钛合金粘接件表面技术研究

详细地说明了钛合金表面处理的原理，进行了钛合金粘接接头的阳极氧化表面处理方法的研究，与其他表面处理方法相比，本试验方法大大改善了钛合金粘接接头的性能，便于工艺实施。     

Electrochemical properties of quaternary ammonium borodiglycolates and borodioxalates

Quaternary ammonium borodiglycolates and borodioxalates were prepared by the reaction of quaternary ammonium tetrahydroxyborates with glycolic acid and oxalic acid, respectively. These compounds are used as the electrolyte salts of aluminum electrolytic capacitors. Their molar conductivities, limiting molar conductivities and oxidation potentials in γ-butyrolactone were higher than those of borodisalicylates and borodicatecholates due to the lack of aromatic rings. Their film-forming ability of anodic aluminum oxide in γ-butyrolactone electrolytes containing a small amount of water was poor, because both anodic dissolution and oxidation occurred simultaneously.     

Effect of anodization on the graphitization of PAN-based carbon fibers of PAN-based carbon fibers

One-step pretreatment,anodization,is used to activate the polyacrylonitrile (PAN)-based carbon fibers instead of the routine two-step pretreatment,sensitization with SnCl2 and activation with PdCl2.The effect of the anodization pretreatment on the graphitization of PAN-based carbon fibers is investigated as a function of Ni-P catalyst.The PAN-based carbon fibers are anodized in H3PO4 electrolyte resulting in the formation of active sites,which thereby facilitates the following electroless Ni-P coating.Carbon fibers in the presence and absence of Ni-P coatings are heat treated and the structural changes are characterized by X-ray diffraction and Raman spectroscopy,both of which indicate that the graphitization of PAN-based carbon fibers are accelerated by both the anodization treatment and the catalysts Ni-P.Using the anodized carbon fibers,the routine two-step pretreatment,sensitization and activation,is not needed.     

挤压铸造5035 铝镁合金阳极氧化染黑色后白点故障分析

挤压铸造5035铝镁合金在硫酸阳极氧化以及在酸性染色溶液染黑色后表面出现白点,影响产品的外观。采用能谱仪分析了5035铝镁合金基体及阳极氧化膜的元素成分,并采用金相显微镜观察基体表面形貌及阳极氧化膜的表面与截面形貌,结合基材的挤压铸造过程进行分析,得出产生白点的可能原因是挤压铸造时产生的缩孔。提出了挤压铸造及阳极氧化工艺的改进措施。     

Vertical Organic Thin‐Film Transistors with an Anodized Permeable Base for Very Low Leakage Current

The organic permeable base transistor (OPBT) is currently the fastest organic transistor with a transition frequency of 40 MHz. It relies on a thin aluminum base electrode to control the transistor current. This electrode is surrounded by a native oxide layer for passivation, currently created by oxidation in air. However, this process is not reliable and leads to large performance variations between samples, slow production, and relatively high leakage currents. Here, for the first time it is demonstrated that electrochemical anodization can be conveniently employed for the fabrication of high‐performance OPBTs with vastly reduced leakage currents and more controlled process parameters. Very large transmission factors of 99.9996% are achieved, while excellent on/off ratios of 5 × 10⁵ and high on‐currents greater than 300 mA cm^?2 show that the C₆₀ semiconductor layer can withstand the electrochemical anodization. These results make anodization an intriguing option for innovative organic transistor design.     

环保型镁合金阳极氧化工艺的研究

研究一种无铬无磷无氟的镁合金阳极氧化工艺.对AZ31B镁合金进行阳极氧化时,在植酸、电流密度和时间不变的条件下,研究了NaOH、Na2SiO3、Na2B4O7不同浓度的16种电解液的阳极氧化膜性能.研究结果表明,组成为NaOH 50g/L、Na2SiO3 60g/L、Na2B4O7 40g/L的电解液,进行阳极氧化得到的氧化膜光滑致密,与基体的结合力强,耐蚀性高,用该电解液对镁合金进行阳极氧化是一种环保型生产工艺.     

氧化时间和温度对Si基AAO模板制备的影响

采用一次阳极氧化法,通过电解P型<100>晶向Si衬底上的高纯Al膜,在40V下,0.3M草酸中制备了Si基anodic aluminum oxide(AAO)模板。在Si基Al氧化过程中,通过电流密度随时间实时变化曲线的分析,研究了Si基AAO的生长机理。实验发现,电解液温度对Si基AAO制备的影响很大,在30℃下的氧化速度是在10℃下的5倍多。     

钽的熔盐阳极化工艺研究

研究了金属钽在ＬｉＮＯ３－助熔盐的熔盐体系中阳极氧化、生成表面硬质膜的工艺，并在应用稀土添加剂改善膜层，从而强化钽材，提高耐蚀性能。     

铝阳极氧化膜在亚铁盐溶液中的电解着色

在亚铁盐溶液中添加渗透剂JF制备了Fe盐铝电解着色膜。用分光光度计测量了铁在氧化膜中的含量，讨论了着色液中各组分及电解参数对着色的影响。试验结果表明只有在含有JF的亚铁盐溶液中才能在氧化膜中沉积铁，膜的颜色随氧化膜中铁的含量增加而加深，但不成正比关系，真黑色的膜难以得到。     

镁合金的阳极氧化研究

阳极氧化是镁合金表面改性的有效方法.基于经典的阳极氧化工艺,目前的研究取得了长足的进步,主要表现在电解质溶液成分的改进、电参数的研究、成膜机理、膜层成分和结构的研究,以及后处理等.本文对其进行了详细的综述,同时指出了发展趋向.