｖｅｌｏｐｍｅａｎｓｔｏｓｌｏｗｄｏｗｎｔｈｅｐｈａｓｅｔｒａｎｓｆｏｒｍａｔｉｏｎｋｉｎｅｔｉｃｓｄｕｒｉｎｇｔｈｅ     

Investigation of microstructure of laser cladding Ni-WC layer on Al-Si alloy

A plasma-sprayed Ni-WC layer was deposited on an Al-Si cast alloy surface, and then it was further melted by a 5 kW CO₂ laser. The microstructure and chemical composition of the laser-melted zone were investigated, and the microhardness in different parts was measured. Experimental results showed that the chemical composition of the sample was not uniform. Compositional segregation in the laser-melted zone was found. Some amorphous structure appeared in the nickel-rich locations after laser melting. Owing to the thermal effect of the laser scanning, an intermediate-phase Ni₃Al segregated from this region and formed Ni₃Al grains and amorphous grains. Some WC particles melted in the matrix, and chromium carbide Cr2;|C6 and (Cr,W)C separated during the cooling process. The highest microhardness (1027HV) was found in the high-nickel region.