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91.
Shuichi Osanai Yoshiro Abe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(1):43-45
Optically active and racemic quaternary ammonium cationics containing a chiral alkyl group, such as N,N-dimethyl-N-(1-phenylethyl)alkylammonium bromides were prepared and showed excellent antimicrobial properties against Gram positive and negative bacteria, with some exceptions, and against fungi. The influence of optical isomerism on their antimicrobial properties showed that the antimicrobial properties between racemic and optically active cationics were obscure. The order of activity of substituted alkyl groups was tetradecyl > dodecyl ° hexadecyl. 相似文献
92.
亚硫酸钙氧化为石膏的研究 总被引:6,自引:0,他引:6
进行了亚硫酸钙氧化为二水石膏的研究 ,考察了初始 p H值、反应温度、空塔气速、固含量和停留时间对氧化率的影响 ,给出了适宜的反应条件 .在这些条件下 ,氧化率达 96 %以上 相似文献
93.
Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen 总被引:2,自引:0,他引:2
The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism. 相似文献
94.
二次型时频分析技术的开发与应用 总被引:1,自引:1,他引:0
基于二次型的时频分析是高分辨率时频分析技术的有效方法之一,该项技术能够有效反映时变信号的频谱特性,具有分辨率高、能量集中和跟踪瞬时频率的特点。从时变信号的特点出发,阐述了二次型时频分析技术的基本方法原理,采用正演模型分析验证了该方法的有效性,并在实际地震资料中应用于识别物源方向、划分沉积相带、预测储层结构以及相对厚度等诸多方面,均取得了较好的效果。 相似文献
95.
Alexander Pavlov Gonzalo D Garcia De Fernando Juan A Ordoez Lorenzo Hoz 《Journal of the science of food and agriculture》1994,64(2):141-143
The β-hydroxyacyl-CoA-dehydrogenase (HADH) activity of unfrozen and thawed frog legs was investigated. The enzyme was extracted by either immersing frog legs in phosphate buffer 0.1 M, pH 6.0 at 25°C for 15 min or pressing them between trichinoscopy glasses. The enzyme activity was assayed using acetoacetyl-CoA as substrate and measured spectrophotometrically at 340 nm. It was possible by both extraction methods to distinguish between thawed and unfrozen samples although when the juice was obtained by pressing the HADH activity of the dilution was ~ 1.5 times higher than that obtained by immersion. The HADH activity was significantly higher (P≤0·001) in frozen-thawed frogs than in unfrozen legs because during freezing there is a release of HADH. No significative differences were found in the HADH activity in samples frozen in the temperature range -10 to -196°C. HADH activity was not affected by the storage time in crushed ice up to 6 days. 相似文献
96.
Enzymatic Browning in Apple Pulps 总被引:3,自引:0,他引:3
Enzymatic browning in Golden Delicious apple pulp was studied as related to degree of ripeness and temperature (3.5–31°C). Green apple pulp showed the highest rate of browning. This was attributable to differences in ascorbic acid (AA) content and polyphenoloxidase activity in young fruits. The rate of browning determined by CIE L* measurements followed complex temperature dependent kinetics, represented by a multiple linear effects with log time. Equal changes in L* parameter yielded straight lines in a log temperature vs log time plot. Inhibition with AA caused an initial slow rate of browning and a well defined break point associated with exhaustion of antioxidant properties of the AA. The greater the AA concentration the longer the initial period. 相似文献
97.
本实验用透射电镜和扫描电镜观察了动情期家兔输卵管上皮。证实分泌细胞和纤毛细胞都有分泌功能,共分泌三种分泌物质。本文对这些分泌物质的分泌方式、分泌活动进行了研究和探讨。另外,发现上皮基膜下方始终有一层成纤维细胞形成的胞质膜伴行,据此,对血一输卵管腔屏障的构成亦进行了讨论。 相似文献
98.
钼酸铵生产中杂质的分离方法 总被引:1,自引:0,他引:1
简要地介绍了钼酸铵生产中有害杂质的各种分离方达及应用情况,并就各种方法的利弊作了对比说明。 相似文献
99.
经试验发现应用一种化学肥料硫酸铵可以显著提高乌拉嘎金矿石的浮选回收率。闭路试验尾矿工艺矿物学鉴定证明,以硫酸铵作为调整剂的浮选过程中,微细粒单体金和金与石英边生体被有效回收。 相似文献
100.
The interaction of alkali metal with surfaces has been of great interest to the community of catalysis since alkali metal can play an important role as a promoter. On alkali-doped MoS2, such a promotion effect of alkali metal has been exemplified in the direct synthesis of linear alcohols from CO and H2, where the alkali-doping switches the catalyst selectivity from methanation to alcohol synthesis. This paper reviews recent high-resolution X-ray photoelectron spectroscopy experiments that have provided direct
observation of electron transfer from alkali metals to a model single crystal MoS2 and the capture of the supra-valence electrons in the subsequent oxidation reactions. 相似文献