液态金属钠高温沸腾实验回路应力分析与强度计算

本文主要完成了液态金属钠高温沸腾实验回路的应力分析与计算，确定了回路高温区连接管系的布置型式和支吊架系统，是该回路总体设计的重要组成部分。     

膜催化氧化正丁烷制顺酐

以多孔玻璃管为基体，制备４种用于正丁烷氧化制顺酐的膜反应器。在一定的操作条件下，考察了固定床反应器与这４种膜反应器在正丁烷氧化制顺酐中的反应性能并加以比较，发现ＹＳＺ膜反应器可获得高于固定床反应器的选择性和收率。     

新型废水厌氧处理工艺——内循环厌氧反应器

介绍内循环(IC)厌氧反应器的发展、基本结构、运行机理。分析该反应器的工艺过程,指出该工艺具有处理效率高、抗冲击能力强等优点。针对IC反应器存在的缺陷,人们对该反应器进行技术改进:通过提高它的内循环的气量进行处理低浓度有机废水;增加外循环装置缩短IC反应器的启动周期。     

Optimal Conditions for Preparing Ultra-Fine CeO2 Powders in A Submerged Circulative Impinging Stream Reactor

Cerium carbonate powders were produced in a submerged circulation impinging stream reactor (SCISR) from Ce(NO3)3·6H2O. NH4HCO3 was used as a precipitant in the reaction. Cerium carbonate powders were roasted to produce ultra-fine cerium dioxide (CeO2) powders. The optimal conditions of such production process were obtained by orthogonal and one-factor experiments. The results showed that ultra-fine and narrowly distributed cerium carbonate powders were produced under the optimal flowing conditions. The concentrations of Ce(NO3)3 and NH4HCO3 solutions were 0.25 and 0.3 mol·L-1, respectively. The concentration of PEG4000 added in these two solutions was 4 g·L-1. The stirring ratio, reaction temperature, feeding time, solution pH, reaction time and digestion time were 900 r·min-1, 80 ℃, 20 min, 5～6, 5 min and 1 h, respectively. The final product, CeO2 powders, was obtained by roasting the produced cerium carbonate in air for 3 h at 500 ℃. The finally produced CeO2 powders were torispherical particles with a narrow size distribution of 0.8～2.5 μm. The crystal structure of CeO2 powders belonged to cubic crystal system and its space point group was O5H-FM3M. Under optimal conditions, powders produced by SCISR were finer and more narrowly distributed than that by Stirred Tank Reactor (STR).     

Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

利用扫描电镜研究三维电极主电极表面腐蚀状况

借助扫描电镜（SEM）对不同实验条件下的三维电极主电极表面腐蚀状况进行研究。结果表明，三维电极主极阳极的内侧腐蚀程度远大于其外侧，水样性质、电极材料性质对电极的腐蚀程度有很大的影响，不锈钢做三维电极主电极优于铝、铁电极。为三维电极主电极的选材提供了一定的理论依据。     

R－X图解法计算多级串联理想混合反应器

论述Ｒ－Ｘ图解法计算多级串联理想混合反应器的基本原理，并结合实例，对Ｒ－Ｘ法的计算步骤予以详细介绍，为多级串联反应器的设计与计算，提供一种新颖适用的图解计算方法。     

Analysis of low load transients for the Vandellòs-II NPP: Application to operation and control support

The Technical University of Catalonia (UPC) has been jointly working with the Asociación Nuclear Ascó-Vandellòs (ANAV) for a number of years in order to establish, qualify and use best estimate (BE) models for the reactors under the control of ANAV. ANAV is the consortium that is responsible for operation of the Ascó and Vandellòs-II reactors. The reactors are Westinghouse-design three-loop PWRs with an approximate electrical power of 1000 MW. The existing integral plant models for each plant are currently used for many different purposes among which are support of plant operation and control. Quite a number of studies have been done in order to improve both safety and plant competitiveness. Most of these dynamic analyses were carried out in relation to transients starting at nominal full power or at least, very close to full power. This paper develops a specific use of the Vandellòs-II plant model for operation and control support at low power involving new ranges of system actuation parameters. It also examines scenarios that are somewhat different from those typically analysed. The study starts showing the results of an assessment case, which is a start-up test and provides some additional qualification, and subsequently attempts to establish calculations to support both an improvement in feed water controls and to set up operating recommendations for low-load manual operation of feed water turbo-pump. Both results hopefully, will produce an outcome, which leads to an improvement in safety and reduces reactor trip probability.     

我国核裂变能可持续发展战略研究

本文从科学技术的角度,分析我国国民经济增长对核能发展的需求,探讨我国核能的近中期发展战略构想,指出为实现其发展战略目标而应重点研究的关键科学技术与问题,并提出一些相关的政策建议,为国家制定核能中长期发展规划提供参考。     

中空纤维酶膜反应器及其动力学初步探讨──Ⅰ．单酶系统中空纤维酶膜反应器

单酶系统中空纤维酶膜反应器是用天津纺织工学院研制的ＴＦＣ－００３型聚砜中空纤维超滤器固定β－淀粉酶，在一定条件下催化可溶性淀粉制取麦芽糖的反应器。试验中，对温度、ｐＨ、酶及底物浓度变化动力学参数进行了初步探讨，试验重复性好。