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31.
Oxygen nonstoichiometry in the distorted perovskite BaBiO3 has been studied by thermogravimetric analysis using controlled oxygen pressures. Three distinct regions of nonstoichiometry are observed with composition ranges which narrow as the temperature is lowered. Samples isolated from each region were shown by powder X-ray diffraction to retain the perovskite subcell but show different types of framework distortion. Low temperature reoxidation of the oxygen deficient phases is also described. 相似文献
32.
《中国稀土学报(英文版)》2022,40(12):1849-1859
A series of Ce1–xTixO2 mixed oxide catalysts were synthesized by sol-gel method and then loading of noble metal (M = Pt, Rh, Ru) was used for soot oxidation. Ti-doped Ce1–xTixO2 catalysts (x is the molar ratio of Ti/(Ti + Ce) and ranges from 0.1 to 0.5) exhibit much better oxidation performance than CeO2 catalyst, and the Ce0.9Ti0.1O2 catalyst calcined at 500 °C has the best catalysis activity. Each noble metal (1 wt%) was supported on Ce0.9Ti0.1O2 (M/C9T1) and the properties of the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman, Brunauer–Emmett–Teller (BET) method, and H2-temperature programmed reduction (H2-TPR) results. Results show that the introduction of Ti into CeO2 forming Ti-O-Ce structure enhances the catalytic activity and increases the number of oxygen vacancies at the catalyst surface. The noble metal is highly dispersed over Ce0.9Ti0.1O2, and M/C9T1 catalysts present enhanced activity in comparison to Ce0.9Ti0.1O2. It is found that noble metals can greatly increase the activity of the catalyst and the corresponding oxidation rate of soot can enhance the electron transfer capacity and oxygen adsorption capacity of the catalyst. A small amount of Ti doping in CeO2 can significantly improve the activity of the catalyst, while a large amount of Ti reduces the performance of the catalyst because a large amount of Ti is enriched on the surface of the catalyst, which hinders the contact and reaction between the catalyst and the soot. 相似文献
33.
Activated carbon is a suitable adsorbent for removal of hydrogen sulphide from natural, synthesis or other product gases. The process depends predominantly on physical adsorption, though catalytic oxidation is also involved. During catalytic oxidation the H2S is converted in the presence of oxygen to elemental sulphur, which is adsorbed onto the internal surface of the activated carbon, thus leading to a sulphur load of up to 120% by weight. The oxidation rate depends on the partial pressure of both reactants, H2S and O2 and is largely controlled by the characteristics of the activated carbon. The activity of the catalyst can be improved by impregnating the activated carbon with promoters such as iron and iodine. The regeneration of spent carbon is currently carried out using hot gas desorption methods at temperatures around 450 °C. 相似文献
34.
The effect of the platinum particle size was investigated for the catalytic oxidative dehydrogenation of aqueous ethanol to ethanal at a temperature of 303 K, an ethanol concentration of 260 mol m–3, a partial oxygen pressure 60 kPa, a pH of 9, and an ethanal and ethanoate concentration of 20 mol m–3. A particle size effect on the turnover frequency was observed but only for particle sizes smaller than 2 nm. Hence, the reaction shows a limited structure sensitivity. 相似文献
35.
Polycrystalline Ag treated with O2 at pressures up to 1 bar and at temperatures up to 920 K was examined by TDS. It was found that the peak commonly observed at 595±25 K and assigned to adsorbed atomic oxygen (Oa) is shifted to higher desorption temperatures with rising dosing temperatures. Since saturation of the uptake was not possible either, this peak was identified as dissolved atomic oxygen (Od). The existence of a maximum for the O2 uptake after exposure at 820 K was found. Hence, under conditions of formaldehyde synthesis ( 920 K) the ability of the catalyst to dissolve oxygen is near its maximum. 相似文献
36.
37.
ABSTRACT In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH?/Ca(OH)+ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic. 相似文献
38.
甲酸甲酯合成与转化的催化技术 总被引:3,自引:0,他引:3
本文评述了甲酸甲酯(MF)合成与转化的催化技术,展示了从MF出发发展C_1化学的可能途径,在MF的合成方面详细地分析了从甲醇出发的羰化法、脱氢法和氧化法催化技术,简介了我们的有关研究工作。 相似文献
39.
Bleached and unbleached forms of a rosemary oleoresin (RO) in stripped and nonstripped soybean oil behave both as antioxidant
and prooxidant in a light-induced oxidative system. At 0.02 and 0.05% levels, RO had the greatest antioxidant activity, while
at 0.01 and 0.5% levels it had the highest prooxidant activity in both stripped and nonstripped soybean oil. Treatment of
both soybean oil systems with tertiary butylhydroquinone controlled light-induced oxidation of the oil better than did the
oleoresin treatments. The prooxidant activity of the 0.5% RO level was probably due to an excess of prooxidant components
being carried into the oil at that level, whereas the reduced antioxidant activity at 0.01% was probably due to the low initial
level of active antioxidant components being added to the oil.
Published as Journal Series No. 10072, Nebraska Agricultural Research Division, Department of Food Science and Technology,
University of Nebraska, Lincoln, NE 68583-0919. 相似文献
40.
Utilising a pseudo-reference electrode in polymer electrolyte fuel cells allows for the separation of anodic and cathodic contributions to the entire cell impedance. Modelling the impedance responses by using equivalent circuits inhibits the investigation of kinetic parameters of the basic electrochemical reactions, which take place at single electrode-electrolyte interfaces. Therefore, we evaluate single electrode impedance measurements by a kinetic model, which is based on specific reaction pathways, either for the oxygen reduction reaction (ORR) or the hydrogen oxidation reaction (HOR). As a consequence, it is possible to obtain kinetic parameters for the specific reaction of interest. Furthermore, the information gained from the single electrode impedance measurements and the kinetic model can give insight into single reactions steps. In particular, the ORR has to include a chemical step in the reaction pathway. 相似文献